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Title: Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative

Abstract

Reaction of 2-(1-methyl-1,2-dihydroimidazol-3-yl)acetonitrile tetrafluoroborate with silver oxide in dichloromethane readily yields [Ag(DIM){sub 2}]BF{sub 4}, where DIM is 2-(1-methyl-1, 2-dihydroimidazol-3-yl)acetonitrile, representing a carbene organic ligand. The title compound was characterized by elemental analysis, IR, MS and single crystal X-ray diffraction. The crystal is of monoclinic system, space group C2/c with a = 14.010(18), b = 8.303(11), c = 14.936(20) Å, β = 93.910(4)°, V = 1639(4) Å{sup 3}, Z = 4, D{sub x} = 1.771 g/cm{sup 3}, F (000) = 864, µ(MoK{sub α}) = 1.278 mm{sup –1}. The final R{sup 1} = 0.0711 and wR{sup 2} = 0.1903 for reflections with I > 2σ(I). In addition, the preliminary biological test showed that the title compound had anti-fungus yeast activity.

Authors:
; ;  [1]
  1. Chemical Engineering College, Shaanxi University of Technology (China)
Publication Date:
OSTI Identifier:
22472049
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 60; Journal Issue: 7; Other Information: Copyright (c) 2015 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ACETONITRILE; FLUOROBORATES; INFRARED SPECTRA; IODINE COMPLEXES; LIGANDS; METHYLENE CHLORIDE; MONOCLINIC LATTICES; MONOCRYSTALS; REFLECTION; SILVER; SILVER OXIDES; SYNTHESIS; X-RAY DIFFRACTION

Citation Formats

Jiu-Fu, Lu, E-mail: jiufulu@163.com, Hong-Guang, Ge, and Juan, Shi. Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative. United States: N. p., 2015. Web. doi:10.1134/S1063774515070159.
Jiu-Fu, Lu, E-mail: jiufulu@163.com, Hong-Guang, Ge, & Juan, Shi. Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative. United States. doi:10.1134/S1063774515070159.
Jiu-Fu, Lu, E-mail: jiufulu@163.com, Hong-Guang, Ge, and Juan, Shi. Tue . "Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative". United States. doi:10.1134/S1063774515070159.
@article{osti_22472049,
title = {Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative},
author = {Jiu-Fu, Lu, E-mail: jiufulu@163.com and Hong-Guang, Ge and Juan, Shi},
abstractNote = {Reaction of 2-(1-methyl-1,2-dihydroimidazol-3-yl)acetonitrile tetrafluoroborate with silver oxide in dichloromethane readily yields [Ag(DIM){sub 2}]BF{sub 4}, where DIM is 2-(1-methyl-1, 2-dihydroimidazol-3-yl)acetonitrile, representing a carbene organic ligand. The title compound was characterized by elemental analysis, IR, MS and single crystal X-ray diffraction. The crystal is of monoclinic system, space group C2/c with a = 14.010(18), b = 8.303(11), c = 14.936(20) Å, β = 93.910(4)°, V = 1639(4) Å{sup 3}, Z = 4, D{sub x} = 1.771 g/cm{sup 3}, F (000) = 864, µ(MoK{sub α}) = 1.278 mm{sup –1}. The final R{sup 1} = 0.0711 and wR{sup 2} = 0.1903 for reflections with I > 2σ(I). In addition, the preliminary biological test showed that the title compound had anti-fungus yeast activity.},
doi = {10.1134/S1063774515070159},
journal = {Crystallography Reports},
number = 7,
volume = 60,
place = {United States},
year = {Tue Dec 15 00:00:00 EST 2015},
month = {Tue Dec 15 00:00:00 EST 2015}
}