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Title: Thermally induced formation of 2D hexagonal BN nanoplates with tunable characteristics

Abstract

We have investigated a thermally induced combustion route for preparing 2D hexagonal BN nanoplates from B{sub 2}O{sub 3}+(3+0.5k)Mg+kNH{sub 4}Cl solid system, for k=1–4 interval. Temperature–time profiles recorded by thermocouples indicated the existence of two sequential exothermic processes in the combustion wave leading to the BN nanoplates formation. The resulting BN nanoplates were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy, PL spectrometry, and Brunauer–Emmett–Teller surface area analysis. It was found that B{sub 2}O{sub 3} was converted into BN completely (by XRD) at 1450–1930 °C within tens of seconds in a single-step synthesis process. The BN prepared at a k=1–4 interval comprised well-shaped nanoplates with an average edge length ranging from 50 nm to several micrometer and thickness from 5 to 100 nm. The specific surface area of BN nanoplates was 13.7 g/m{sup 2} for k=2 and 28.4 m{sup 2}/g for k=4. - Graphical abstract: 2D hexagonal BN nanoplates with an average edge length ranging from 50 nm to several micrometer and thickness from 5 to 100 nm were prepared by combustion of B{sub 2}O{sub 3}+(3+0.5k)Mg+kNH{sub 4}Cl solid mixture in nitrogen atmosphere. - Highlights: • Thermally induced combustion route was developed for synthesizing BN nanoplates from B{sub 2}O{sub 3}. •more » Mg was used as reductive agent and NH{sub 4}Cl as an effective nitrogen source. • Temperature–time profiles and the combustion parameters were recorded and discussed. • BN with an average edge length from 50 nm to several micrometer and thickness from 5 to 100 nm were prepared. • Our study clarifies the formation mechanism of BN in the combustion wave.« less

Authors:
;  [1];  [2]; ; ;  [3];  [2];  [4];  [4]
  1. Graduate School of Department of Advanced Materials Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon (Korea, Republic of)
  2. Department of Nanomaterials Engineering, Chungnam National University, 99 Daehakro, Yuseong-gu, Daejeon (Korea, Republic of)
  3. Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeong (Korea, Republic of)
  4. (Korea, Republic of)
Publication Date:
OSTI Identifier:
22475570
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: 225; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AMMONIUM CHLORIDES; BORATES; BORON NITRIDES; BORON OXIDES; COMBUSTION; COMBUSTION WAVES; EMISSION SPECTROSCOPY; FIELD EMISSION; MIXTURES; NANOSTRUCTURES; NITROGEN; SCANNING ELECTRON MICROSCOPY; SOLIDS; SPECIFIC SURFACE AREA; SURFACE AREA; SYNTHESIS; X-RAY DIFFRACTION

Citation Formats

Nersisyan, Hayk, Lee, Tae-Hyuk, Lee, Kap-Ho, Jeong, Seong-Uk, Kang, Kyung-Soo, Bae, Ki-Kwang, Lee, Jong-Hyeon, E-mail: jonglee@cnu.ac.kr, Graduate School of Department of Advanced Materials Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, and Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon. Thermally induced formation of 2D hexagonal BN nanoplates with tunable characteristics. United States: N. p., 2015. Web. doi:10.1016/J.JSSC.2014.11.019.
Nersisyan, Hayk, Lee, Tae-Hyuk, Lee, Kap-Ho, Jeong, Seong-Uk, Kang, Kyung-Soo, Bae, Ki-Kwang, Lee, Jong-Hyeon, E-mail: jonglee@cnu.ac.kr, Graduate School of Department of Advanced Materials Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, & Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon. Thermally induced formation of 2D hexagonal BN nanoplates with tunable characteristics. United States. doi:10.1016/J.JSSC.2014.11.019.
Nersisyan, Hayk, Lee, Tae-Hyuk, Lee, Kap-Ho, Jeong, Seong-Uk, Kang, Kyung-Soo, Bae, Ki-Kwang, Lee, Jong-Hyeon, E-mail: jonglee@cnu.ac.kr, Graduate School of Department of Advanced Materials Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon, and Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon. Fri . "Thermally induced formation of 2D hexagonal BN nanoplates with tunable characteristics". United States. doi:10.1016/J.JSSC.2014.11.019.
@article{osti_22475570,
title = {Thermally induced formation of 2D hexagonal BN nanoplates with tunable characteristics},
author = {Nersisyan, Hayk and Lee, Tae-Hyuk and Lee, Kap-Ho and Jeong, Seong-Uk and Kang, Kyung-Soo and Bae, Ki-Kwang and Lee, Jong-Hyeon, E-mail: jonglee@cnu.ac.kr and Graduate School of Department of Advanced Materials Engineering, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon and Graduate School of Energy Science and Technology, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon},
abstractNote = {We have investigated a thermally induced combustion route for preparing 2D hexagonal BN nanoplates from B{sub 2}O{sub 3}+(3+0.5k)Mg+kNH{sub 4}Cl solid system, for k=1–4 interval. Temperature–time profiles recorded by thermocouples indicated the existence of two sequential exothermic processes in the combustion wave leading to the BN nanoplates formation. The resulting BN nanoplates were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy, PL spectrometry, and Brunauer–Emmett–Teller surface area analysis. It was found that B{sub 2}O{sub 3} was converted into BN completely (by XRD) at 1450–1930 °C within tens of seconds in a single-step synthesis process. The BN prepared at a k=1–4 interval comprised well-shaped nanoplates with an average edge length ranging from 50 nm to several micrometer and thickness from 5 to 100 nm. The specific surface area of BN nanoplates was 13.7 g/m{sup 2} for k=2 and 28.4 m{sup 2}/g for k=4. - Graphical abstract: 2D hexagonal BN nanoplates with an average edge length ranging from 50 nm to several micrometer and thickness from 5 to 100 nm were prepared by combustion of B{sub 2}O{sub 3}+(3+0.5k)Mg+kNH{sub 4}Cl solid mixture in nitrogen atmosphere. - Highlights: • Thermally induced combustion route was developed for synthesizing BN nanoplates from B{sub 2}O{sub 3}. • Mg was used as reductive agent and NH{sub 4}Cl as an effective nitrogen source. • Temperature–time profiles and the combustion parameters were recorded and discussed. • BN with an average edge length from 50 nm to several micrometer and thickness from 5 to 100 nm were prepared. • Our study clarifies the formation mechanism of BN in the combustion wave.},
doi = {10.1016/J.JSSC.2014.11.019},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = 225,
place = {United States},
year = {2015},
month = {5}
}