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Title: Inhomogeneous distribution of manganese atoms in ferromagnetic ZnSnAs{sub 2}:Mn thin films on InP revealed by three-dimensional atom probe investigation

Abstract

Atomic-scale Mn distributions in ferromagnetic ZnSnAs{sub 2}:Mn thin films grown on InP substrates have been studied by applying three-dimensional atom probe (3DAP) microscopy. It is found that Mn atoms in cross-sectional 3DAP maps show the presence of inhomogeneities in Mn distribution, which is characteristic patterns of a spinoidal decomposition phase with slightly high and low concentration regions. The high Mn concentration regions are expected to be coherently clustered MnAs in the zinc-blende structure, resulting in the formation of Mn-As random connecting patterns. The origin of room-temperature ferromagnetism in ZnSnAs{sub 2}:Mn on InP can be well explained by the formation of atomic-scale magnetic clustering by spinoidal decomposition without breaking the continuity of the zinc-blende structure, which has been suggested by previous theoretical works. The lattice-matching between magnetic epi-layers and substrates should be one of the most important factors to avoid the formation of secondary hexagonal MnAs phase precipitates in preparing ferromagnetic semiconductor thin films.

Authors:
; ; ;  [1];  [2]
  1. Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)
  2. Toshiba Nanoanalysis Corporation, 8 Shinsugita-cho, Isogo-ku, Yokohama 235-8522 (Japan)
Publication Date:
OSTI Identifier:
22409991
Resource Type:
Journal Article
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 117; Journal Issue: 17; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-8979
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CONCENTRATION RATIO; FERROMAGNETIC MATERIALS; FERROMAGNETISM; HEXAGONAL LATTICES; INDIUM PHOSPHIDES; LAYERS; MANGANESE ARSENIDES; PRECIPITATION; PROBES; SUBSTRATES; TEMPERATURE RANGE 0273-0400 K; THIN FILMS; THREE-DIMENSIONAL CALCULATIONS; THREE-DIMENSIONAL LATTICES; TIN ARSENIDES; ZINC ARSENIDES

Citation Formats

Uchitomi, Naotaka, E-mail: uchitomi@nagaokaut.ac.jp, Inoue, Hiroaki, Kato, Takahiro, Toyota, Hideyuki, and Uchida, Hiroshi. Inhomogeneous distribution of manganese atoms in ferromagnetic ZnSnAs{sub 2}:Mn thin films on InP revealed by three-dimensional atom probe investigation. United States: N. p., 2015. Web. doi:10.1063/1.4914065.
Uchitomi, Naotaka, E-mail: uchitomi@nagaokaut.ac.jp, Inoue, Hiroaki, Kato, Takahiro, Toyota, Hideyuki, & Uchida, Hiroshi. Inhomogeneous distribution of manganese atoms in ferromagnetic ZnSnAs{sub 2}:Mn thin films on InP revealed by three-dimensional atom probe investigation. United States. doi:10.1063/1.4914065.
Uchitomi, Naotaka, E-mail: uchitomi@nagaokaut.ac.jp, Inoue, Hiroaki, Kato, Takahiro, Toyota, Hideyuki, and Uchida, Hiroshi. Thu . "Inhomogeneous distribution of manganese atoms in ferromagnetic ZnSnAs{sub 2}:Mn thin films on InP revealed by three-dimensional atom probe investigation". United States. doi:10.1063/1.4914065.
@article{osti_22409991,
title = {Inhomogeneous distribution of manganese atoms in ferromagnetic ZnSnAs{sub 2}:Mn thin films on InP revealed by three-dimensional atom probe investigation},
author = {Uchitomi, Naotaka, E-mail: uchitomi@nagaokaut.ac.jp and Inoue, Hiroaki and Kato, Takahiro and Toyota, Hideyuki and Uchida, Hiroshi},
abstractNote = {Atomic-scale Mn distributions in ferromagnetic ZnSnAs{sub 2}:Mn thin films grown on InP substrates have been studied by applying three-dimensional atom probe (3DAP) microscopy. It is found that Mn atoms in cross-sectional 3DAP maps show the presence of inhomogeneities in Mn distribution, which is characteristic patterns of a spinoidal decomposition phase with slightly high and low concentration regions. The high Mn concentration regions are expected to be coherently clustered MnAs in the zinc-blende structure, resulting in the formation of Mn-As random connecting patterns. The origin of room-temperature ferromagnetism in ZnSnAs{sub 2}:Mn on InP can be well explained by the formation of atomic-scale magnetic clustering by spinoidal decomposition without breaking the continuity of the zinc-blende structure, which has been suggested by previous theoretical works. The lattice-matching between magnetic epi-layers and substrates should be one of the most important factors to avoid the formation of secondary hexagonal MnAs phase precipitates in preparing ferromagnetic semiconductor thin films.},
doi = {10.1063/1.4914065},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 17,
volume = 117,
place = {United States},
year = {2015},
month = {5}
}