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Title: Resonant nature of intrinsic defect energy levels in PbTe revealed by infrared photoreflectance spectroscopy

Abstract

Step-scan Fourier-transform infrared photoreflectance and modulated photoluminescence spectroscopy were used to characterize the optical transitions of the epitaxial PbTe thin film grown by molecular beam epitaxy on BaF{sub 2} (111) substrate in the vicinity of energy gap of lead telluride at 77 K. It is found that the intrinsic defect energy levels in the electronic structure are of resonant nature. The Te-vacancy energy level is located above the conduction band minimum by 29.1 meV. Another defect (V{sub X}) energy level situated below valance band maximum by 18.1 meV is also revealed. Whether it is associated with the Pb vacancy is still not clear. It might also be related to the misfit dislocations stemming from the lattice mismatch between PbTe and BaF{sub 2} substrate. The experimental results support the theory prediction (N. J. Parada and G. W. Pratt, Jr., Phys. Rev. Lett. 22, 180 (1969), N. J. Parada, Phys. Rev. B 3, 2042 (1971)) and are consistent with the reported Hall experimental results (G. Bauer, H. Burkhard, H. Heinrich, and A. Lopez-Otero, J. Appl. Phys. 47, 1721 (1976)).

Authors:
; ; ; ;  [1];  [2]
  1. Department of Physics and State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou, Zhejiang 310027 (China)
  2. National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083 (China)
Publication Date:
OSTI Identifier:
22311082
Resource Type:
Journal Article
Resource Relation:
Journal Name: Applied Physics Letters; Journal Volume: 105; Journal Issue: 2; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ACTIVATION ENERGY; BARIUM FLUORIDES; CRYSTAL DEFECTS; DISLOCATIONS; ELECTRONIC STRUCTURE; ENERGY GAP; FORECASTING; FOURIER TRANSFORM SPECTROMETERS; LEAD TELLURIDES; MOLECULAR BEAM EPITAXY; PHOTOLUMINESCENCE; SPECTROSCOPY; SUBSTRATES; THIN FILMS; VACANCIES

Citation Formats

Zhang, Bingpo, Cai, Chunfeng, Jin, Shuqiang, Ye, Zhenyu, Wu, Huizhen, E-mail: hzwu@zju.edu.cn, and Qi, Zhen. Resonant nature of intrinsic defect energy levels in PbTe revealed by infrared photoreflectance spectroscopy. United States: N. p., 2014. Web. doi:10.1063/1.4890621.
Zhang, Bingpo, Cai, Chunfeng, Jin, Shuqiang, Ye, Zhenyu, Wu, Huizhen, E-mail: hzwu@zju.edu.cn, & Qi, Zhen. Resonant nature of intrinsic defect energy levels in PbTe revealed by infrared photoreflectance spectroscopy. United States. doi:10.1063/1.4890621.
Zhang, Bingpo, Cai, Chunfeng, Jin, Shuqiang, Ye, Zhenyu, Wu, Huizhen, E-mail: hzwu@zju.edu.cn, and Qi, Zhen. Mon . "Resonant nature of intrinsic defect energy levels in PbTe revealed by infrared photoreflectance spectroscopy". United States. doi:10.1063/1.4890621.
@article{osti_22311082,
title = {Resonant nature of intrinsic defect energy levels in PbTe revealed by infrared photoreflectance spectroscopy},
author = {Zhang, Bingpo and Cai, Chunfeng and Jin, Shuqiang and Ye, Zhenyu and Wu, Huizhen, E-mail: hzwu@zju.edu.cn and Qi, Zhen},
abstractNote = {Step-scan Fourier-transform infrared photoreflectance and modulated photoluminescence spectroscopy were used to characterize the optical transitions of the epitaxial PbTe thin film grown by molecular beam epitaxy on BaF{sub 2} (111) substrate in the vicinity of energy gap of lead telluride at 77 K. It is found that the intrinsic defect energy levels in the electronic structure are of resonant nature. The Te-vacancy energy level is located above the conduction band minimum by 29.1 meV. Another defect (V{sub X}) energy level situated below valance band maximum by 18.1 meV is also revealed. Whether it is associated with the Pb vacancy is still not clear. It might also be related to the misfit dislocations stemming from the lattice mismatch between PbTe and BaF{sub 2} substrate. The experimental results support the theory prediction (N. J. Parada and G. W. Pratt, Jr., Phys. Rev. Lett. 22, 180 (1969), N. J. Parada, Phys. Rev. B 3, 2042 (1971)) and are consistent with the reported Hall experimental results (G. Bauer, H. Burkhard, H. Heinrich, and A. Lopez-Otero, J. Appl. Phys. 47, 1721 (1976)).},
doi = {10.1063/1.4890621},
journal = {Applied Physics Letters},
number = 2,
volume = 105,
place = {United States},
year = {Mon Jul 14 00:00:00 EDT 2014},
month = {Mon Jul 14 00:00:00 EDT 2014}
}
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