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Title: Tailoring the dipole properties in dielectric polymers to realize high energy density with high breakdown strength and low dielectric loss

Abstract

High energy density polymer materials are desirable for a broad range of modern power electronic systems. Here, we report the development of a new class of polymer dielectrics based on polyurea and polythiourea, which possess high thermal stability. By increasing the dipole density, the dielectric constant of meta-phenylene polyurea and methylene polythiourea can be increased to 5.7, compared with aromatic polyurea and aromatic polythiourea, which have a dielectric constant in the range of 4.1–4.3. The random dipoles with high dipolar moment and amorphous structure of these polyurea and polythiourea based polymers provide strong scattering to the charge carriers, resulting in low losses even at high electric fields. Consequently, this new class of polymers exhibit a linear dielectric response to the highest field measured (>700 MV/m) with a high breakdown strength, achieving high energy density (>13 J/cm{sup 3}) with high efficiency (>90%)

Authors:
; ; ;  [1];  [1];  [2];  [3]
  1. Department of Electrical Engineering and Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States)
  2. (China)
  3. Department of Materials Science and Engineering, Inha University, Incheon 402-751 (Korea, Republic of)
Publication Date:
OSTI Identifier:
22399308
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 117; Journal Issue: 11; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 36 MATERIALS SCIENCE; CHARGE CARRIERS; COMPARATIVE EVALUATIONS; DIELECTRIC MATERIALS; DIPOLE MOMENTS; DIPOLES; ELECTRIC FIELDS; ENERGY DENSITY; ORGANIC POLYMERS; PERMITTIVITY; PHASE STABILITY; RELAXATION LOSSES

Citation Formats

Thakur, Yash, Lin, Minren, Wu, Shan, Zhang, Q. M., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu, Cheng, Zhaoxi, Department of Polymer Science and Engineering and Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, and Jeong, D.-Y., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu. Tailoring the dipole properties in dielectric polymers to realize high energy density with high breakdown strength and low dielectric loss. United States: N. p., 2015. Web. doi:10.1063/1.4915942.
Thakur, Yash, Lin, Minren, Wu, Shan, Zhang, Q. M., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu, Cheng, Zhaoxi, Department of Polymer Science and Engineering and Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, & Jeong, D.-Y., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu. Tailoring the dipole properties in dielectric polymers to realize high energy density with high breakdown strength and low dielectric loss. United States. doi:10.1063/1.4915942.
Thakur, Yash, Lin, Minren, Wu, Shan, Zhang, Q. M., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu, Cheng, Zhaoxi, Department of Polymer Science and Engineering and Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, and Jeong, D.-Y., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu. Sat . "Tailoring the dipole properties in dielectric polymers to realize high energy density with high breakdown strength and low dielectric loss". United States. doi:10.1063/1.4915942.
@article{osti_22399308,
title = {Tailoring the dipole properties in dielectric polymers to realize high energy density with high breakdown strength and low dielectric loss},
author = {Thakur, Yash and Lin, Minren and Wu, Shan and Zhang, Q. M., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu and Cheng, Zhaoxi and Department of Polymer Science and Engineering and Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093 and Jeong, D.-Y., E-mail: dqj100@gmail.com, E-mail: qxz1@psu.edu},
abstractNote = {High energy density polymer materials are desirable for a broad range of modern power electronic systems. Here, we report the development of a new class of polymer dielectrics based on polyurea and polythiourea, which possess high thermal stability. By increasing the dipole density, the dielectric constant of meta-phenylene polyurea and methylene polythiourea can be increased to 5.7, compared with aromatic polyurea and aromatic polythiourea, which have a dielectric constant in the range of 4.1–4.3. The random dipoles with high dipolar moment and amorphous structure of these polyurea and polythiourea based polymers provide strong scattering to the charge carriers, resulting in low losses even at high electric fields. Consequently, this new class of polymers exhibit a linear dielectric response to the highest field measured (>700 MV/m) with a high breakdown strength, achieving high energy density (>13 J/cm{sup 3}) with high efficiency (>90%)},
doi = {10.1063/1.4915942},
journal = {Journal of Applied Physics},
number = 11,
volume = 117,
place = {United States},
year = {Sat Mar 21 00:00:00 EDT 2015},
month = {Sat Mar 21 00:00:00 EDT 2015}
}