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Title: Hybrid improper ferroelectricity in Ruddlesden-Popper Ca{sub 3}(Ti,Mn){sub 2}O{sub 7} ceramics

Abstract

The hybrid improper ferroelectricity (HIF) has been proposed as a promising way to create multiferroic materials with strong magnetoelectric coupling by the first-principle calculation, and the experimental evidences of HIF in Ruddlesden-Poper Ca{sub 3}(Ti{sub 1−x}Mn{sub x}){sub 2}O{sub 7} (x = 0, 0.05, 0.1, and 0.15) ceramics have been shown in the present work. The room temperature ferroelectric hysteresis loops are observed in these ceramics, and a polar orthorhombic structure with two oxygen tilting modes has been confirmed by the X-ray powder diffraction. A first-order phase transition around 1100 K in Ca{sub 3}Ti{sub 2}O{sub 7} was evidenced, and the temperatures of phase transitions decrease linearly with increasing of the contents of Mn{sup 4+} ions. Based on the result of first-principle calculations, the polarization should be reversed by switching through the mediated Amam phase in Ca{sub 3}Ti{sub 2}O{sub 7} ceramics.

Authors:
; ; ; ; ;  [1]; ;  [2]
  1. Laboratory of Dielectric Materials, School of Materials Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027 (China)
  2. Department of Physics, Shanghai University, 99 Shangda Road, Shanghai 200444 (China)
Publication Date:
OSTI Identifier:
22402464
Resource Type:
Journal Article
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 106; Journal Issue: 20; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0003-6951
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; CALCIUM COMPOUNDS; CERAMICS; ELECTRICAL PROPERTIES; FERROELECTRIC MATERIALS; HYSTERESIS; MAGNETIC PROPERTIES; MANGANESE COMPOUNDS; MANGANESE IONS; ORTHORHOMBIC LATTICES; OXYGEN; PHASE TRANSFORMATIONS; POLARIZATION; TITANIUM OXIDES; X-RAY DIFFRACTION

Citation Formats

Liu, X. Q., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn, Wu, J. W., Shi, X. X., Zhao, H. J., Zhou, H. Y., Chen, X. M., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn, Qiu, R. H., and Zhang, W. Q. Hybrid improper ferroelectricity in Ruddlesden-Popper Ca{sub 3}(Ti,Mn){sub 2}O{sub 7} ceramics. United States: N. p., 2015. Web. doi:10.1063/1.4921624.
Liu, X. Q., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn, Wu, J. W., Shi, X. X., Zhao, H. J., Zhou, H. Y., Chen, X. M., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn, Qiu, R. H., & Zhang, W. Q. Hybrid improper ferroelectricity in Ruddlesden-Popper Ca{sub 3}(Ti,Mn){sub 2}O{sub 7} ceramics. United States. doi:10.1063/1.4921624.
Liu, X. Q., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn, Wu, J. W., Shi, X. X., Zhao, H. J., Zhou, H. Y., Chen, X. M., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn, Qiu, R. H., and Zhang, W. Q. Mon . "Hybrid improper ferroelectricity in Ruddlesden-Popper Ca{sub 3}(Ti,Mn){sub 2}O{sub 7} ceramics". United States. doi:10.1063/1.4921624.
@article{osti_22402464,
title = {Hybrid improper ferroelectricity in Ruddlesden-Popper Ca{sub 3}(Ti,Mn){sub 2}O{sub 7} ceramics},
author = {Liu, X. Q., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn and Wu, J. W. and Shi, X. X. and Zhao, H. J. and Zhou, H. Y. and Chen, X. M., E-mail: xqliu@zju.edu.cn, E-mail: xmchen59@zju.edu.cn and Qiu, R. H. and Zhang, W. Q.},
abstractNote = {The hybrid improper ferroelectricity (HIF) has been proposed as a promising way to create multiferroic materials with strong magnetoelectric coupling by the first-principle calculation, and the experimental evidences of HIF in Ruddlesden-Poper Ca{sub 3}(Ti{sub 1−x}Mn{sub x}){sub 2}O{sub 7} (x = 0, 0.05, 0.1, and 0.15) ceramics have been shown in the present work. The room temperature ferroelectric hysteresis loops are observed in these ceramics, and a polar orthorhombic structure with two oxygen tilting modes has been confirmed by the X-ray powder diffraction. A first-order phase transition around 1100 K in Ca{sub 3}Ti{sub 2}O{sub 7} was evidenced, and the temperatures of phase transitions decrease linearly with increasing of the contents of Mn{sup 4+} ions. Based on the result of first-principle calculations, the polarization should be reversed by switching through the mediated Amam phase in Ca{sub 3}Ti{sub 2}O{sub 7} ceramics.},
doi = {10.1063/1.4921624},
journal = {Applied Physics Letters},
issn = {0003-6951},
number = 20,
volume = 106,
place = {United States},
year = {2015},
month = {5}
}