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Title: Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one]

Abstract

The title compound, C{sub 30}H{sub 24}N{sub 2}O{sub 4}, 3,3′-[1,2-ethanediyl-bis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one] was synthesized and characterized by elemental analysis, FT-IR spectra, {sup 1}H NMR, and X-ray single-crystal diffraction. In the molecule, the pyridine plane and the adjacent phenyl plane are almost coplanar with the dihedral angle of 3.07°, while the dihedral angle between the mean planes of the two asymmetric units is 67.56°. The crystal packing is stabilized by weak intermolecular C-H...N and C-H...O hydrogen bonds, C-H...π and π...π stacking interactions.

Authors:
; ; ;  [1]
  1. Yuncheng University, Department of Applied Chemistry (China)
Publication Date:
OSTI Identifier:
22311401
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 58; Journal Issue: 7; Other Information: Copyright (c) 2013 Pleiades Publishing, Inc.; http://www.springer-ny.com; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; ALDEHYDES; CRYSTAL STRUCTURE; FOURIER TRANSFORMATION; INFRARED SPECTRA; KETONES; MONOCRYSTALS; NUCLEAR MAGNETIC RESONANCE; PHENYLENE RADICALS; PYRIDINE; PYRIDYL RADICALS; X-RAY DIFFRACTION

Citation Formats

Wang, G.-F., E-mail: wgf1979@126.com, Gong, Q.-J., E-mail: gqjuan@163.com, Sun, H., and Yao, C-Z. Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one]. United States: N. p., 2013. Web. doi:10.1134/S1063774513080105.
Wang, G.-F., E-mail: wgf1979@126.com, Gong, Q.-J., E-mail: gqjuan@163.com, Sun, H., & Yao, C-Z. Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one]. United States. doi:10.1134/S1063774513080105.
Wang, G.-F., E-mail: wgf1979@126.com, Gong, Q.-J., E-mail: gqjuan@163.com, Sun, H., and Yao, C-Z. Sun . "Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one]". United States. doi:10.1134/S1063774513080105.
@article{osti_22311401,
title = {Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one]},
author = {Wang, G.-F., E-mail: wgf1979@126.com and Gong, Q.-J., E-mail: gqjuan@163.com and Sun, H. and Yao, C-Z.},
abstractNote = {The title compound, C{sub 30}H{sub 24}N{sub 2}O{sub 4}, 3,3′-[1,2-ethanediyl-bis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one] was synthesized and characterized by elemental analysis, FT-IR spectra, {sup 1}H NMR, and X-ray single-crystal diffraction. In the molecule, the pyridine plane and the adjacent phenyl plane are almost coplanar with the dihedral angle of 3.07°, while the dihedral angle between the mean planes of the two asymmetric units is 67.56°. The crystal packing is stabilized by weak intermolecular C-H...N and C-H...O hydrogen bonds, C-H...π and π...π stacking interactions.},
doi = {10.1134/S1063774513080105},
journal = {Crystallography Reports},
number = 7,
volume = 58,
place = {United States},
year = {Sun Dec 15 00:00:00 EST 2013},
month = {Sun Dec 15 00:00:00 EST 2013}
}