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Title: Molecular layer deposition of alucone films using trimethylaluminum and hydroquinone

Abstract

A hybrid organic–inorganic polymer film grown by molecular layer deposition (MLD) is demonstrated here. Sequential exposures of trimethylaluminum [Al(CH{sub 3}){sub 3}] and hydroquinone [C{sub 6}H{sub 4}(OH){sub 2}] are used to deposit the polymeric films, which is a representative of a class of aluminum oxide polymers known as “alucones.” In-situ quartz crystal microbalance (QCM) studies are employed to determine the growth characteristics. An average growth rate of 4.1 Å per cycle at 150 °C is obtained by QCM and subsequently verified with x-ray reflectivity measurements. Surface chemistry during each MLD-half cycle is studied in depth by in-situ Fourier transform infrared (FTIR) vibration spectroscopy. Self limiting nature of the reaction is confirmed from both QCM and FTIR measurements. The conformal nature of the deposit, typical for atomic layer deposition and MLD, is verified with transmission electron microscopy imaging. Secondary ion mass spectroscopy measurements confirm the uniform elemental distribution along the depth of the films.

Authors:
;  [1];  [2]
  1. Department of Energy Science and Engineering, Indian Institute of Technology Bombay, Mumbai 400076 (India)
  2. Centre for Research in Nanotechnology and Science, Indian Institute of Technology Bombay, Mumbai 400076 (India)
Publication Date:
OSTI Identifier:
22318085
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Vacuum Science and Technology. A, Vacuum, Surfaces and Films; Journal Volume: 33; Journal Issue: 1; Other Information: (c) 2014 American Vacuum Society; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALUMINIUM OXIDES; DEPOSITION; FOURIER TRANSFORMATION; INORGANIC POLYMERS; ION MICROPROBE ANALYSIS; MASS SPECTROSCOPY; MICROBALANCES; ORGANIC POLYMERS; QUARTZ; TRANSMISSION ELECTRON MICROSCOPY; X RADIATION

Citation Formats

Choudhury, Devika, Sarkar, Shaibal K., E-mail: shaibal.sarkar@iitb.ac.in, and Mahuli, Neha. Molecular layer deposition of alucone films using trimethylaluminum and hydroquinone. United States: N. p., 2015. Web. doi:10.1116/1.4900934.
Choudhury, Devika, Sarkar, Shaibal K., E-mail: shaibal.sarkar@iitb.ac.in, & Mahuli, Neha. Molecular layer deposition of alucone films using trimethylaluminum and hydroquinone. United States. doi:10.1116/1.4900934.
Choudhury, Devika, Sarkar, Shaibal K., E-mail: shaibal.sarkar@iitb.ac.in, and Mahuli, Neha. Thu . "Molecular layer deposition of alucone films using trimethylaluminum and hydroquinone". United States. doi:10.1116/1.4900934.
@article{osti_22318085,
title = {Molecular layer deposition of alucone films using trimethylaluminum and hydroquinone},
author = {Choudhury, Devika and Sarkar, Shaibal K., E-mail: shaibal.sarkar@iitb.ac.in and Mahuli, Neha},
abstractNote = {A hybrid organic–inorganic polymer film grown by molecular layer deposition (MLD) is demonstrated here. Sequential exposures of trimethylaluminum [Al(CH{sub 3}){sub 3}] and hydroquinone [C{sub 6}H{sub 4}(OH){sub 2}] are used to deposit the polymeric films, which is a representative of a class of aluminum oxide polymers known as “alucones.” In-situ quartz crystal microbalance (QCM) studies are employed to determine the growth characteristics. An average growth rate of 4.1 Å per cycle at 150 °C is obtained by QCM and subsequently verified with x-ray reflectivity measurements. Surface chemistry during each MLD-half cycle is studied in depth by in-situ Fourier transform infrared (FTIR) vibration spectroscopy. Self limiting nature of the reaction is confirmed from both QCM and FTIR measurements. The conformal nature of the deposit, typical for atomic layer deposition and MLD, is verified with transmission electron microscopy imaging. Secondary ion mass spectroscopy measurements confirm the uniform elemental distribution along the depth of the films.},
doi = {10.1116/1.4900934},
journal = {Journal of Vacuum Science and Technology. A, Vacuum, Surfaces and Films},
number = 1,
volume = 33,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}