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Title: High resolution electronic spectroscopy of the A {sup 2}Σ{sup −} − X {sup 2}Π{sub 1/2} transition of PtN

Abstract

The (2,0) vibrational band of the A {sup 2}Σ{sup −} − X {sup 2}Π{sub 1/2} transition of platinum nitride, PtN, was recorded at Doppler-limited resolution using intracavity laser absorption spectroscopy (ILS) and at sub-Doppler resolution using molecular beam laser induced fluorescence (LIF) spectroscopy. Isotopologue structure for {sup 194}PtN, {sup 195}PtN, and {sup 196}PtN, magnetic hyperfine splitting due to {sup 195}Pt (I = ½), and nuclear quadrupole splitting due to {sup 14}N (I = 1) were observed in the spectrum. Molecular constants for the ground and excited states are derived. The hyperfine interactions are used to illuminate the nature of the A {sup 2}Σ{sup −} excited electronic state.

Authors:
;  [1]; ;  [2]; ;  [3]
  1. Department of Chemistry, Southern Illinois University, Edwardsville, Illinois 62026-1652 (United States)
  2. Department of Chemistry and Biochemistry and Center for Nanoscience, University of Missouri, St. Louis, Missouri 63121-4400 (United States)
  3. Department of Chemistry, Arizona State University, Tempe, Arizona 96287-1604 (United States)
Publication Date:
OSTI Identifier:
22419827
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Chemical Physics; Journal Volume: 141; Journal Issue: 8; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; FLUORESCENCE; INTERACTIONS; LITHIUM FLUORIDES; MOLECULAR BEAMS; PLATINUM; PLATINUM 195; SPECTRA; VIBRATIONAL STATES

Citation Formats

Womack, Kaitlin, O’Brien, Leah C., E-mail: lobrien@siue.edu, Whittemore, Sean, O’Brien, James J., Le, Anh, and Steimle, Timothy C. High resolution electronic spectroscopy of the A {sup 2}Σ{sup −} − X {sup 2}Π{sub 1/2} transition of PtN. United States: N. p., 2014. Web. doi:10.1063/1.4893703.
Womack, Kaitlin, O’Brien, Leah C., E-mail: lobrien@siue.edu, Whittemore, Sean, O’Brien, James J., Le, Anh, & Steimle, Timothy C. High resolution electronic spectroscopy of the A {sup 2}Σ{sup −} − X {sup 2}Π{sub 1/2} transition of PtN. United States. doi:10.1063/1.4893703.
Womack, Kaitlin, O’Brien, Leah C., E-mail: lobrien@siue.edu, Whittemore, Sean, O’Brien, James J., Le, Anh, and Steimle, Timothy C. Thu . "High resolution electronic spectroscopy of the A {sup 2}Σ{sup −} − X {sup 2}Π{sub 1/2} transition of PtN". United States. doi:10.1063/1.4893703.
@article{osti_22419827,
title = {High resolution electronic spectroscopy of the A {sup 2}Σ{sup −} − X {sup 2}Π{sub 1/2} transition of PtN},
author = {Womack, Kaitlin and O’Brien, Leah C., E-mail: lobrien@siue.edu and Whittemore, Sean and O’Brien, James J. and Le, Anh and Steimle, Timothy C.},
abstractNote = {The (2,0) vibrational band of the A {sup 2}Σ{sup −} − X {sup 2}Π{sub 1/2} transition of platinum nitride, PtN, was recorded at Doppler-limited resolution using intracavity laser absorption spectroscopy (ILS) and at sub-Doppler resolution using molecular beam laser induced fluorescence (LIF) spectroscopy. Isotopologue structure for {sup 194}PtN, {sup 195}PtN, and {sup 196}PtN, magnetic hyperfine splitting due to {sup 195}Pt (I = ½), and nuclear quadrupole splitting due to {sup 14}N (I = 1) were observed in the spectrum. Molecular constants for the ground and excited states are derived. The hyperfine interactions are used to illuminate the nature of the A {sup 2}Σ{sup −} excited electronic state.},
doi = {10.1063/1.4893703},
journal = {Journal of Chemical Physics},
number = 8,
volume = 141,
place = {United States},
year = {Thu Aug 28 00:00:00 EDT 2014},
month = {Thu Aug 28 00:00:00 EDT 2014}
}