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Title: Response to reply on “Structural and magnetic behavior of the cubic oxyfluoride SrFeO{sub 2}F studied by neutron diffraction”

Abstract

Clemens et al. reported on the results published by us (Thompson et al. J. Solid State Chem. 219 (2014) 173–178) on the crystal structure of SrFeO{sub 2}F, which they suggest to actually crystallize in the orthorhombic space group Imma rather than the cubic Pm-3m structure at lower temperatures (Clemens et al. J. Solid State Chem. (2015), (http://dx.doi.org/10.1016/j.jssc.2015.02.022)). In this report, we provide evidence to support their claim that at lower temperatures (<523 K) the structure is evidently Imma. Furthermore, we will highlight the significance of our previous report and comment on the proposed explanations of the magnetic behavior of SrFeO{sub 2}F reported by both groups.

Authors:
 [1];  [2];  [3];  [1];  [2]
  1. Department of Chemistry and Brockhouse Institute of Materials Research, McMaster University, Hamilton, ON, Canada L8S 4M1 (Canada)
  2. Department of Chemistry, Michigan State University, East Lansing, MI 48824 (United States)
  3. Canadian Neutron Beam Centre, National Research Council, Chalk River Laboratories, Chalk River, ON, Canada K0J 1J0 (Canada)
Publication Date:
OSTI Identifier:
22475672
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 226; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANTIFERROMAGNETISM; CRYSTALLIZATION; ION MICROPROBE ANALYSIS; NEUTRON DIFFRACTION; ORTHORHOMBIC LATTICES; OXYFLUORIDES; SOLIDS; TEMPERATURE DEPENDENCE; TETRAGONAL LATTICES

Citation Formats

Thompson, Corey M., E-mail: thompco@mcmaster.ca, Blakely, Colin K., Flacau, Roxana, Greedan, John E., and Poltavets, Viktor V. Response to reply on “Structural and magnetic behavior of the cubic oxyfluoride SrFeO{sub 2}F studied by neutron diffraction”. United States: N. p., 2015. Web. doi:10.1016/J.JSSC.2015.03.021.
Thompson, Corey M., E-mail: thompco@mcmaster.ca, Blakely, Colin K., Flacau, Roxana, Greedan, John E., & Poltavets, Viktor V. Response to reply on “Structural and magnetic behavior of the cubic oxyfluoride SrFeO{sub 2}F studied by neutron diffraction”. United States. doi:10.1016/J.JSSC.2015.03.021.
Thompson, Corey M., E-mail: thompco@mcmaster.ca, Blakely, Colin K., Flacau, Roxana, Greedan, John E., and Poltavets, Viktor V. Sun . "Response to reply on “Structural and magnetic behavior of the cubic oxyfluoride SrFeO{sub 2}F studied by neutron diffraction”". United States. doi:10.1016/J.JSSC.2015.03.021.
@article{osti_22475672,
title = {Response to reply on “Structural and magnetic behavior of the cubic oxyfluoride SrFeO{sub 2}F studied by neutron diffraction”},
author = {Thompson, Corey M., E-mail: thompco@mcmaster.ca and Blakely, Colin K. and Flacau, Roxana and Greedan, John E. and Poltavets, Viktor V.},
abstractNote = {Clemens et al. reported on the results published by us (Thompson et al. J. Solid State Chem. 219 (2014) 173–178) on the crystal structure of SrFeO{sub 2}F, which they suggest to actually crystallize in the orthorhombic space group Imma rather than the cubic Pm-3m structure at lower temperatures (Clemens et al. J. Solid State Chem. (2015), (http://dx.doi.org/10.1016/j.jssc.2015.02.022)). In this report, we provide evidence to support their claim that at lower temperatures (<523 K) the structure is evidently Imma. Furthermore, we will highlight the significance of our previous report and comment on the proposed explanations of the magnetic behavior of SrFeO{sub 2}F reported by both groups.},
doi = {10.1016/J.JSSC.2015.03.021},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 226,
place = {United States},
year = {Sun Mar 15 00:00:00 EDT 2015},
month = {Sun Mar 15 00:00:00 EDT 2015}
}