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Title: Structural phases driven by oxygen vacancies at the La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/SrTiO{sub 3} hetero-interface

Abstract

An oxygen vacancy driven structural response at the epitaxial interface between La{sub 0.7}Sr{sub 0.3}MnO{sub 3} films and SrTiO{sub 3} substrates is reported. A combined scanning transmission electron microscopy and electron energy loss spectroscopy study reveal the presence of an elongated out-of-plane lattice parameter, coupled to oxygen vacancies and reduced manganese oxidation state at the La{sub 0.7}Sr{sub 0.3}MnO{sub 3} side of the interface. Density functional theory calculations support that the measured interface structure is a disordered oxygen deficient brownmillerite structure. The effect of oxygen vacancy mobility is assessed, revealing an ordering of the vacancies with time.

Authors:
;  [1];  [1];  [2]; ; ;  [3];  [4]
  1. Department of Physics, NTNU, 7491 Trondheim (Norway)
  2. (Norway)
  3. Department of Electronics and Telecommunications, NTNU, 7491 Trondheim (Norway)
  4. Department of Materials Science and Engineering, NTNU, 7491 Trondheim (Norway)
Publication Date:
OSTI Identifier:
22415180
Resource Type:
Journal Article
Resource Relation:
Journal Name: Applied Physics Letters; Journal Volume: 106; Journal Issue: 4; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; DENSITY FUNCTIONAL METHOD; ELECTRONS; ENERGY-LOSS SPECTROSCOPY; EPITAXY; FILMS; INTERFACES; LANTHANUM; LATTICE PARAMETERS; MANGANESE; MANGANESE OXIDES; OXYGEN; STRONTIUM; STRONTIUM TITANATES; SUBSTRATES; TRANSMISSION ELECTRON MICROSCOPY; VACANCIES

Citation Formats

Nord, M., Holmestad, R., Vullum, P. E., Materials and Chemistry, SINTEF, 7465 Trondheim, Moreau, M., Boschker, J. E., Tybell, T., E-mail: thomas.tybell@iet.ntnu.no, and Selbach, S. M. Structural phases driven by oxygen vacancies at the La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/SrTiO{sub 3} hetero-interface. United States: N. p., 2015. Web. doi:10.1063/1.4906920.
Nord, M., Holmestad, R., Vullum, P. E., Materials and Chemistry, SINTEF, 7465 Trondheim, Moreau, M., Boschker, J. E., Tybell, T., E-mail: thomas.tybell@iet.ntnu.no, & Selbach, S. M. Structural phases driven by oxygen vacancies at the La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/SrTiO{sub 3} hetero-interface. United States. doi:10.1063/1.4906920.
Nord, M., Holmestad, R., Vullum, P. E., Materials and Chemistry, SINTEF, 7465 Trondheim, Moreau, M., Boschker, J. E., Tybell, T., E-mail: thomas.tybell@iet.ntnu.no, and Selbach, S. M. Mon . "Structural phases driven by oxygen vacancies at the La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/SrTiO{sub 3} hetero-interface". United States. doi:10.1063/1.4906920.
@article{osti_22415180,
title = {Structural phases driven by oxygen vacancies at the La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/SrTiO{sub 3} hetero-interface},
author = {Nord, M. and Holmestad, R. and Vullum, P. E. and Materials and Chemistry, SINTEF, 7465 Trondheim and Moreau, M. and Boschker, J. E. and Tybell, T., E-mail: thomas.tybell@iet.ntnu.no and Selbach, S. M.},
abstractNote = {An oxygen vacancy driven structural response at the epitaxial interface between La{sub 0.7}Sr{sub 0.3}MnO{sub 3} films and SrTiO{sub 3} substrates is reported. A combined scanning transmission electron microscopy and electron energy loss spectroscopy study reveal the presence of an elongated out-of-plane lattice parameter, coupled to oxygen vacancies and reduced manganese oxidation state at the La{sub 0.7}Sr{sub 0.3}MnO{sub 3} side of the interface. Density functional theory calculations support that the measured interface structure is a disordered oxygen deficient brownmillerite structure. The effect of oxygen vacancy mobility is assessed, revealing an ordering of the vacancies with time.},
doi = {10.1063/1.4906920},
journal = {Applied Physics Letters},
number = 4,
volume = 106,
place = {United States},
year = {Mon Jan 26 00:00:00 EST 2015},
month = {Mon Jan 26 00:00:00 EST 2015}
}