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Title: Electrodeposited cobalt sulfide hole collecting layer for polymer solar cells

Abstract

In polymer solar cells based on the blend of regioregular poly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester, the hole collecting layer has to be endowed with its ionization potential close to or greater than that of P3HT (∼5 eV). Conductive polymer blends such as poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and metal oxides such as vanadium pentoxide (V{sub 2}O{sub 5}) and molybdenum trioxide (MoO{sub 3}) satisfy this requirement and have been the most common materials used so far in bulk heterojunction structures. We report here cobalt sulfide (CoS) to be a promising hole collecting material deposited by convenient and room temperature electrodeposition. By simply tuning the CoS electrodeposition parameters, power conversion efficiencies similar (within 15%) to a reference structure with PEDOT:PSS were obtained.

Authors:
; ; ; ; ;  [1]
  1. CHOSE (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, University of Rome “Tor Vergata,” Via del Politecnico 1, 00133 Rome (Italy)
Publication Date:
OSTI Identifier:
22318020
Resource Type:
Journal Article
Resource Relation:
Journal Name: Applied Physics Letters; Journal Volume: 105; Journal Issue: 6; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; BUTYRIC ACID; COBALT SULFIDES; EFFICIENCY; ELECTRODEPOSITION; ESTERS; HETEROJUNCTIONS; HOLES; MOLYBDENUM OXIDES; ORGANIC SOLAR CELLS; POLYMERS; STYRENE; THIOPHENE; VANADATES; VANADIUM OXIDES

Citation Formats

Zampetti, Andrea, De Rossi, Francesca, Brunetti, Francesca, Reale, Andrea, Di Carlo, Aldo, and Brown, Thomas M., E-mail: thomas.brown@uniroma2.it. Electrodeposited cobalt sulfide hole collecting layer for polymer solar cells. United States: N. p., 2014. Web. doi:10.1063/1.4892845.
Zampetti, Andrea, De Rossi, Francesca, Brunetti, Francesca, Reale, Andrea, Di Carlo, Aldo, & Brown, Thomas M., E-mail: thomas.brown@uniroma2.it. Electrodeposited cobalt sulfide hole collecting layer for polymer solar cells. United States. doi:10.1063/1.4892845.
Zampetti, Andrea, De Rossi, Francesca, Brunetti, Francesca, Reale, Andrea, Di Carlo, Aldo, and Brown, Thomas M., E-mail: thomas.brown@uniroma2.it. Mon . "Electrodeposited cobalt sulfide hole collecting layer for polymer solar cells". United States. doi:10.1063/1.4892845.
@article{osti_22318020,
title = {Electrodeposited cobalt sulfide hole collecting layer for polymer solar cells},
author = {Zampetti, Andrea and De Rossi, Francesca and Brunetti, Francesca and Reale, Andrea and Di Carlo, Aldo and Brown, Thomas M., E-mail: thomas.brown@uniroma2.it},
abstractNote = {In polymer solar cells based on the blend of regioregular poly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester, the hole collecting layer has to be endowed with its ionization potential close to or greater than that of P3HT (∼5 eV). Conductive polymer blends such as poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and metal oxides such as vanadium pentoxide (V{sub 2}O{sub 5}) and molybdenum trioxide (MoO{sub 3}) satisfy this requirement and have been the most common materials used so far in bulk heterojunction structures. We report here cobalt sulfide (CoS) to be a promising hole collecting material deposited by convenient and room temperature electrodeposition. By simply tuning the CoS electrodeposition parameters, power conversion efficiencies similar (within 15%) to a reference structure with PEDOT:PSS were obtained.},
doi = {10.1063/1.4892845},
journal = {Applied Physics Letters},
number = 6,
volume = 105,
place = {United States},
year = {Mon Aug 11 00:00:00 EDT 2014},
month = {Mon Aug 11 00:00:00 EDT 2014}
}