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Title: Low temperature structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} single crystal: Evidences from optical ellipsometry and Raman scattering

Abstract

Optical properties and structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} (NBT-7%BT) single crystal have been studied by temperature-dependent optical ellipsometry and Raman spectroscopy from 4.2 to 300 K. The second derivative of the complex dielectric functions reveals two interband transitions (E{sub cp1} and E{sub cp2}) located at about 3.49 and 4.25 eV, respectively. Depending on the temperature evolution of electronic transitions, structural variations appear near 60, 150, and 240 K, respectively. These anomalies are also well illustrated from the low-frequency phonon modes involving vibrations of Bi. The low-temperature structural variations of NBT-7%BT crystal can be associated with instability of the crystalline lattice driven by off-centered Bi ions, followed by the variations of polarizability of the unit cells.

Authors:
; ; ;  [1]; ;  [2]
  1. Key Laboratory of Polar Materials and Devices, Ministry of Education, Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China)
  2. Key Laboratory of Inorganic Functional Materials and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800 (China)
Publication Date:
OSTI Identifier:
22412920
Resource Type:
Journal Article
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 117; Journal Issue: 22; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-8979
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; BARIUM COMPOUNDS; BISMUTH COMPOUNDS; BISMUTH IONS; CRYSTAL LATTICES; DIELECTRIC MATERIALS; ELLIPSOMETRY; ENERGY-LEVEL TRANSITIONS; MONOCRYSTALS; OPTICAL PROPERTIES; PERMITTIVITY; PHONONS; POLARIZABILITY; RAMAN SPECTROSCOPY; SODIUM COMPOUNDS; TEMPERATURE DEPENDENCE; TITANATES

Citation Formats

Huang, T., Guo, S., Xu, L. P., Hu, Z. G., E-mail: zghu@ee.ecnu.edu.cn, Chu, J. H., Chen, C., and Luo, H. S. Low temperature structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} single crystal: Evidences from optical ellipsometry and Raman scattering. United States: N. p., 2015. Web. doi:10.1063/1.4922424.
Huang, T., Guo, S., Xu, L. P., Hu, Z. G., E-mail: zghu@ee.ecnu.edu.cn, Chu, J. H., Chen, C., & Luo, H. S. Low temperature structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} single crystal: Evidences from optical ellipsometry and Raman scattering. United States. https://doi.org/10.1063/1.4922424
Huang, T., Guo, S., Xu, L. P., Hu, Z. G., E-mail: zghu@ee.ecnu.edu.cn, Chu, J. H., Chen, C., and Luo, H. S. Sun . "Low temperature structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} single crystal: Evidences from optical ellipsometry and Raman scattering". United States. https://doi.org/10.1063/1.4922424.
@article{osti_22412920,
title = {Low temperature structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} single crystal: Evidences from optical ellipsometry and Raman scattering},
author = {Huang, T. and Guo, S. and Xu, L. P. and Hu, Z. G., E-mail: zghu@ee.ecnu.edu.cn and Chu, J. H. and Chen, C. and Luo, H. S.},
abstractNote = {Optical properties and structural variations of Na{sub 0.5}Bi{sub 0.5}TiO{sub 3}-7%BaTiO{sub 3} (NBT-7%BT) single crystal have been studied by temperature-dependent optical ellipsometry and Raman spectroscopy from 4.2 to 300 K. The second derivative of the complex dielectric functions reveals two interband transitions (E{sub cp1} and E{sub cp2}) located at about 3.49 and 4.25 eV, respectively. Depending on the temperature evolution of electronic transitions, structural variations appear near 60, 150, and 240 K, respectively. These anomalies are also well illustrated from the low-frequency phonon modes involving vibrations of Bi. The low-temperature structural variations of NBT-7%BT crystal can be associated with instability of the crystalline lattice driven by off-centered Bi ions, followed by the variations of polarizability of the unit cells.},
doi = {10.1063/1.4922424},
url = {https://www.osti.gov/biblio/22412920}, journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 22,
volume = 117,
place = {United States},
year = {2015},
month = {6}
}