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Title: Laser induced fluorescence spectroscopy of the Ca dimer deposited on helium and mixed helium/xenon clusters

Abstract

We study how the laser induced fluorescence spectroscopy of the calcium dimer deposited on pure helium clusters is modified by the addition of xenon atoms. In the wavelength range between 365 and 385 nm, the Ca dimer is excited from its ground state up to two excited electronic states leading to its photodissociation in Ca({sup 1}P)+Ca({sup 1}S): this process is monitored by recording the Ca({sup 1}P) fluorescence at 422.7nm. One of these electronic states of Ca{sub 2} is a diexcited one correlating to the Ca(4s4p{sup 3}P(+Ca(4s3d{sup 3}D), the other one is a repulsive state correlating to the Ca(4s4p1P)+Ca(4s21S) asymptote, accounting for the dissociation of Ca{sub 2} and the observation of the subsequent Ca({sup 1}P) emission. On pure helium clusters, the fluorescence exhibits the calcium atomic resonance line Ca({sup 1}S←{sup 1}P) at 422.7 nm (23652 cm{sup −1}) assigned to ejected calcium, and a narrow red sided band corresponding to calcium that remains solvated on the helium cluster. When adding xenon atoms to the helium clusters, the intensity of these two features decreases and a new spectral band appears on the red side of calcium resonance line; the intensity and the red shift of this component increase along with the xenon quantitymore » deposited on the helium cluster: it is assigned to the emission of Ca({sup 1}P) associated with the small xenon aggregate embedded inside the helium cluster.« less

Authors:
; ; ;  [1]
  1. Laboratoire Francis Perrin, CNRS URA 2453, DSM/IRAMIS/LIDYL, CEA Saclay, 91191 Gif-sur-Yvette Cedex (France)
Publication Date:
OSTI Identifier:
22390587
Resource Type:
Journal Article
Journal Name:
AIP Conference Proceedings
Additional Journal Information:
Journal Volume: 1628; Journal Issue: 1; Conference: 29. International Symposium on Rarefied Gas Dynamics, Xi'an (China), 13-18 Jul 2014; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; ATOMIC CLUSTERS; ATOMS; CALCIUM; DIMERS; DISSOCIATION; ELECTRONIC STRUCTURE; EXCITED STATES; FLUORESCENCE; FLUORESCENCE SPECTROSCOPY; GROUND STATES; HELIUM; LASER RADIATION; PHOTOLYSIS; RED SHIFT; RESONANCE; XENON

Citation Formats

Gaveau, Marc-André, Pothier, Christophe, Briant, Marc, and Mestdagh, Jean-Michel. Laser induced fluorescence spectroscopy of the Ca dimer deposited on helium and mixed helium/xenon clusters. United States: N. p., 2014. Web. doi:10.1063/1.4902686.
Gaveau, Marc-André, Pothier, Christophe, Briant, Marc, & Mestdagh, Jean-Michel. Laser induced fluorescence spectroscopy of the Ca dimer deposited on helium and mixed helium/xenon clusters. United States. doi:10.1063/1.4902686.
Gaveau, Marc-André, Pothier, Christophe, Briant, Marc, and Mestdagh, Jean-Michel. Tue . "Laser induced fluorescence spectroscopy of the Ca dimer deposited on helium and mixed helium/xenon clusters". United States. doi:10.1063/1.4902686.
@article{osti_22390587,
title = {Laser induced fluorescence spectroscopy of the Ca dimer deposited on helium and mixed helium/xenon clusters},
author = {Gaveau, Marc-André and Pothier, Christophe and Briant, Marc and Mestdagh, Jean-Michel},
abstractNote = {We study how the laser induced fluorescence spectroscopy of the calcium dimer deposited on pure helium clusters is modified by the addition of xenon atoms. In the wavelength range between 365 and 385 nm, the Ca dimer is excited from its ground state up to two excited electronic states leading to its photodissociation in Ca({sup 1}P)+Ca({sup 1}S): this process is monitored by recording the Ca({sup 1}P) fluorescence at 422.7nm. One of these electronic states of Ca{sub 2} is a diexcited one correlating to the Ca(4s4p{sup 3}P(+Ca(4s3d{sup 3}D), the other one is a repulsive state correlating to the Ca(4s4p1P)+Ca(4s21S) asymptote, accounting for the dissociation of Ca{sub 2} and the observation of the subsequent Ca({sup 1}P) emission. On pure helium clusters, the fluorescence exhibits the calcium atomic resonance line Ca({sup 1}S←{sup 1}P) at 422.7 nm (23652 cm{sup −1}) assigned to ejected calcium, and a narrow red sided band corresponding to calcium that remains solvated on the helium cluster. When adding xenon atoms to the helium clusters, the intensity of these two features decreases and a new spectral band appears on the red side of calcium resonance line; the intensity and the red shift of this component increase along with the xenon quantity deposited on the helium cluster: it is assigned to the emission of Ca({sup 1}P) associated with the small xenon aggregate embedded inside the helium cluster.},
doi = {10.1063/1.4902686},
journal = {AIP Conference Proceedings},
issn = {0094-243X},
number = 1,
volume = 1628,
place = {United States},
year = {2014},
month = {12}
}