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Title: Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures

Abstract

The average density of D{sub 2}O confined in a nanoporous silica matrix (MCM-41-S) is studied with neutron scattering. We find that below ∼210 K, the pressure-temperature plane of the system can be divided into two regions. The average density of the confined D{sub 2}O in the higher-pressure region is about 16% larger than that in the lower-pressure region. These two regions could represent the so-called “low-density liquid” and “high-density liquid” phases. The dividing line of these two regions, which could represent the associated 1st order liquid-liquid transition line, is also determined.

Authors:
;  [1];  [1]; ;  [2]
  1. Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)
  2. National Institute of Standards and Technology Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States)
Publication Date:
OSTI Identifier:
22308754
Resource Type:
Journal Article
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 141; Journal Issue: 1; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-9606
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; DENSITY; HEAVY WATER; LIQUIDS; NEUTRON DIFFRACTION; SILICA

Citation Formats

Wang, Zhe, Chen, Sow-Hsin, Liu, Kao-Hsiang, Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan, Harriger, Leland, and Leão, Juscelino B. Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures. United States: N. p., 2014. Web. doi:10.1063/1.4885844.
Wang, Zhe, Chen, Sow-Hsin, Liu, Kao-Hsiang, Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan, Harriger, Leland, & Leão, Juscelino B. Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures. United States. https://doi.org/10.1063/1.4885844
Wang, Zhe, Chen, Sow-Hsin, Liu, Kao-Hsiang, Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan, Harriger, Leland, and Leão, Juscelino B. Mon . "Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures". United States. https://doi.org/10.1063/1.4885844.
@article{osti_22308754,
title = {Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures},
author = {Wang, Zhe and Chen, Sow-Hsin and Liu, Kao-Hsiang and Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan and Harriger, Leland and Leão, Juscelino B.},
abstractNote = {The average density of D{sub 2}O confined in a nanoporous silica matrix (MCM-41-S) is studied with neutron scattering. We find that below ∼210 K, the pressure-temperature plane of the system can be divided into two regions. The average density of the confined D{sub 2}O in the higher-pressure region is about 16% larger than that in the lower-pressure region. These two regions could represent the so-called “low-density liquid” and “high-density liquid” phases. The dividing line of these two regions, which could represent the associated 1st order liquid-liquid transition line, is also determined.},
doi = {10.1063/1.4885844},
url = {https://www.osti.gov/biblio/22308754}, journal = {Journal of Chemical Physics},
issn = {0021-9606},
number = 1,
volume = 141,
place = {United States},
year = {2014},
month = {7}
}