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Title: Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers

Abstract

By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, ([Ln{sup III}Ag{sup I}(na)(ina)(ox)]·2(H{sub 2}O)){sub n} [Ln=Sm(1), Eu(2), Gd(3), Tb(4), Dy(5), Ho(6), Y(7), Yb(8)], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail. - Graphical abstract: Series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction which are featured by tetranuclear Ln{sub 2}Ag{sub 2} and ‘non-linear’ N–Ag–N linkages. - Highlights: • Complexes 1–8 are first built by three kinds of organic ligands based on nicotinic acid and isonicotinic acid. • PCPs 1–8 are featured by tetranuclear Ln{sub 2}Ag{sub 2} and ‘non-linear’ N–Ag–N linkages. • The total solvent-accessible volume of PCP 2 comprises 11.6% of the crystal volume after dislodging the free water molecules. • Complexes 2 and 4 exhibit characteristic lanthanide-centered luminescence, while compounds 3 and 5 show antiferromagnetic behaviors.

Authors:
 [1];  [2]; ; ;  [1];  [2];  [1];  [3];  [4]
  1. School of Chemistry and Environment, South China Normal University, Guangzhou 510006 (China)
  2. School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)
  3. (China)
  4. College of Science, South China Agricultural University, Guangzhou 510642 (China)
Publication Date:
OSTI Identifier:
22475572
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 225; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANTIFERROMAGNETISM; CRYSTALS; EMISSION SPECTROSCOPY; FOURIER TRANSFORMATION; HYDROTHERMAL SYNTHESIS; INFRARED SPECTRA; LAYERS; LUMINESCENCE; MAGNETIC PROPERTIES; MOLECULES; NICOTINIC ACID; ORGANIC POLYMERS; PH VALUE; POROUS MATERIALS; POWDERS; RARE EARTH COMPOUNDS; SOLVENTS; THERMAL GRAVIMETRIC ANALYSIS; THREE-DIMENSIONAL LATTICES; X-RAY DIFFRACTION

Citation Formats

Ran, Xing-Rui, Wang, Ning, Xie, Wei-Ping, Xiong, Yan-Ju, Cheng, Qian, Long, Yi, Yue, Shan-Tang, E-mail: yuesht@scnu.edu.cn, Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Guangzhou, and Liu, Ying-Liang. Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers. United States: N. p., 2015. Web. doi:10.1016/J.JSSC.2014.11.022.
Ran, Xing-Rui, Wang, Ning, Xie, Wei-Ping, Xiong, Yan-Ju, Cheng, Qian, Long, Yi, Yue, Shan-Tang, E-mail: yuesht@scnu.edu.cn, Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Guangzhou, & Liu, Ying-Liang. Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers. United States. doi:10.1016/J.JSSC.2014.11.022.
Ran, Xing-Rui, Wang, Ning, Xie, Wei-Ping, Xiong, Yan-Ju, Cheng, Qian, Long, Yi, Yue, Shan-Tang, E-mail: yuesht@scnu.edu.cn, Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Guangzhou, and Liu, Ying-Liang. Fri . "Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers". United States. doi:10.1016/J.JSSC.2014.11.022.
@article{osti_22475572,
title = {Syntheses, crystal structures and properties of series of 4d–4f ln(III)–Ag(I) heterometallic coordination polymers},
author = {Ran, Xing-Rui and Wang, Ning and Xie, Wei-Ping and Xiong, Yan-Ju and Cheng, Qian and Long, Yi and Yue, Shan-Tang, E-mail: yuesht@scnu.edu.cn and Guangzhou Key Laboratory of Materials for Energy Conversion and Storage, Guangzhou and Liu, Ying-Liang},
abstractNote = {By control of the experimental parameters such as ligands, pH value and reacting temperature, series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction, namely, ([Ln{sup III}Ag{sup I}(na)(ina)(ox)]·2(H{sub 2}O)){sub n} [Ln=Sm(1), Eu(2), Gd(3), Tb(4), Dy(5), Ho(6), Y(7), Yb(8)], have been successfully synthesized under hydrothermal conditions and structurally characterized. All the complexes are characterized by elemental analyses, FT-IR spectroscopy, Powder X-ray diffraction (PXRD) and thermogravimetric analyses (TGA). Furthermore, the luminescence properties of compounds 2 and 4 and the magsnetic properties of complexes 3 and 5 were also investigated in detail. - Graphical abstract: Series of three-dimensional (3D) 4d–4f Ln(III)–Ag(I) porous coordination polymers (PCPs) with interesting chain-layer construction which are featured by tetranuclear Ln{sub 2}Ag{sub 2} and ‘non-linear’ N–Ag–N linkages. - Highlights: • Complexes 1–8 are first built by three kinds of organic ligands based on nicotinic acid and isonicotinic acid. • PCPs 1–8 are featured by tetranuclear Ln{sub 2}Ag{sub 2} and ‘non-linear’ N–Ag–N linkages. • The total solvent-accessible volume of PCP 2 comprises 11.6% of the crystal volume after dislodging the free water molecules. • Complexes 2 and 4 exhibit characteristic lanthanide-centered luminescence, while compounds 3 and 5 show antiferromagnetic behaviors.},
doi = {10.1016/J.JSSC.2014.11.022},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 225,
place = {United States},
year = {2015},
month = {5}
}