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Title: Preparation and characterization of SiO₂:Sm³⁺ nanotube arrays with 1.06 μm laser antireflective property

Journal Article · · Journal of Solid State Chemistry
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  1. National Engineering Research Center for Coatings, CNOOC Changzhou Paint and Coatings Industry Research Institute, Changzhou 213016 (China)
  2. National Quality Supervision and Test Center for Coatings, CNOOC Changzhou Paint and Coatings Industry Research Institute, Changzhou 213016 (China)
  3. Institute of Joint Bioenergy, Nanjing University of Technology, Nanjing 210009 (China)
  4. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China)

SiO₂: Sm³⁺ nanotube arrays with excellent antireflective property at 1.06 μm were synthesized by a template-assisted sol–gel process. The molecular structure, morphology and optical properties of the fabricated SiO₂:Sm³⁺ nanotube arrays were investigated by a Fourier transform infrared spectroscope (FTIR), a Scanning electron microscope (SEM), and a spectro-fluorometer, respectively. The experimental results demonstrate that the SiO₂:Sm³⁺ nanotube arrays were formed via the AAO membrane during the sol–gel process. The remarkable antireflective characteristic of about 0.166% at 1.06 μm was attributed to the drastic decrease of effective refraction index which enhances the matching effect between air and substrate. As well as the absorption performance of Sm³⁺ at 1.06 μm which consumes the energies of incident light. - Graphical abstract: Directional aligned SiO₂:Sm³⁺ nanotube arrays were synthesized in AAO template by sol–gel process, and the antiflective performance of arrays is prominent comparing to the blank AAO template. Highlights: • SiO₂:Sm³⁺ nanotube arrays are synthesized by a template-assisted sol–gel process. • SiO₂:Sm³⁺ nanotube arrays have remarkable antireflective properties at 1.06 μm. • The subwavelength structure results in a decrease of effective refraction index. • The absorption performance of Sm³⁺ at 1.06 μm consume the energies of incident light.

OSTI ID:
22306259
Journal Information:
Journal of Solid State Chemistry, Vol. 201; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
Country of Publication:
United States
Language:
English