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Title: Superparamagnetic properties of carbon nanotubes filled with NiFe{sub 2}O{sub 4} nanoparticles

Abstract

Multi walled carbon nanotubes (MWCNTs) were successfully synthesized using custom-made 80 nm pore-size alumina templates, and were uniformly filled with nickel ferrite (NFO) nanoparticles of 7.4 ± 1.7 nm diameter using a novel magnetically assisted capillary action method. X-ray diffraction confirmed the inverse spinel phase for the synthesized NFO. Transmission electron microscopy confirms spherical NFO nanoparticles with an average diameter of 7.4 nm inside MWCNTs. Magnetometry indicates that both NFO and NFO-filled MWCNTs present a blocking temperature around 52 K, with similar superparamagnetic-like behavior, and weak dipolar interactions, giving rise to a super-spin-glass-like behavior at low temperatures. These properties along with the uniformity of sub-100 nm structures and the possibility of tunable magnetic response in variable diameter carbon nanotubes make them ideal for advanced biomedical and microwave applications.

Authors:
; ; ;  [1];  [1];  [2]; ;  [3]
  1. Department of Physics, University of South Florida, Tampa, Florida 33620 (United States)
  2. (Spain)
  3. Instituto de Ciencia de Materiales de Madrid, CSIC, 28049 Madrid (Spain)
Publication Date:
OSTI Identifier:
22410027
Resource Type:
Journal Article
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 117; Journal Issue: 17; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-8979
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; ALUMINIUM OXIDES; CARBON NANOTUBES; CHANNELING; FERRITES; MICROWAVE RADIATION; NANOPARTICLES; NICKEL COMPOUNDS; SPHERICAL CONFIGURATION; SPIN GLASS STATE; SUPERPARAMAGNETISM; TEMPERATURE DEPENDENCE; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION

Citation Formats

Stojak Repa, K., Israel, D., Phan, M. H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu, Srikanth, H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu, Alonso, J., BCMaterials Edificio No. 500, Parque Tecnológico de Vizcaya, 48160 Derio, Palmero, E. M., and Vazquez, M. Superparamagnetic properties of carbon nanotubes filled with NiFe{sub 2}O{sub 4} nanoparticles. United States: N. p., 2015. Web. doi:10.1063/1.4914952.
Stojak Repa, K., Israel, D., Phan, M. H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu, Srikanth, H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu, Alonso, J., BCMaterials Edificio No. 500, Parque Tecnológico de Vizcaya, 48160 Derio, Palmero, E. M., & Vazquez, M. Superparamagnetic properties of carbon nanotubes filled with NiFe{sub 2}O{sub 4} nanoparticles. United States. doi:10.1063/1.4914952.
Stojak Repa, K., Israel, D., Phan, M. H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu, Srikanth, H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu, Alonso, J., BCMaterials Edificio No. 500, Parque Tecnológico de Vizcaya, 48160 Derio, Palmero, E. M., and Vazquez, M. Thu . "Superparamagnetic properties of carbon nanotubes filled with NiFe{sub 2}O{sub 4} nanoparticles". United States. doi:10.1063/1.4914952.
@article{osti_22410027,
title = {Superparamagnetic properties of carbon nanotubes filled with NiFe{sub 2}O{sub 4} nanoparticles},
author = {Stojak Repa, K. and Israel, D. and Phan, M. H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu and Srikanth, H., E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu and Alonso, J. and BCMaterials Edificio No. 500, Parque Tecnológico de Vizcaya, 48160 Derio and Palmero, E. M. and Vazquez, M.},
abstractNote = {Multi walled carbon nanotubes (MWCNTs) were successfully synthesized using custom-made 80 nm pore-size alumina templates, and were uniformly filled with nickel ferrite (NFO) nanoparticles of 7.4 ± 1.7 nm diameter using a novel magnetically assisted capillary action method. X-ray diffraction confirmed the inverse spinel phase for the synthesized NFO. Transmission electron microscopy confirms spherical NFO nanoparticles with an average diameter of 7.4 nm inside MWCNTs. Magnetometry indicates that both NFO and NFO-filled MWCNTs present a blocking temperature around 52 K, with similar superparamagnetic-like behavior, and weak dipolar interactions, giving rise to a super-spin-glass-like behavior at low temperatures. These properties along with the uniformity of sub-100 nm structures and the possibility of tunable magnetic response in variable diameter carbon nanotubes make them ideal for advanced biomedical and microwave applications.},
doi = {10.1063/1.4914952},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 17,
volume = 117,
place = {United States},
year = {2015},
month = {5}
}