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Title: Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature

Abstract

The effects of heavy rare earth (RE) additions on the Curie temperature (T{sub C}) and magnetocaloric effect of the Fe-RE-B-Nb (RE = Gd, Dy and Ho) bulk metallic glasses were studied. The type of dopping RE element and its concentration can easily tune T{sub C} in a large temperature range of 120 K without significantly decreasing the magnetic entropy change (ΔS{sub M}) and refrigerant capacity (RC) of the alloys. The observed values of ΔS{sub M} and RC of these alloys compare favorably with those of recently reported Fe-based metallic glasses with enhanced RC compared to Gd{sub 5}Ge{sub 1.9}Si{sub 2}Fe{sub 0.1}. The tunable T{sub C} and large glass-forming ability of these RE doped Fe-based bulk metallic glasses can be used in a wide temperature range with the final required shapes.

Authors:
; ; ; ; ; ;  [1];  [2];  [3]
  1. Key Laboratory of Magnetic Materials and Devices, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China)
  2. (China)
  3. Department of Applied Physics, Chalmers University of Technology, SE-412 96 Göteborg (Sweden)
Publication Date:
OSTI Identifier:
22314612
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 116; Journal Issue: 6; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ALLOYS; COMPARATIVE EVALUATIONS; CONCENTRATION RATIO; CURIE POINT; DOPED MATERIALS; ENTROPY; GLASS; MAGNETIC PROPERTIES; METALLIC GLASSES; RARE EARTHS; REFRIGERANTS; TEMPERATURE RANGE

Citation Formats

Li, Jiawei, Huo, Juntao, Chang, Chuntao, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn, Du, Juan, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn, Man, Qikui, Wang, Xinmin, Li, Run-Wei, Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, and Law, Jiayan. Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature. United States: N. p., 2014. Web. doi:10.1063/1.4892431.
Li, Jiawei, Huo, Juntao, Chang, Chuntao, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn, Du, Juan, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn, Man, Qikui, Wang, Xinmin, Li, Run-Wei, Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, & Law, Jiayan. Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature. United States. doi:10.1063/1.4892431.
Li, Jiawei, Huo, Juntao, Chang, Chuntao, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn, Du, Juan, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn, Man, Qikui, Wang, Xinmin, Li, Run-Wei, Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201, and Law, Jiayan. Thu . "Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature". United States. doi:10.1063/1.4892431.
@article{osti_22314612,
title = {Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature},
author = {Li, Jiawei and Huo, Juntao and Chang, Chuntao, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn and Du, Juan, E-mail: ctchang@nimte.ac.cn, E-mail: dujun@nimte.ac.cn and Man, Qikui and Wang, Xinmin and Li, Run-Wei and Zhejiang Province Key Laboratory of Magnetic Materials and Application Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 and Law, Jiayan},
abstractNote = {The effects of heavy rare earth (RE) additions on the Curie temperature (T{sub C}) and magnetocaloric effect of the Fe-RE-B-Nb (RE = Gd, Dy and Ho) bulk metallic glasses were studied. The type of dopping RE element and its concentration can easily tune T{sub C} in a large temperature range of 120 K without significantly decreasing the magnetic entropy change (ΔS{sub M}) and refrigerant capacity (RC) of the alloys. The observed values of ΔS{sub M} and RC of these alloys compare favorably with those of recently reported Fe-based metallic glasses with enhanced RC compared to Gd{sub 5}Ge{sub 1.9}Si{sub 2}Fe{sub 0.1}. The tunable T{sub C} and large glass-forming ability of these RE doped Fe-based bulk metallic glasses can be used in a wide temperature range with the final required shapes.},
doi = {10.1063/1.4892431},
journal = {Journal of Applied Physics},
number = 6,
volume = 116,
place = {United States},
year = {Thu Aug 14 00:00:00 EDT 2014},
month = {Thu Aug 14 00:00:00 EDT 2014}
}
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