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Title: Synthesis, crystal structure and optical property of three coordination polymer constructed from m-phenylenediacrylate acid

Abstract

Three new complexes of the wholly deprotonated flexible ligand m-phenylenediacrylate acid (H{sub 2}mpda), namely, [Zn (mpda) (H{sub 2}O)] [1], [Pr{sub 2}(mpda){sub 2}(H{sub 2}O){sub 2}(CHOO){sub 2}] [2], and [Mn{sub 2}(mpda){sub 2} (H{sub 2}O){sub 4}] [3], were synthesized by the solvothermal reaction. The complexes were characterized by IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. A mixed sample [Nd(mpda)(H{sub 2}O)(CHOO)·Pr(mpda)(H{sub 2}O)(CHOO)] [2{sup ]} was also synthesized and studied. Compounds [1] and [2] exhibit a selective sensing function with respect to acetone, and they are a potential luminescent sensory material for the selective detection of Zn{sup 2+} and Ni{sup 2+} ions, respectively. Furthermore, the fluorescent changes of compound [1] upon the addition of cations (Fe{sup 3+} and Zn{sup 2+}, Bi{sup 2+} and Zn{sup 2+}) are utilized to construct two logic gates at the molecular level. - Graphical abstract: Three new complexes of flexible ligand m-phenylenedicarboxylic acid were synthesized by solvothermal reaction. Three metal−organic frameworks exhibiting 1D, 2D, 3D structures, respectively. - Highlights: • Three new complexes of m-phenylenedicarboxylic acid were synthesized. • Three metal−organic frameworks exhibiting 1D, 2D, 3D structures, respectively. • [1] and [2] exhibits a very high quenching effect with acetone. • [1] and [2] are a potential luminescent sensory materialmore » for Zn{sup 2+}, Ni{sup 2+} ions. • Two logic gates have been constructed using compound [1].« less

Authors:
; ;
Publication Date:
OSTI Identifier:
22443476
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 221; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACETONE; CATIONS; CRYSTAL STRUCTURE; DETECTION; FLUORESCENCE; INFRARED SPECTRA; IRON IONS; LIGANDS; MONOCRYSTALS; NICKEL IONS; OPTICAL PROPERTIES; POLYMERS; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; WATER; X-RAY DIFFRACTION; ZINC IONS

Citation Formats

Xiao, YiFan, Wang, TingTing, and Zeng, HePing, E-mail: hpzeng@scut.edu.cn. Synthesis, crystal structure and optical property of three coordination polymer constructed from m-phenylenediacrylate acid. United States: N. p., 2015. Web. doi:10.1016/J.JSSC.2014.09.015.
Xiao, YiFan, Wang, TingTing, & Zeng, HePing, E-mail: hpzeng@scut.edu.cn. Synthesis, crystal structure and optical property of three coordination polymer constructed from m-phenylenediacrylate acid. United States. doi:10.1016/J.JSSC.2014.09.015.
Xiao, YiFan, Wang, TingTing, and Zeng, HePing, E-mail: hpzeng@scut.edu.cn. Thu . "Synthesis, crystal structure and optical property of three coordination polymer constructed from m-phenylenediacrylate acid". United States. doi:10.1016/J.JSSC.2014.09.015.
@article{osti_22443476,
title = {Synthesis, crystal structure and optical property of three coordination polymer constructed from m-phenylenediacrylate acid},
author = {Xiao, YiFan and Wang, TingTing and Zeng, HePing, E-mail: hpzeng@scut.edu.cn},
abstractNote = {Three new complexes of the wholly deprotonated flexible ligand m-phenylenediacrylate acid (H{sub 2}mpda), namely, [Zn (mpda) (H{sub 2}O)] [1], [Pr{sub 2}(mpda){sub 2}(H{sub 2}O){sub 2}(CHOO){sub 2}] [2], and [Mn{sub 2}(mpda){sub 2} (H{sub 2}O){sub 4}] [3], were synthesized by the solvothermal reaction. The complexes were characterized by IR spectroscopy, thermogravimetric analysis, and X-ray single-crystal diffraction. A mixed sample [Nd(mpda)(H{sub 2}O)(CHOO)·Pr(mpda)(H{sub 2}O)(CHOO)] [2{sup ]} was also synthesized and studied. Compounds [1] and [2] exhibit a selective sensing function with respect to acetone, and they are a potential luminescent sensory material for the selective detection of Zn{sup 2+} and Ni{sup 2+} ions, respectively. Furthermore, the fluorescent changes of compound [1] upon the addition of cations (Fe{sup 3+} and Zn{sup 2+}, Bi{sup 2+} and Zn{sup 2+}) are utilized to construct two logic gates at the molecular level. - Graphical abstract: Three new complexes of flexible ligand m-phenylenedicarboxylic acid were synthesized by solvothermal reaction. Three metal−organic frameworks exhibiting 1D, 2D, 3D structures, respectively. - Highlights: • Three new complexes of m-phenylenedicarboxylic acid were synthesized. • Three metal−organic frameworks exhibiting 1D, 2D, 3D structures, respectively. • [1] and [2] exhibits a very high quenching effect with acetone. • [1] and [2] are a potential luminescent sensory material for Zn{sup 2+}, Ni{sup 2+} ions. • Two logic gates have been constructed using compound [1].},
doi = {10.1016/J.JSSC.2014.09.015},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 221,
place = {United States},
year = {Thu Jan 15 00:00:00 EST 2015},
month = {Thu Jan 15 00:00:00 EST 2015}
}