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Title: Permeation of hydrogen in hastelloy C-276 alloy at high temperature

Journal Article · · Fusion Science and Technology
DOI:https://doi.org/10.13182/FST14-T109· OSTI ID:22429796
; ;  [1];  [2]
  1. Shanghai Institute of Applied Physics, Jiading District, Shanghai (China)
  2. Nuclear and Radiation Safety Center, Haidian District, Beijing (China)

Tritium is generated by the interaction of neutrons with the lithium and beryllium in the molten salt reactors (MSRs), which use FLiBe as one of solvents of fluoride fuel. Tritium as by-product in the MSRs is an important safety issue because it could easily diffuse into environment through high temperature heat exchangers. The experimental technique of gas driven permeation has been used to investigate the transport parameter of hydrogen in Hastelloy C-276 which is considered as one of the candidate for structure materials. The measurements were carried out at the temperature range of 400-800 Celsius degrees with hydrogen loading pressures ranging from 5*10{sup 3} to 4*10{sup 4} Pa. The H diffusive transport parameters for Hastelloy C-276 follow an Arrhenius law in this temperature range. Regarding diffusivity and Sieverts' constant, Hastelloy C-276 has lower values compared with Ni201 alloy. The possible reason may be the trapping effects, which were formed by the alloying elements of Mo and Cr in the matrix. At the same time, the thin oxidation layer formed by the high Cr content could lead to a slower dissociation process of H{sub 2} at the surface. (authors)

OSTI ID:
22429796
Journal Information:
Fusion Science and Technology, Vol. 67, Issue 3; Conference: TRITIUM 2013: 10. International Conference on Tritium Science and Technology, Nice Acropolis (France), 21-25 Oct 2013; Other Information: Country of input: France; 16 refs.; ISSN 1536-1055
Country of Publication:
United States
Language:
English