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Title: Spin reorientation in multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} with Mössbauer spectroscopy

Abstract

We studied the magnetic properties of multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4}, especially focusing on the spin-ordering, spin-reorientation, and charge re-distribution effects. From the Rietveld refinement analysis, the crystal structure was identified to be a normal cubic spinel of Fd-3m. Based on the temperature-dependent measurements of the magnetization and magnetic hyperfine field (H{sub hf}), Curie temperature (T{sub C}) of Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} was determined to be around 86 K where H{sub hf}  ≅  0. From the change of slope in the M-T curve, the conical-spiral magnetic ordering temperature was determined to be 20 K, which coincides with H{sub hf} measurement. Also, we have observed the decrease in the slope of the electric quadrupole splitting (ΔE{sub Q}) curve above 20 K, suggesting that the change in ΔE{sub Q} around T{sub S} is originated from charge redistribution due to the spin-relocation associated with the distortion of each tetrahedral site around Fe{sup 2+} ion above T{sub S}. This indicates that Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} has the noncollinear conical-spiral spin ordering with incommensurate spin structure below T{sub S}, while above T{sub S}, it has ferrimagnetic spin ordering with commensuration in the collinear state. In addition, the Jahn-teller distortion temperature is measured to be around 155 K,more » since both ΔE{sub Q} and Δ{sub 1} of {sup 5}T{sub 2g} band decrease rapidly with increasing temperature and disappear around 155 K.« less

Authors:
;  [1]
  1. Department of Physics, Kookmin University, Seoul 136-702 (Korea, Republic of)
Publication Date:
OSTI Identifier:
22409984
Resource Type:
Journal Article
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 117; Journal Issue: 17; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-8979
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; CHROMATES; COBALT COMPOUNDS; CRYSTAL STRUCTURE; CUBIC LATTICES; CURIE POINT; IRON COMPOUNDS; IRON IONS; JAHN-TELLER EFFECT; MAGNETIC PROPERTIES; MAGNETIZATION; SPIN; SPINELS; TEMPERATURE DEPENDENCE

Citation Formats

Myoung, Bo Ra, and Kim, Chul Sung, E-mail: cskim@kookmin.ac.kr. Spin reorientation in multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} with Mössbauer spectroscopy. United States: N. p., 2015. Web. doi:10.1063/1.4918968.
Myoung, Bo Ra, & Kim, Chul Sung, E-mail: cskim@kookmin.ac.kr. Spin reorientation in multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} with Mössbauer spectroscopy. United States. doi:10.1063/1.4918968.
Myoung, Bo Ra, and Kim, Chul Sung, E-mail: cskim@kookmin.ac.kr. Thu . "Spin reorientation in multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} with Mössbauer spectroscopy". United States. doi:10.1063/1.4918968.
@article{osti_22409984,
title = {Spin reorientation in multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} with Mössbauer spectroscopy},
author = {Myoung, Bo Ra and Kim, Chul Sung, E-mail: cskim@kookmin.ac.kr},
abstractNote = {We studied the magnetic properties of multiferroic spinel Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4}, especially focusing on the spin-ordering, spin-reorientation, and charge re-distribution effects. From the Rietveld refinement analysis, the crystal structure was identified to be a normal cubic spinel of Fd-3m. Based on the temperature-dependent measurements of the magnetization and magnetic hyperfine field (H{sub hf}), Curie temperature (T{sub C}) of Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} was determined to be around 86 K where H{sub hf}  ≅  0. From the change of slope in the M-T curve, the conical-spiral magnetic ordering temperature was determined to be 20 K, which coincides with H{sub hf} measurement. Also, we have observed the decrease in the slope of the electric quadrupole splitting (ΔE{sub Q}) curve above 20 K, suggesting that the change in ΔE{sub Q} around T{sub S} is originated from charge redistribution due to the spin-relocation associated with the distortion of each tetrahedral site around Fe{sup 2+} ion above T{sub S}. This indicates that Co{sub 0.5}Fe{sub 0.5}Cr{sub 2}O{sub 4} has the noncollinear conical-spiral spin ordering with incommensurate spin structure below T{sub S}, while above T{sub S}, it has ferrimagnetic spin ordering with commensuration in the collinear state. In addition, the Jahn-teller distortion temperature is measured to be around 155 K, since both ΔE{sub Q} and Δ{sub 1} of {sup 5}T{sub 2g} band decrease rapidly with increasing temperature and disappear around 155 K.},
doi = {10.1063/1.4918968},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 17,
volume = 117,
place = {United States},
year = {2015},
month = {5}
}