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Title: Wide emission-tunable CdTeSe/ZnSe/ZnS core–shell quantum dots and their conjugation with E. coli O-157

Abstract

Highlights: • QDs with variety morphology were obtained via an injection controlled process. • 3-D PL spectra of core–shell QDs show different excitation wavelength dependence. • The PL intensity of QDs with ZnSe transition layer increases dramatically. • Core–shell QDs were processed into aqueous phase and conjugated with E. coli O-157. - Abstract: Wide emission-tunable and different morphological alloyed CdTeSe quantum dots (QDs), CdTeSe/ZnS and CdTeSe/ZnSe/ZnS core–shell QDs were successfully synthesized via an injection controlled process. The effect of injection procedure and reaction temperature were systematically discussed and the growth mechanism was proposed. Most efficient PL wavelength was correlated with reaction time and temperature. The 3-D PL spectra of spherical bare CdTeSe and core–shell QDs with different passivation showed different excitation wavelength dependency. The PL intensity of CdTeSe/ZnSe/ZnS core–shell QDs increased greatly in comparison with that of CdTeSe and CdTeSe/ZnSe QDs. ZnSe transition layer played an important role in improving the PL intensity by providing a smoothened interface and gradient band offsets. The core–shell QDs were transferred into aqueous phase and successfully conjugated with Escherichia coli O-157. The proposed phase-transfer and bio-labeling strategy may be applicable to various QDs with different compositions.

Authors:
 [1];  [1];  [2]; ; ; ;  [1]
  1. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100 (China)
  2. Center for Disease Control and Prevention of Jinan Military Command, Jinan 250014 (China)
Publication Date:
OSTI Identifier:
22475756
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 65; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ALLOYS; CADMIUM COMPOUNDS; ESCHERICHIA COLI; EXCITATION; FREQUENCY DEPENDENCE; INJECTION; INTERFACES; LAYERS; LUMINESCENCE; PASSIVATION; QUANTUM DOTS; SELENIUM COMPOUNDS; SPECTRA; SYNTHESIS; TELLURIUM COMPOUNDS; WAVELENGTHS; ZINC SELENIDES; ZINC SULFIDES

Citation Formats

Zhou, Haifeng, Zhou, Guangjun, E-mail: gjzhou@sdu.edu.cn, Zhou, Juan, Xu, Dong, Zhang, Xingshuang, Kong, Peng, and Yang, Zhongsen. Wide emission-tunable CdTeSe/ZnSe/ZnS core–shell quantum dots and their conjugation with E. coli O-157. United States: N. p., 2015. Web. doi:10.1016/J.MATERRESBULL.2015.01.036.
Zhou, Haifeng, Zhou, Guangjun, E-mail: gjzhou@sdu.edu.cn, Zhou, Juan, Xu, Dong, Zhang, Xingshuang, Kong, Peng, & Yang, Zhongsen. Wide emission-tunable CdTeSe/ZnSe/ZnS core–shell quantum dots and their conjugation with E. coli O-157. United States. doi:10.1016/J.MATERRESBULL.2015.01.036.
Zhou, Haifeng, Zhou, Guangjun, E-mail: gjzhou@sdu.edu.cn, Zhou, Juan, Xu, Dong, Zhang, Xingshuang, Kong, Peng, and Yang, Zhongsen. Fri . "Wide emission-tunable CdTeSe/ZnSe/ZnS core–shell quantum dots and their conjugation with E. coli O-157". United States. doi:10.1016/J.MATERRESBULL.2015.01.036.
@article{osti_22475756,
title = {Wide emission-tunable CdTeSe/ZnSe/ZnS core–shell quantum dots and their conjugation with E. coli O-157},
author = {Zhou, Haifeng and Zhou, Guangjun, E-mail: gjzhou@sdu.edu.cn and Zhou, Juan and Xu, Dong and Zhang, Xingshuang and Kong, Peng and Yang, Zhongsen},
abstractNote = {Highlights: • QDs with variety morphology were obtained via an injection controlled process. • 3-D PL spectra of core–shell QDs show different excitation wavelength dependence. • The PL intensity of QDs with ZnSe transition layer increases dramatically. • Core–shell QDs were processed into aqueous phase and conjugated with E. coli O-157. - Abstract: Wide emission-tunable and different morphological alloyed CdTeSe quantum dots (QDs), CdTeSe/ZnS and CdTeSe/ZnSe/ZnS core–shell QDs were successfully synthesized via an injection controlled process. The effect of injection procedure and reaction temperature were systematically discussed and the growth mechanism was proposed. Most efficient PL wavelength was correlated with reaction time and temperature. The 3-D PL spectra of spherical bare CdTeSe and core–shell QDs with different passivation showed different excitation wavelength dependency. The PL intensity of CdTeSe/ZnSe/ZnS core–shell QDs increased greatly in comparison with that of CdTeSe and CdTeSe/ZnSe QDs. ZnSe transition layer played an important role in improving the PL intensity by providing a smoothened interface and gradient band offsets. The core–shell QDs were transferred into aqueous phase and successfully conjugated with Escherichia coli O-157. The proposed phase-transfer and bio-labeling strategy may be applicable to various QDs with different compositions.},
doi = {10.1016/J.MATERRESBULL.2015.01.036},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = ,
volume = 65,
place = {United States},
year = {2015},
month = {5}
}