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Title: Synthesis and characterization of ester and amide derivatives of titanium(IV) carboxymethylphosphonate

Abstract

A set of layered ester and amide derivatives of titanium(IV) carboxymethylphosphonate was prepared by solvothermal treatment of amorphous titanium(IV) carboxymethylphosphonate with corresponding 1-alkanols, 1,ω-alkanediols, 1-aminoalkanes, 1,ω-diaminoalkanes and 1,ω-amino alcohols and characterized by powder X-ray diffraction, IR spectroscopy and thermogravimetric analysis. Whereas alkyl chains with one functional group form bilayers tilted to the layers, 1,ω-diaminoalkanes and most of 1,ω-alkanediols form bridges connecting the adjacent layers. In the case of amino alcohols, the alkyl chains form bilayer and either hydroxyl or amino group is used for bonding. This simple method for the synthesis of ester and amide derivatives does not require preparation of acid chloride derivative as a precursor or pre-intercalation with alkylamines and can be used also for the preparation of ester and amide derivatives of titanium carboxyethylphosphonate and zirconium carboxymethylphosphonate. - Graphical abstract: Ester and amide derivatives of layered titanium carboxymethylphosphonate were prepared by solvothermal treatment of amorphous solid with alkanol or alkylamine. - Highlights: • Ester and amide derivatives of titanium carboxymethylphosphonate. • Solvothermal treatment of amorphous solid with alkanol or alkylamine. • Ester and amide formation confirmed by IR spectroscopy.

Authors:
 [1];  [2]; ; ;  [1]
  1. Institute of Macromolecular Chemistry of Academy of Sciences of the Czech Republic, Heyrovský Square 2, 162 06 Prague (Czech Republic)
  2. University of Pardubice, Faculty of Chemical Technology, Studentská 95, 532 10 Pardubice (Czech Republic)
Publication Date:
OSTI Identifier:
22306319
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 202; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CLATHRATES; ESTERS; INFRARED SPECTRA; SOLIDS; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; TITANIUM; X-RAY DIFFRACTION; ZIRCONIUM

Citation Formats

Melánová, Klára, E-mail: klara.melanova@upce.cz, Beneš, Ludvík, Trchová, Miroslava, Svoboda, Jan, and Zima, Vítězslav. Synthesis and characterization of ester and amide derivatives of titanium(IV) carboxymethylphosphonate. United States: N. p., 2013. Web. doi:10.1016/J.JSSC.2013.03.031.
Melánová, Klára, E-mail: klara.melanova@upce.cz, Beneš, Ludvík, Trchová, Miroslava, Svoboda, Jan, & Zima, Vítězslav. Synthesis and characterization of ester and amide derivatives of titanium(IV) carboxymethylphosphonate. United States. doi:10.1016/J.JSSC.2013.03.031.
Melánová, Klára, E-mail: klara.melanova@upce.cz, Beneš, Ludvík, Trchová, Miroslava, Svoboda, Jan, and Zima, Vítězslav. 2013. "Synthesis and characterization of ester and amide derivatives of titanium(IV) carboxymethylphosphonate". United States. doi:10.1016/J.JSSC.2013.03.031.
@article{osti_22306319,
title = {Synthesis and characterization of ester and amide derivatives of titanium(IV) carboxymethylphosphonate},
author = {Melánová, Klára, E-mail: klara.melanova@upce.cz and Beneš, Ludvík and Trchová, Miroslava and Svoboda, Jan and Zima, Vítězslav},
abstractNote = {A set of layered ester and amide derivatives of titanium(IV) carboxymethylphosphonate was prepared by solvothermal treatment of amorphous titanium(IV) carboxymethylphosphonate with corresponding 1-alkanols, 1,ω-alkanediols, 1-aminoalkanes, 1,ω-diaminoalkanes and 1,ω-amino alcohols and characterized by powder X-ray diffraction, IR spectroscopy and thermogravimetric analysis. Whereas alkyl chains with one functional group form bilayers tilted to the layers, 1,ω-diaminoalkanes and most of 1,ω-alkanediols form bridges connecting the adjacent layers. In the case of amino alcohols, the alkyl chains form bilayer and either hydroxyl or amino group is used for bonding. This simple method for the synthesis of ester and amide derivatives does not require preparation of acid chloride derivative as a precursor or pre-intercalation with alkylamines and can be used also for the preparation of ester and amide derivatives of titanium carboxyethylphosphonate and zirconium carboxymethylphosphonate. - Graphical abstract: Ester and amide derivatives of layered titanium carboxymethylphosphonate were prepared by solvothermal treatment of amorphous solid with alkanol or alkylamine. - Highlights: • Ester and amide derivatives of titanium carboxymethylphosphonate. • Solvothermal treatment of amorphous solid with alkanol or alkylamine. • Ester and amide formation confirmed by IR spectroscopy.},
doi = {10.1016/J.JSSC.2013.03.031},
journal = {Journal of Solid State Chemistry},
number = ,
volume = 202,
place = {United States},
year = 2013,
month = 6
}
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