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Title: Investigation of hydrogen isotope exchange reaction rate in mixed gas (H{sub 2} and D{sub 2}) at pressure up to 200 MPa using Raman spectroscopy

Abstract

Raman spectroscopy is a relevant method for obtaining objective data on isotopic exchange rate in a gaseous mix of hydrogen isotopes, since it allows one to determine a gaseous mix composition in real time without sampling. We have developed a high-pressure fiber-optic probe to be used for obtaining protium Raman spectra under pressures up to 400 MPa and we have recorded spectral line broadening induced by molecule collisions starting from ∼ 40 MPa. Using this fiber-optic probe we have performed experiments to study isotopic exchange kinetics in a gaseous mix of hydrogen isotopes (protium-deuterium) at pressures up to 200 MPa. Preliminary results show that the dependence of the average isotopic exchange rate related to pressure take unexpected values at the very beginning of the time evolution. More work is required to understand this inconsistency.

Authors:
; ; ;  [1]
  1. Russian Federal Nuclear Center, All-Russian Research Institute of Experimental Physics, Sarov (Russian Federation)
Publication Date:
OSTI Identifier:
22429779
Resource Type:
Journal Article
Resource Relation:
Journal Name: Fusion Science and Technology; Journal Volume: 67; Journal Issue: 3; Conference: TRITIUM 2013: 10. International Conference on Tritium Science and Technology, Nice Acropolis (France), 21-25 Oct 2013; Other Information: Country of input: France; 7 refs.
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; 07 ISOTOPES AND RADIATION SOURCES; DEUTERIUM; HYDROGEN; HYDROGEN 1; ISOTOPIC EXCHANGE; LINE BROADENING; MOLECULE COLLISIONS; PRESSURE RANGE MEGA PA 100-1000; RAMAN SPECTRA; RAMAN SPECTROSCOPY; REACTION KINETICS

Citation Formats

Tikhonov, V.V., Yukhimchuk, A.A., Musyayev, R.K., and Gurkin, A.I. Investigation of hydrogen isotope exchange reaction rate in mixed gas (H{sub 2} and D{sub 2}) at pressure up to 200 MPa using Raman spectroscopy. United States: N. p., 2015. Web. doi:10.13182/FST14-T92.
Tikhonov, V.V., Yukhimchuk, A.A., Musyayev, R.K., & Gurkin, A.I. Investigation of hydrogen isotope exchange reaction rate in mixed gas (H{sub 2} and D{sub 2}) at pressure up to 200 MPa using Raman spectroscopy. United States. doi:10.13182/FST14-T92.
Tikhonov, V.V., Yukhimchuk, A.A., Musyayev, R.K., and Gurkin, A.I. Sun . "Investigation of hydrogen isotope exchange reaction rate in mixed gas (H{sub 2} and D{sub 2}) at pressure up to 200 MPa using Raman spectroscopy". United States. doi:10.13182/FST14-T92.
@article{osti_22429779,
title = {Investigation of hydrogen isotope exchange reaction rate in mixed gas (H{sub 2} and D{sub 2}) at pressure up to 200 MPa using Raman spectroscopy},
author = {Tikhonov, V.V. and Yukhimchuk, A.A. and Musyayev, R.K. and Gurkin, A.I.},
abstractNote = {Raman spectroscopy is a relevant method for obtaining objective data on isotopic exchange rate in a gaseous mix of hydrogen isotopes, since it allows one to determine a gaseous mix composition in real time without sampling. We have developed a high-pressure fiber-optic probe to be used for obtaining protium Raman spectra under pressures up to 400 MPa and we have recorded spectral line broadening induced by molecule collisions starting from ∼ 40 MPa. Using this fiber-optic probe we have performed experiments to study isotopic exchange kinetics in a gaseous mix of hydrogen isotopes (protium-deuterium) at pressures up to 200 MPa. Preliminary results show that the dependence of the average isotopic exchange rate related to pressure take unexpected values at the very beginning of the time evolution. More work is required to understand this inconsistency.},
doi = {10.13182/FST14-T92},
journal = {Fusion Science and Technology},
number = 3,
volume = 67,
place = {United States},
year = {Sun Mar 15 00:00:00 EDT 2015},
month = {Sun Mar 15 00:00:00 EDT 2015}
}