Four unexpected lanthanide coordination polymers involving in situ reaction of solvent N, N-Dimethylformamide

Journal Article · Fri May 15 00:00:00 EDT 2015 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/J.JSSC.2014.12.026· OSTI ID:22475597

Jin, Jun-Cheng; Tong, Wen-Quan ^[1]; Fu, Ai-Yun ^[2]; Xie, Cheng-Gen; Chang, Wen-Gui; Wu, Ju ^[1]; Xu, Guang-Nian ^[1]; Zhang, Ya-Nan ^[3]; Li, Jun; Li, Yong; Yang, Peng-Qi ^[1]

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1. Technology Promotion Center of Nano Composite Material Preparation and Application, Anhui Provincial Laboratory of Biomimetic Sensor and Detecting Technology, West Anhui University, Lu’an, Anhui 237012 (China)
2. Shandong Collegial Key Laboratory of Biotechnology and Utilization of Biological Resources, College of Life Science, Dezhou University, Dezhou 253023, P.R.China (China)
3. College of Chemistry & Chemical Engineering, Shaanxi University of Science & Techology, Xi’an, Shaanxi, 710021 (China)

Four unexpected 2D lanthanide coordination polymers have been synthesized through in situ reactions of DMF solvent under solvothermal conditions. The isostructural complexes 1–3 contain four types of 2{sub 1} helical chains. While the Nd(III) ions are bridged through μ{sub 2}-HIDC{sup 2−} and oxalate to form a 2D sheet along the bc plane without helical character in 4. Therefore, complex 1 exhibits bright red solid-state phosphorescence upon exposure to UV radiation at room temperature. - Graphical abstract: Four unexpected 2D lanthanide coordination polymers have been synthesized through in situ reactions of solvent DMF to formate acid or oxalic acid under solvothermal conditions. The isostructural complexes 1–3 contain four types of different 2{sub 1} helical chains in the 2D layer and 1 exhibits bright red solid-state phosphorescence upon UV radiation. - Highlights: • Four unexpected 2D lanthanide coordination compounds have been synthesized through in situ reactions under solvothermal conditions. • The complexes 1–3 contain four types of 2{sub 1} helical chains in the layer. • Complex 1 exhibits bright red solid-state phosphorescence upon exposure to UV radiation at room temperature.

• OSTI ID: 22475597
• Journal Information: Journal of Solid State Chemistry, Vol. 225; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AMIDES
COORDINATION NUMBER
CRYSTALS
FLUORESCENCE
FORMATES
LAYERS
OXALATES
OXALIC ACID
PHOSPHORESCENCE
POLYMERS
RARE EARTH COMPLEXES
RARE EARTHS
SOLIDS
SOLVENTS
TEMPERATURE RANGE 0273-0400 K
ULTRAVIOLET RADIATION