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Title: Resistance switching in epitaxial SrCoO{sub x} thin films

Abstract

We observed bipolar switching behavior from an epitaxial strontium cobaltite film grown on a SrTiO{sub 3} (001) substrate. The crystal structure of strontium cobaltite has been known to undergo topotactic phase transformation between two distinct phases: insulating brownmillerite (SrCoO{sub 2.5}) and conducting perovskite (SrCoO{sub 3−δ}) depending on the oxygen content. The current–voltage characteristics of the strontium cobaltite film showed that it could have a reversible insulator-to-metal transition triggered by electrical bias voltage. We propose that the resistance switching in the SrCoO{sub x} thin film could be related to the topotactic phase transformation and the peculiar structure of SrCoO{sub 2.5}.

Authors:
; ; ; ;  [1]; ;  [2]; ;  [3]; ;  [4];  [5];  [6]; ;  [7]; ; ; ;  [8]
  1. Department of Physics, Hankuk University of Foreign Studies, Yongin 449-791 (Korea, Republic of)
  2. Division of Quantum Phases and Devices, Department of Physics, Konkuk University, Seoul 143-791 (Korea, Republic of)
  3. Department of Physics and Division of Energy System Research, Ajou University, Suwon 443-749 (Korea, Republic of)
  4. Department of Physics and Astronomy and Center for Subwavelength Optics, Seoul National University, Seoul 151-747 (Korea, Republic of)
  5. Department of Physics, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)
  6. Department of Physics, Ewha Womans University, Seoul 120-750 (Korea, Republic of)
  7. Electronic Materials Research Center, Korea Institute of Science and Technology, Seoul 136-791 (Korea, Republic of)
  8. Department of Material Science and Engineering, Seoul National University, Seoul 151-747 (Korea, Republic of)
Publication Date:
OSTI Identifier:
22318026
Resource Type:
Journal Article
Resource Relation:
Journal Name: Applied Physics Letters; Journal Volume: 105; Journal Issue: 6; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; CRYSTAL STRUCTURE; EPITAXY; OXYGEN; PEROVSKITE; PHASE TRANSFORMATIONS; STRONTIUM; STRONTIUM CARBONATES; STRONTIUM TITANATES; THIN FILMS

Citation Formats

Tambunan, Octolia T., Parwanta, Kadek J., Acharya, Susant K., Lee, Bo Wha, Jung, Chang Uk, E-mail: cu-jung@hufs.ac.kr, Kim, Yeon Soo, Park, Bae Ho, Jeong, Huiseong, Park, Ji-Yong, Cho, Myung Rae, Park, Yun Daniel, Choi, Woo Seok, Kim, Dong-Wook, Jin, Hyunwoo, Lee, Suyoun, Song, Seul Ji, Kang, Sung-Jin, Kim, Miyoung, and Hwang, Cheol Seong. Resistance switching in epitaxial SrCoO{sub x} thin films. United States: N. p., 2014. Web. doi:10.1063/1.4893323.
Tambunan, Octolia T., Parwanta, Kadek J., Acharya, Susant K., Lee, Bo Wha, Jung, Chang Uk, E-mail: cu-jung@hufs.ac.kr, Kim, Yeon Soo, Park, Bae Ho, Jeong, Huiseong, Park, Ji-Yong, Cho, Myung Rae, Park, Yun Daniel, Choi, Woo Seok, Kim, Dong-Wook, Jin, Hyunwoo, Lee, Suyoun, Song, Seul Ji, Kang, Sung-Jin, Kim, Miyoung, & Hwang, Cheol Seong. Resistance switching in epitaxial SrCoO{sub x} thin films. United States. doi:10.1063/1.4893323.
Tambunan, Octolia T., Parwanta, Kadek J., Acharya, Susant K., Lee, Bo Wha, Jung, Chang Uk, E-mail: cu-jung@hufs.ac.kr, Kim, Yeon Soo, Park, Bae Ho, Jeong, Huiseong, Park, Ji-Yong, Cho, Myung Rae, Park, Yun Daniel, Choi, Woo Seok, Kim, Dong-Wook, Jin, Hyunwoo, Lee, Suyoun, Song, Seul Ji, Kang, Sung-Jin, Kim, Miyoung, and Hwang, Cheol Seong. Mon . "Resistance switching in epitaxial SrCoO{sub x} thin films". United States. doi:10.1063/1.4893323.
@article{osti_22318026,
title = {Resistance switching in epitaxial SrCoO{sub x} thin films},
author = {Tambunan, Octolia T. and Parwanta, Kadek J. and Acharya, Susant K. and Lee, Bo Wha and Jung, Chang Uk, E-mail: cu-jung@hufs.ac.kr and Kim, Yeon Soo and Park, Bae Ho and Jeong, Huiseong and Park, Ji-Yong and Cho, Myung Rae and Park, Yun Daniel and Choi, Woo Seok and Kim, Dong-Wook and Jin, Hyunwoo and Lee, Suyoun and Song, Seul Ji and Kang, Sung-Jin and Kim, Miyoung and Hwang, Cheol Seong},
abstractNote = {We observed bipolar switching behavior from an epitaxial strontium cobaltite film grown on a SrTiO{sub 3} (001) substrate. The crystal structure of strontium cobaltite has been known to undergo topotactic phase transformation between two distinct phases: insulating brownmillerite (SrCoO{sub 2.5}) and conducting perovskite (SrCoO{sub 3−δ}) depending on the oxygen content. The current–voltage characteristics of the strontium cobaltite film showed that it could have a reversible insulator-to-metal transition triggered by electrical bias voltage. We propose that the resistance switching in the SrCoO{sub x} thin film could be related to the topotactic phase transformation and the peculiar structure of SrCoO{sub 2.5}.},
doi = {10.1063/1.4893323},
journal = {Applied Physics Letters},
number = 6,
volume = 105,
place = {United States},
year = {Mon Aug 11 00:00:00 EDT 2014},
month = {Mon Aug 11 00:00:00 EDT 2014}
}