Crystal field parameters and energy levels scheme of trivalent chromium doped BSO
- Shumen University Konstantin Preslavsky, 115 Universitetska street, 9712 Shumen (Bulgaria)
- Department of Physics, West University of Timisoara, Bd. V. Parvan No. 4, 300223 Timisoara (Romania)
The aim of this paper is to give an analysis of crystal field parameters and energy levels schemes for the above doped material, in order to give a reliable explanation for experimental data. The crystal field parameters have been modeled in the frame of Exchange Charge Model (ECM) of the crystal field theory, taken into account the geometry of systems, with actually site symmetry of the impurity ions. The effect of the charges of the ligands and covalence bonding between chromium cation and oxygen anions, in the cluster approach, also were taken into account. With the obtained values of the crystal field parameters we simulated the scheme of energy levels of chromium ions by diagonalizing the matrix of the Hamiltonian of the doped crystal. The obtained energy levels and estimated Racah parameters B and C were compared with the experimental spectroscopic data and discussed. Comparison with experiment shows that the results are quite satisfactory which justify the model and simulation scheme used for the title system.
- OSTI ID:
- 22390731
- Journal Information:
- AIP Conference Proceedings, Vol. 1634, Issue 1; Conference: TIM-13 Physics Conference, Timisoara (Romania), 21-24 Nov 2013; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
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