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Title: Discovery of a thermally persistent h.c.p. solid-solution phase in the Ni-W system

Abstract

Although the accepted Ni-W phase diagram does not reveal the existence of h.c.p.-based phases, h.c.p.-like stacking sequences were observed in magnetron-co-sputtered Ni-W thin films at W contents of 20 to 25 at. %, by using transmission electron microscopy and X-ray diffraction. The occurrence of this h.c.p.-like solid-solution phase could be rationalized by first-principles calculations, showing that the vicinity of the system's ground-state line is populated with metastable h.c.p.-based superstructures in the intermediate concentration range from 20 to 50 at. % W. The h.c.p.-like stacking in Ni-W films was observed to be thermally persistent, up to temperatures as high as at least 850 K, as evidenced by extensive X-ray diffraction analyses on specimens before and after annealing treatments. The tendency of Ni-W for excessive planar faulting is discussed in the light of these new findings.

Authors:
;  [1]; ; ;  [2];  [1];  [3]
  1. Max Planck Institute for Intelligent Systems (formerly Max Planck Institute for Metals Research), Heisenbergstraße 3, D-70569 Stuttgart (Germany)
  2. Institute of Advanced Ceramics, Hamburg University of Technology, Denickestraße 15, D-21073 Hamburg (Germany)
  3. (Germany)
Publication Date:
OSTI Identifier:
22314331
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 116; Journal Issue: 8; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ANNEALING; GROUND STATES; MAGNETRONS; PHASE DIAGRAMS; SOLID SOLUTIONS; SPUTTERING; THIN FILMS; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION

Citation Formats

Kurz, S. J. B., E-mail: s.kurz@is.mpg.de, Leineweber, A., Maisel, S. B., Höfler, M., Müller, S., Mittemeijer, E. J., and Institute for Materials Science, University of Stuttgart, Heisenbergstraße 3, D-70569 Stuttgart. Discovery of a thermally persistent h.c.p. solid-solution phase in the Ni-W system. United States: N. p., 2014. Web. doi:10.1063/1.4894148.
Kurz, S. J. B., E-mail: s.kurz@is.mpg.de, Leineweber, A., Maisel, S. B., Höfler, M., Müller, S., Mittemeijer, E. J., & Institute for Materials Science, University of Stuttgart, Heisenbergstraße 3, D-70569 Stuttgart. Discovery of a thermally persistent h.c.p. solid-solution phase in the Ni-W system. United States. doi:10.1063/1.4894148.
Kurz, S. J. B., E-mail: s.kurz@is.mpg.de, Leineweber, A., Maisel, S. B., Höfler, M., Müller, S., Mittemeijer, E. J., and Institute for Materials Science, University of Stuttgart, Heisenbergstraße 3, D-70569 Stuttgart. Thu . "Discovery of a thermally persistent h.c.p. solid-solution phase in the Ni-W system". United States. doi:10.1063/1.4894148.
@article{osti_22314331,
title = {Discovery of a thermally persistent h.c.p. solid-solution phase in the Ni-W system},
author = {Kurz, S. J. B., E-mail: s.kurz@is.mpg.de and Leineweber, A. and Maisel, S. B. and Höfler, M. and Müller, S. and Mittemeijer, E. J. and Institute for Materials Science, University of Stuttgart, Heisenbergstraße 3, D-70569 Stuttgart},
abstractNote = {Although the accepted Ni-W phase diagram does not reveal the existence of h.c.p.-based phases, h.c.p.-like stacking sequences were observed in magnetron-co-sputtered Ni-W thin films at W contents of 20 to 25 at. %, by using transmission electron microscopy and X-ray diffraction. The occurrence of this h.c.p.-like solid-solution phase could be rationalized by first-principles calculations, showing that the vicinity of the system's ground-state line is populated with metastable h.c.p.-based superstructures in the intermediate concentration range from 20 to 50 at. % W. The h.c.p.-like stacking in Ni-W films was observed to be thermally persistent, up to temperatures as high as at least 850 K, as evidenced by extensive X-ray diffraction analyses on specimens before and after annealing treatments. The tendency of Ni-W for excessive planar faulting is discussed in the light of these new findings.},
doi = {10.1063/1.4894148},
journal = {Journal of Applied Physics},
number = 8,
volume = 116,
place = {United States},
year = {Thu Aug 28 00:00:00 EDT 2014},
month = {Thu Aug 28 00:00:00 EDT 2014}
}