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Title: Small angle scattering methods to study porous materials under high uniaxial strain

Abstract

We developed a high pressure cell for the in situ study of the porosity of solids under high uniaxial strain using neutron small angle scattering. The cell comprises a hydraulically actioned piston and a main body equipped with two single-crystal sapphire windows allowing for the neutron scattering of the sample. The sample cavity is designed to allow for a large volume variation as expected when compressing highly porous materials. We also implemented a loading protocol to adapt an existing diamond anvil cell for the study of porous materials by X-ray small angle scattering under high pressure. The two techniques are complementary as the radiation beam and the applied pressure are in one case perpendicular to each other (neutron cell) and in the other case parallel (X-ray cell). We will illustrate the use of these two techniques in the study of lamellar porous systems up to a maximum pressure of 0.1 GPa and 0.3 GPa for the neutron and X-ray cells, respectively. These devices allow obtaining information on the evolution of porosity with pressure in the pore dimension subdomain defined by the wave-numbers explored in the scattering process. The evolution with the applied load of such parameters as the fractal dimensionmore » of the pore-matrix interface or the apparent specific surface in expanded graphite and in expanded vermiculite is used to illustrate the use of the high pressure cells.« less

Authors:
; ; ; ;  [1]
  1. Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon, 69622 Villeurbanne Cedex (France)
Publication Date:
OSTI Identifier:
22392371
Resource Type:
Journal Article
Resource Relation:
Journal Name: Review of Scientific Instruments; Journal Volume: 86; Journal Issue: 2; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; BEAMS; DESIGN; DIAMONDS; EQUIPMENT; FRACTALS; GRAPHITE; INTERFACES; MONOCRYSTALS; NEUTRON DIFFRACTION; POROSITY; POROUS MATERIALS; SAPPHIRE; SMALL ANGLE SCATTERING; SOLIDS; STRAINS; SURFACES; VARIATIONS; VERMICULITE; X RADIATION

Citation Formats

Le Floch, Sylvie, E-mail: sylvie.le-floch@univ-lyon1.fr, Balima, Félix, Pischedda, Vittoria, Legrand, Franck, and San-Miguel, Alfonso. Small angle scattering methods to study porous materials under high uniaxial strain. United States: N. p., 2015. Web. doi:10.1063/1.4908168.
Le Floch, Sylvie, E-mail: sylvie.le-floch@univ-lyon1.fr, Balima, Félix, Pischedda, Vittoria, Legrand, Franck, & San-Miguel, Alfonso. Small angle scattering methods to study porous materials under high uniaxial strain. United States. doi:10.1063/1.4908168.
Le Floch, Sylvie, E-mail: sylvie.le-floch@univ-lyon1.fr, Balima, Félix, Pischedda, Vittoria, Legrand, Franck, and San-Miguel, Alfonso. Sun . "Small angle scattering methods to study porous materials under high uniaxial strain". United States. doi:10.1063/1.4908168.
@article{osti_22392371,
title = {Small angle scattering methods to study porous materials under high uniaxial strain},
author = {Le Floch, Sylvie, E-mail: sylvie.le-floch@univ-lyon1.fr and Balima, Félix and Pischedda, Vittoria and Legrand, Franck and San-Miguel, Alfonso},
abstractNote = {We developed a high pressure cell for the in situ study of the porosity of solids under high uniaxial strain using neutron small angle scattering. The cell comprises a hydraulically actioned piston and a main body equipped with two single-crystal sapphire windows allowing for the neutron scattering of the sample. The sample cavity is designed to allow for a large volume variation as expected when compressing highly porous materials. We also implemented a loading protocol to adapt an existing diamond anvil cell for the study of porous materials by X-ray small angle scattering under high pressure. The two techniques are complementary as the radiation beam and the applied pressure are in one case perpendicular to each other (neutron cell) and in the other case parallel (X-ray cell). We will illustrate the use of these two techniques in the study of lamellar porous systems up to a maximum pressure of 0.1 GPa and 0.3 GPa for the neutron and X-ray cells, respectively. These devices allow obtaining information on the evolution of porosity with pressure in the pore dimension subdomain defined by the wave-numbers explored in the scattering process. The evolution with the applied load of such parameters as the fractal dimension of the pore-matrix interface or the apparent specific surface in expanded graphite and in expanded vermiculite is used to illustrate the use of the high pressure cells.},
doi = {10.1063/1.4908168},
journal = {Review of Scientific Instruments},
number = 2,
volume = 86,
place = {United States},
year = {Sun Feb 15 00:00:00 EST 2015},
month = {Sun Feb 15 00:00:00 EST 2015}
}