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Title: Magnetism switching and band-gap narrowing in Ni-doped PbTiO{sub 3} thin films

Abstract

Ions doping-driven structural phase transition accompanied by magnetism switching and band-gap narrowing effects has been observed in PbTi{sub 1−x}Ni{sub x}O{sub 3−δ} (xPTNO, x = 0.00, 0.06, and 0.33) thin films. With the increase of x, the xPTNO thin films exhibit not only a phase transition from the pseudotetragonal structure to a centrosymmetric cubic structure but also a drastic decrease of grain size. Moreover, the as-grown Ni-doped PbTiO{sub 3} (PTO) thin films show obvious room-temperature ferromagnetism and an increased saturation magnetization with increasing the Ni content, in contrast to undoped PTO, which shows diamagnetism. A bound magnetic polaron model was proposed to understand the observed ferromagnetic behavior of PTO-derived perovskite thin films. Furthermore, the 0.33PTNO thin film presents a narrowed band-gap, much smaller than that of PTO, which is attributed to new states of both the highest occupied molecular orbital and the lowest unoccupied molecular orbital in an electronic structure with the presence of Ni. These findings may open up a route to explore promising perovskite oxides as candidate materials for use in multiferroics and solar-energy devices.

Authors:
; ; ;  [1];  [2]
  1. Key Laboratory of Polar Materials and Devices, Ministry of Education, Department of Electronic Engineering, East China Normal University, Shanghai 200241 (China)
  2. Instrumental Analysis and Research Center, Institute of Materials, Shanghai University, 99 Shangda Road, Shanghai 200444 (China)
Publication Date:
OSTI Identifier:
22410214
Resource Type:
Journal Article
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 117; Journal Issue: 19; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-8979
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CONCENTRATION RATIO; DIAMAGNETISM; DOPED MATERIALS; ELECTRONIC STRUCTURE; ENERGY GAP; FERROMAGNETISM; GRAIN SIZE; LEAD COMPOUNDS; MAGNETIZATION; MOLECULAR ORBITAL METHOD; NICKEL COMPOUNDS; PHASE TRANSFORMATIONS; SOLAR ENERGY; TEMPERATURE RANGE 0273-0400 K; THIN FILMS; TITANATES

Citation Formats

Zhou, Wenliang, Yu, Lu, Yang, Pingxiong, E-mail: pxyang@ee.ecnu.edu.cn, Chu, Junhao, and Deng, Hongmei. Magnetism switching and band-gap narrowing in Ni-doped PbTiO{sub 3} thin films. United States: N. p., 2015. Web. doi:10.1063/1.4921459.
Zhou, Wenliang, Yu, Lu, Yang, Pingxiong, E-mail: pxyang@ee.ecnu.edu.cn, Chu, Junhao, & Deng, Hongmei. Magnetism switching and band-gap narrowing in Ni-doped PbTiO{sub 3} thin films. United States. doi:10.1063/1.4921459.
Zhou, Wenliang, Yu, Lu, Yang, Pingxiong, E-mail: pxyang@ee.ecnu.edu.cn, Chu, Junhao, and Deng, Hongmei. Thu . "Magnetism switching and band-gap narrowing in Ni-doped PbTiO{sub 3} thin films". United States. doi:10.1063/1.4921459.
@article{osti_22410214,
title = {Magnetism switching and band-gap narrowing in Ni-doped PbTiO{sub 3} thin films},
author = {Zhou, Wenliang and Yu, Lu and Yang, Pingxiong, E-mail: pxyang@ee.ecnu.edu.cn and Chu, Junhao and Deng, Hongmei},
abstractNote = {Ions doping-driven structural phase transition accompanied by magnetism switching and band-gap narrowing effects has been observed in PbTi{sub 1−x}Ni{sub x}O{sub 3−δ} (xPTNO, x = 0.00, 0.06, and 0.33) thin films. With the increase of x, the xPTNO thin films exhibit not only a phase transition from the pseudotetragonal structure to a centrosymmetric cubic structure but also a drastic decrease of grain size. Moreover, the as-grown Ni-doped PbTiO{sub 3} (PTO) thin films show obvious room-temperature ferromagnetism and an increased saturation magnetization with increasing the Ni content, in contrast to undoped PTO, which shows diamagnetism. A bound magnetic polaron model was proposed to understand the observed ferromagnetic behavior of PTO-derived perovskite thin films. Furthermore, the 0.33PTNO thin film presents a narrowed band-gap, much smaller than that of PTO, which is attributed to new states of both the highest occupied molecular orbital and the lowest unoccupied molecular orbital in an electronic structure with the presence of Ni. These findings may open up a route to explore promising perovskite oxides as candidate materials for use in multiferroics and solar-energy devices.},
doi = {10.1063/1.4921459},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 19,
volume = 117,
place = {United States},
year = {2015},
month = {5}
}