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Title: Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam

Abstract

We present a novel method of delivering a low-concentration (<15%) ozone beam to an ultra-high vacuum environment for the purpose of cleaning and dosing experimental samples through oxidation processing. The system described is safe, low-cost, and practical and overcomes the limitations of ozone transport in the molecular flow environment of high or ultrahigh vacuum whilst circumventing the use of pure ozone gas which is potentially highly explosive. The effectiveness of this method in removing surface contamination is demonstrated through comparison of high-temperature annealing of a simple oxide (MgO) in ozone and oxygen environments as monitored using quadrupole mass spectroscopy and Auger electron spectroscopy. Additionally, we demonstrate the potential of ozone for obtaining clean complex oxide surfaces without the need for high-temperature annealing which may significantly alter surface structure.

Authors:
 [1];  [2]; ; ;  [3];  [4];  [1]
  1. National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)
  2. (United Kingdom)
  3. CNR – ISMN, Consiglio Nazionale delle Ricerche – Istituto per lo Studio dei Materiali Nanostrutturati, v. Gobetti 101, 40129 Bologna (Italy)
  4. Department of Electrical and Computer Engineering, Harold Frank Hall, University of California, Santa Barbara, California 93106 (United States)
Publication Date:
OSTI Identifier:
22308963
Resource Type:
Journal Article
Resource Relation:
Journal Name: Review of Scientific Instruments; Journal Volume: 85; Journal Issue: 7; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; ABUNDANCE; ANNEALING; AUGER ELECTRON SPECTROSCOPY; BEAMS; CONCENTRATION RATIO; MAGNESIUM OXIDES; MASS SPECTROSCOPY; OXIDATION; OZONE; PRESSURE RANGE NANO PA; SURFACE CLEANING; SURFACE CONTAMINATION; TEMPERATURE RANGE 0065-0273 K; TEMPERATURE RANGE 0400-1000 K

Citation Formats

Pratt, A., Department of Physics, University of York, Heslington, York YO10 5DD, Graziosi, P., Bergenti, I., Dediu, A., Prezioso, M., and Yamauchi, Y., E-mail: yamauchi.yasushi@nims.go.jp. Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam. United States: N. p., 2014. Web. doi:10.1063/1.4890208.
Pratt, A., Department of Physics, University of York, Heslington, York YO10 5DD, Graziosi, P., Bergenti, I., Dediu, A., Prezioso, M., & Yamauchi, Y., E-mail: yamauchi.yasushi@nims.go.jp. Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam. United States. doi:10.1063/1.4890208.
Pratt, A., Department of Physics, University of York, Heslington, York YO10 5DD, Graziosi, P., Bergenti, I., Dediu, A., Prezioso, M., and Yamauchi, Y., E-mail: yamauchi.yasushi@nims.go.jp. Tue . "Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam". United States. doi:10.1063/1.4890208.
@article{osti_22308963,
title = {Ultrahigh vacuum and low-temperature cleaning of oxide surfaces using a low-concentration ozone beam},
author = {Pratt, A. and Department of Physics, University of York, Heslington, York YO10 5DD and Graziosi, P. and Bergenti, I. and Dediu, A. and Prezioso, M. and Yamauchi, Y., E-mail: yamauchi.yasushi@nims.go.jp},
abstractNote = {We present a novel method of delivering a low-concentration (<15%) ozone beam to an ultra-high vacuum environment for the purpose of cleaning and dosing experimental samples through oxidation processing. The system described is safe, low-cost, and practical and overcomes the limitations of ozone transport in the molecular flow environment of high or ultrahigh vacuum whilst circumventing the use of pure ozone gas which is potentially highly explosive. The effectiveness of this method in removing surface contamination is demonstrated through comparison of high-temperature annealing of a simple oxide (MgO) in ozone and oxygen environments as monitored using quadrupole mass spectroscopy and Auger electron spectroscopy. Additionally, we demonstrate the potential of ozone for obtaining clean complex oxide surfaces without the need for high-temperature annealing which may significantly alter surface structure.},
doi = {10.1063/1.4890208},
journal = {Review of Scientific Instruments},
number = 7,
volume = 85,
place = {United States},
year = {Tue Jul 15 00:00:00 EDT 2014},
month = {Tue Jul 15 00:00:00 EDT 2014}
}