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Title: Nb-doped single crystalline MoS{sub 2} field effect transistor

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4919565· OSTI ID:22398978
 [1];  [2];  [1]
  1. Center for Nanoscale Material, Argonne National Laboratory, Argonne, Illinois 60439 (United States)
  2. Division of High Energy Physics, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

We report on the demonstration of a p-type, single crystalline, few layer MoS{sub 2} field effect transistor (FET) using Niobium (Nb) as the dopant. The doping concentration was extracted and determined to be ∼3 × 10{sup 19}/cm{sup 3}. We also report on bilayer Nb-doped MoS{sub 2} FETs with ambipolar conduction. We found that the current ON-OFF ratio of the Nb-doped MoS{sub 2} FETs changes significantly as a function of the flake thickness. We attribute this experimental observation to bulk-type electrostatic effect in ultra-thin MoS{sub 2} crystals. We provide detailed analytical modeling in support of our claims. Finally, we show that in the presence of heavy doping, even ultra-thin 2D-semiconductors cannot be fully depleted and may behave as a 3D material when used in transistor geometry. Our findings provide important insights into the doping constraints of 2D materials, in general.

OSTI ID:
22398978
Journal Information:
Applied Physics Letters, Vol. 106, Issue 17; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English

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Re Doping in 2D Transition Metal Dichalcogenides as a New Route to Tailor Structural Phases and Induced Magnetism journal October 2017
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A Shallow Acceptor of Phosphorous Doped in MoSe 2 Monolayer journal November 2019
Number-of-layer resolved (Mo, W)-(S 2 , Se 2 ) phonon relaxation: Number-of-layer resolved (Mo, W)-(S 2 , Se 2 ) phonon relaxation journal January 2017
Various Structures of 2D Transition-Metal Dichalcogenides and Their Applications journal July 2018
p-Type transition-metal doping of large-area MoS 2 thin films grown by chemical vapor deposition journal January 2017
Synthesis of submillimeter SnSe x S 2−x (0 < x < 1) two-dimensional alloy and photoinduced reversible transformation between Schottky and Ohmic contact behaviors in devices journal January 2018
Engineering of transition metal dichalcogenide-based 2D nanomaterials through doping for environmental applications journal January 2019
Scalable fabrication of a complementary logic inverter based on MoS 2 fin-shaped field effect transistors journal January 2019
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Phosphorous doped p-type MoS2 polycrystalline thin films via direct sulfurization of Mo film journal February 2018
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Strain-Enhanced p Doping in Monolayer MoS 2 journal February 2018
Band gap-tuned MoS2(1−x)Te2x thin films synthesized by a hybrid Co-sputtering and post-deposition tellurization annealing process journal August 2017
Large-Area Ultraviolet Photodetectors Based on p-Type Multilayer MoS2 Enabled by Plasma Doping journal March 2019
Progress in Contact, Doping and Mobility Engineering of MoS2: An Atomically Thin 2D Semiconductor journal August 2018
Heating-up Synthesis of MoS2 Nanosheets and Their Electrical Bistability Performance journal March 2016