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Title: ABSORPTIONS IN THE VISIBLE OF PROTONATED PYRENE COLLISIONALLY COOLED TO 15 K

Abstract

Protonated polycyclic hydrocarbons have been added to the list of suggested carriers of diffuse interstellar absorptions. To test this proposition requires laboratory spectra measured under interstellar conditions, in particular with the rotational and vibrational degrees of freedom equilibrated to low temperatures. This has been achieved for protonated pyrene with absorption bands in the visible, using an ion trap and collisional cooling to ≈15 K. A two-photon excitation-dissociation scheme was employed to record the (1) {sup 1} A' ← X {sup 1} A' electronic spectrum on around 10{sup 5} ions per duty cycle. The origin band of the absorption spectrum of this relatively large polycyclic aromatic species with 27 atoms is located at 4858.86 Å. Two further comparably intense spectral features are present at 4834.48 and 4809.32 Å. This is one of the largest protonated aromatics studied in the gas phase and compared to astronomical observations; however, it is not a carrier of known diffuse interstellar bands.

Authors:
; ; ;  [1]
  1. Department of Chemistry, University of Basel, Klingelbergstr. 80, 4056-CH Basel (Switzerland)
Publication Date:
OSTI Identifier:
22364121
Resource Type:
Journal Article
Resource Relation:
Journal Name: Astrophysical Journal Letters; Journal Volume: 778; Journal Issue: 2; Other Information: Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; 79 ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; ABSORPTION SPECTRA; ASTRONOMY; ASTROPHYSICS; ATOMS; COMPARATIVE EVALUATIONS; COOLING; DEGREES OF FREEDOM; DISSOCIATION; EXCITATION; INTERSTELLAR GRAINS; INTERSTELLAR SPACE; IONS; MOLECULES; PHOTONS; POLYCYCLIC AROMATIC HYDROCARBONS; PYRENE; TRAPS

Citation Formats

Hardy, F.-X., Gause, O., Rice, C. A., and Maier, J. P., E-mail: j.p.maier@unibas.ch. ABSORPTIONS IN THE VISIBLE OF PROTONATED PYRENE COLLISIONALLY COOLED TO 15 K. United States: N. p., 2013. Web. doi:10.1088/2041-8205/778/2/L30.
Hardy, F.-X., Gause, O., Rice, C. A., & Maier, J. P., E-mail: j.p.maier@unibas.ch. ABSORPTIONS IN THE VISIBLE OF PROTONATED PYRENE COLLISIONALLY COOLED TO 15 K. United States. doi:10.1088/2041-8205/778/2/L30.
Hardy, F.-X., Gause, O., Rice, C. A., and Maier, J. P., E-mail: j.p.maier@unibas.ch. 2013. "ABSORPTIONS IN THE VISIBLE OF PROTONATED PYRENE COLLISIONALLY COOLED TO 15 K". United States. doi:10.1088/2041-8205/778/2/L30.
@article{osti_22364121,
title = {ABSORPTIONS IN THE VISIBLE OF PROTONATED PYRENE COLLISIONALLY COOLED TO 15 K},
author = {Hardy, F.-X. and Gause, O. and Rice, C. A. and Maier, J. P., E-mail: j.p.maier@unibas.ch},
abstractNote = {Protonated polycyclic hydrocarbons have been added to the list of suggested carriers of diffuse interstellar absorptions. To test this proposition requires laboratory spectra measured under interstellar conditions, in particular with the rotational and vibrational degrees of freedom equilibrated to low temperatures. This has been achieved for protonated pyrene with absorption bands in the visible, using an ion trap and collisional cooling to ≈15 K. A two-photon excitation-dissociation scheme was employed to record the (1) {sup 1} A' ← X {sup 1} A' electronic spectrum on around 10{sup 5} ions per duty cycle. The origin band of the absorption spectrum of this relatively large polycyclic aromatic species with 27 atoms is located at 4858.86 Å. Two further comparably intense spectral features are present at 4834.48 and 4809.32 Å. This is one of the largest protonated aromatics studied in the gas phase and compared to astronomical observations; however, it is not a carrier of known diffuse interstellar bands.},
doi = {10.1088/2041-8205/778/2/L30},
journal = {Astrophysical Journal Letters},
number = 2,
volume = 778,
place = {United States},
year = 2013,
month =
}
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