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Title: Surfactant-thermal method to synthesize a new Zn(II)-trimesic MOF with confined Ru(bpy){sub 3}{sup 2+} complex

Abstract

A surfactant-thermal method was used to prepare a new zinc-1,3,5-benzentricarboxylate-based metal-organic framework (ZJU-100) with confined Ru(bpy){sub 3}{sup 2+} (RuBpy) complex by using surfactant PEG 400 as reaction medium. The RuBpy molecules were encapsulated between the 2-D sheets in ZJU-100. ZJU-100 showed bathochromic shift in the steady-state emission spectrum and increased emission lifetimes relative to RuBpy molecules. The extended lifetime is attributed to the reduced nonradiative decay rate due to the stabilization of RuBpy within the rigid MOF framework. These results represent the first example of MOF with confined complex synthesized by surfactant, indicating that the surfactant-thermal method could offer exciting opportunities for preparing new MOFs host/guest materials with novel structures and interesting luminescent properties. - Graphical abstract: A surfactant-thermal method was used to prepare a new zinc-1,3,5-benzentricarboxylate-based metal-organic framework (ZJU-100) with confined Ru(bpy){sub 3}{sup 2+} (RuBpy) complex by using surfactant PEG 400 as reaction medium. - Highlights: • Surfactant-thermal synthesis of crystalline metal-organic framework host/guest materials. • RuBpy molecules were encapsulated between the 2-D sheets of MOFs. • Extended lifetime is observed due to the stabilization of RuBpy within the rigid MOF framework.

Authors:
 [1];  [2]; ;  [2]; ; ;  [1];  [1]
  1. State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Cyrus Tang Center for Sensor Materials and Applications, Zhejiang University, Hangzhou 310027 (China)
  2. The Key laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, National Engineering Lab for Textile Fiber Materials and Processing Technology (Zhejiang), College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018 (China)
Publication Date:
OSTI Identifier:
22475668
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 226; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CARBOXYLATION; COMPLEXES; EMISSION SPECTRA; LIFETIME; LUMINESCENCE; MOLECULES; ORGANOMETALLIC COMPOUNDS; PYRIDINES; RUTHENIUM COMPLEXES; RUTHENIUM COMPOUNDS; STABILIZATION; STEADY-STATE CONDITIONS; SURFACTANTS; SYNTHESIS; ZINC COMPOUNDS

Citation Formats

Xu, Hui, Gao, Junkuo, E-mail: jkgao@zstu.edu.cn, Wang, Jiangpeng, Qian, Xuefeng, Song, Ruijing, Cui, Yuanjing, Yang, Yu, and Qian, Guodong, E-mail: gdqian@zju.edu.cn. Surfactant-thermal method to synthesize a new Zn(II)-trimesic MOF with confined Ru(bpy){sub 3}{sup 2+} complex. United States: N. p., 2015. Web. doi:10.1016/J.JSSC.2015.03.012.
Xu, Hui, Gao, Junkuo, E-mail: jkgao@zstu.edu.cn, Wang, Jiangpeng, Qian, Xuefeng, Song, Ruijing, Cui, Yuanjing, Yang, Yu, & Qian, Guodong, E-mail: gdqian@zju.edu.cn. Surfactant-thermal method to synthesize a new Zn(II)-trimesic MOF with confined Ru(bpy){sub 3}{sup 2+} complex. United States. doi:10.1016/J.JSSC.2015.03.012.
Xu, Hui, Gao, Junkuo, E-mail: jkgao@zstu.edu.cn, Wang, Jiangpeng, Qian, Xuefeng, Song, Ruijing, Cui, Yuanjing, Yang, Yu, and Qian, Guodong, E-mail: gdqian@zju.edu.cn. Sun . "Surfactant-thermal method to synthesize a new Zn(II)-trimesic MOF with confined Ru(bpy){sub 3}{sup 2+} complex". United States. doi:10.1016/J.JSSC.2015.03.012.
@article{osti_22475668,
title = {Surfactant-thermal method to synthesize a new Zn(II)-trimesic MOF with confined Ru(bpy){sub 3}{sup 2+} complex},
author = {Xu, Hui and Gao, Junkuo, E-mail: jkgao@zstu.edu.cn and Wang, Jiangpeng and Qian, Xuefeng and Song, Ruijing and Cui, Yuanjing and Yang, Yu and Qian, Guodong, E-mail: gdqian@zju.edu.cn},
abstractNote = {A surfactant-thermal method was used to prepare a new zinc-1,3,5-benzentricarboxylate-based metal-organic framework (ZJU-100) with confined Ru(bpy){sub 3}{sup 2+} (RuBpy) complex by using surfactant PEG 400 as reaction medium. The RuBpy molecules were encapsulated between the 2-D sheets in ZJU-100. ZJU-100 showed bathochromic shift in the steady-state emission spectrum and increased emission lifetimes relative to RuBpy molecules. The extended lifetime is attributed to the reduced nonradiative decay rate due to the stabilization of RuBpy within the rigid MOF framework. These results represent the first example of MOF with confined complex synthesized by surfactant, indicating that the surfactant-thermal method could offer exciting opportunities for preparing new MOFs host/guest materials with novel structures and interesting luminescent properties. - Graphical abstract: A surfactant-thermal method was used to prepare a new zinc-1,3,5-benzentricarboxylate-based metal-organic framework (ZJU-100) with confined Ru(bpy){sub 3}{sup 2+} (RuBpy) complex by using surfactant PEG 400 as reaction medium. - Highlights: • Surfactant-thermal synthesis of crystalline metal-organic framework host/guest materials. • RuBpy molecules were encapsulated between the 2-D sheets of MOFs. • Extended lifetime is observed due to the stabilization of RuBpy within the rigid MOF framework.},
doi = {10.1016/J.JSSC.2015.03.012},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 226,
place = {United States},
year = {Sun Mar 15 00:00:00 EDT 2015},
month = {Sun Mar 15 00:00:00 EDT 2015}
}