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Title: Synthesis and characterization of pure STW-zeotype germanosilicate, Cu- and Co-substituted STW-zeotype materials

Abstract

Pure STW-type germanosilicate (denoted as GeSi-STW), Cu- and Co-containing STW-zeotype (denoted as Cu-STW and Co-STW) materials were synthesized by the hydrothermal method in the presence of an organic structure-directing agent (OSDA), N,N-diethylethylenediamine (DEEDA). The effects of the reaction mixture ratio and the incorporation of transition metals M (M=Cu and Co) on the synthesis of the pure product was investigated. The synthesized samples were characterized by powder and single-crystal X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma analysis (ICP), thermogravimetric and differential scanning calorimetry (TG–DSC) analysis and UV–vis diffuse reflectance spectra (DRS). The results reveal that the crystallization time, the concentration of H{sub 2}O in the reaction mixture and the addition of HF all have an important impact on the synthesis of pure STW-type zeolite. GeSi-STW is stable up to 800 °C, and has much higher thermal stability than SU-32 (stable to 400 °C). Co and Cu have been introduced for the first time into STW-zeotype materials. - Graphical abstract: SEM images of GeSi-STW (A and B), Co-STW (C and D) and Cu-STW (E and F). - Highlights: • Pure STW-type germanosilicate materials were hydrothermally synthesized. • The STW-type germanosilicate has high thermal stability up to 800 °C. •more » Co and Cu have been introduced for the first time in the STW-zeotype materials.« less

Authors:
 [1];  [1];  [1];  [1]; ;  [2]
  1. Shandong Provincial Key Laboratory of Fine Chemicals, Qilu University of Technology, Jinan 250353 (China)
  2. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
Publication Date:
OSTI Identifier:
22475604
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 225; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AMINES; CALORIMETRY; COBALT COMPOUNDS; CONCENTRATION RATIO; COPPER COMPOUNDS; CRYSTALLIZATION; GERMANIUM SILICIDES; HYDROFLUORIC ACID; HYDROTHERMAL SYNTHESIS; MONOCRYSTALS; POWDERS; SCANNING ELECTRON MICROSCOPY; SPECTRAL REFLECTANCE; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION; ZEOLITES

Citation Formats

Zhang, Na, Shi, Lei, E-mail: qg_shilei@163.com, Yu, Tingting, Li, Tianduo, E-mail: ylpt6296@vip.163.com, Hua, Wei, and Lin, Cong. Synthesis and characterization of pure STW-zeotype germanosilicate, Cu- and Co-substituted STW-zeotype materials. United States: N. p., 2015. Web. doi:10.1016/J.JSSC.2014.12.031.
Zhang, Na, Shi, Lei, E-mail: qg_shilei@163.com, Yu, Tingting, Li, Tianduo, E-mail: ylpt6296@vip.163.com, Hua, Wei, & Lin, Cong. Synthesis and characterization of pure STW-zeotype germanosilicate, Cu- and Co-substituted STW-zeotype materials. United States. doi:10.1016/J.JSSC.2014.12.031.
Zhang, Na, Shi, Lei, E-mail: qg_shilei@163.com, Yu, Tingting, Li, Tianduo, E-mail: ylpt6296@vip.163.com, Hua, Wei, and Lin, Cong. Fri . "Synthesis and characterization of pure STW-zeotype germanosilicate, Cu- and Co-substituted STW-zeotype materials". United States. doi:10.1016/J.JSSC.2014.12.031.
@article{osti_22475604,
title = {Synthesis and characterization of pure STW-zeotype germanosilicate, Cu- and Co-substituted STW-zeotype materials},
author = {Zhang, Na and Shi, Lei, E-mail: qg_shilei@163.com and Yu, Tingting and Li, Tianduo, E-mail: ylpt6296@vip.163.com and Hua, Wei and Lin, Cong},
abstractNote = {Pure STW-type germanosilicate (denoted as GeSi-STW), Cu- and Co-containing STW-zeotype (denoted as Cu-STW and Co-STW) materials were synthesized by the hydrothermal method in the presence of an organic structure-directing agent (OSDA), N,N-diethylethylenediamine (DEEDA). The effects of the reaction mixture ratio and the incorporation of transition metals M (M=Cu and Co) on the synthesis of the pure product was investigated. The synthesized samples were characterized by powder and single-crystal X-ray diffraction (XRD), scanning electron microscopy (SEM), inductively coupled plasma analysis (ICP), thermogravimetric and differential scanning calorimetry (TG–DSC) analysis and UV–vis diffuse reflectance spectra (DRS). The results reveal that the crystallization time, the concentration of H{sub 2}O in the reaction mixture and the addition of HF all have an important impact on the synthesis of pure STW-type zeolite. GeSi-STW is stable up to 800 °C, and has much higher thermal stability than SU-32 (stable to 400 °C). Co and Cu have been introduced for the first time into STW-zeotype materials. - Graphical abstract: SEM images of GeSi-STW (A and B), Co-STW (C and D) and Cu-STW (E and F). - Highlights: • Pure STW-type germanosilicate materials were hydrothermally synthesized. • The STW-type germanosilicate has high thermal stability up to 800 °C. • Co and Cu have been introduced for the first time in the STW-zeotype materials.},
doi = {10.1016/J.JSSC.2014.12.031},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 225,
place = {United States},
year = {2015},
month = {5}
}