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Title: Efficient methylammonium lead iodide perovskite solar cells with active layers from 300 to 900 nm

Abstract

Efficient methylammonium lead iodide perovskite-based solar cells have been prepared in which the perovskite layer is sandwiched in between two organic charge transporting layers that block holes and electrons, respectively. This configuration leads to stable and reproducible devices that do not suffer from strong hysteresis effects and when optimized lead to efficiencies close to 15%. The perovskite layer is formed by using a dual-source thermal evaporation method, whereas the organic layers are processed from solution. The dual-source thermal evaporation method leads to smooth films and allows for high precision thickness variations. Devices were prepared with perovskite layer thicknesses ranging from 160 to 900 nm. The short-circuit current observed for these devices increased with increasing perovskite layer thickness. The main parameter that decreases with increasing perovskite layer thickness is the fill factor and as a result optimum device performance is obtained for perovskite layer thickness around 300 nm. However, here we demonstrate that with a slightly oxidized electron blocking layer the fill factor for the solar cells with a perovskite layer thickness of 900 nm increases to the same values as for the devices with thin perovskite layers. As a result the power conversion efficiencies for the cells with 300 andmore » 900 nm are very similar, 12.7% and 12%, respectively.« less

Authors:
; ; ; ; ; ;  [1];  [1];  [2];  [3]
  1. Instituto de Ciencia Molecular, Universidad de Valencia, C/Catedrático J. Beltrán 2, 46980 Paterna, Valencia (Spain)
  2. (Spain)
  3. Department of Materials and Interfaces, Weizmann Institute of Science, Herzl St. 34, Rehovot 76100 (Israel)
Publication Date:
OSTI Identifier:
22303734
Resource Type:
Journal Article
Resource Relation:
Journal Name: APL Materials; Journal Volume: 2; Journal Issue: 8; Other Information: (c) 2014 Author(s); Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ACCURACY; DEPLETION LAYER; EFFICIENCY; ELECTRICAL FAULTS; EVAPORATION; FILL FACTORS; FILMS; HYSTERESIS; LEAD IODIDES; PEROVSKITE; SOLAR CELLS; THICKNESS

Citation Formats

Momblona, C., Malinkiewicz, O., Soriano, A., Gil-Escrig, L., Bandiello, E., Scheepers, M., Bolink, H. J., E-mail: henk.bolink@uv.es, Roldán-Carmona, C., Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Rabanales, Ed. C3, 14014, Córdoba, and Edri, E. Efficient methylammonium lead iodide perovskite solar cells with active layers from 300 to 900 nm. United States: N. p., 2014. Web. doi:10.1063/1.4890056.
Momblona, C., Malinkiewicz, O., Soriano, A., Gil-Escrig, L., Bandiello, E., Scheepers, M., Bolink, H. J., E-mail: henk.bolink@uv.es, Roldán-Carmona, C., Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Rabanales, Ed. C3, 14014, Córdoba, & Edri, E. Efficient methylammonium lead iodide perovskite solar cells with active layers from 300 to 900 nm. United States. doi:10.1063/1.4890056.
Momblona, C., Malinkiewicz, O., Soriano, A., Gil-Escrig, L., Bandiello, E., Scheepers, M., Bolink, H. J., E-mail: henk.bolink@uv.es, Roldán-Carmona, C., Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Rabanales, Ed. C3, 14014, Córdoba, and Edri, E. Fri . "Efficient methylammonium lead iodide perovskite solar cells with active layers from 300 to 900 nm". United States. doi:10.1063/1.4890056.
@article{osti_22303734,
title = {Efficient methylammonium lead iodide perovskite solar cells with active layers from 300 to 900 nm},
author = {Momblona, C. and Malinkiewicz, O. and Soriano, A. and Gil-Escrig, L. and Bandiello, E. and Scheepers, M. and Bolink, H. J., E-mail: henk.bolink@uv.es and Roldán-Carmona, C. and Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Rabanales, Ed. C3, 14014, Córdoba and Edri, E.},
abstractNote = {Efficient methylammonium lead iodide perovskite-based solar cells have been prepared in which the perovskite layer is sandwiched in between two organic charge transporting layers that block holes and electrons, respectively. This configuration leads to stable and reproducible devices that do not suffer from strong hysteresis effects and when optimized lead to efficiencies close to 15%. The perovskite layer is formed by using a dual-source thermal evaporation method, whereas the organic layers are processed from solution. The dual-source thermal evaporation method leads to smooth films and allows for high precision thickness variations. Devices were prepared with perovskite layer thicknesses ranging from 160 to 900 nm. The short-circuit current observed for these devices increased with increasing perovskite layer thickness. The main parameter that decreases with increasing perovskite layer thickness is the fill factor and as a result optimum device performance is obtained for perovskite layer thickness around 300 nm. However, here we demonstrate that with a slightly oxidized electron blocking layer the fill factor for the solar cells with a perovskite layer thickness of 900 nm increases to the same values as for the devices with thin perovskite layers. As a result the power conversion efficiencies for the cells with 300 and 900 nm are very similar, 12.7% and 12%, respectively.},
doi = {10.1063/1.4890056},
journal = {APL Materials},
number = 8,
volume = 2,
place = {United States},
year = {Fri Aug 01 00:00:00 EDT 2014},
month = {Fri Aug 01 00:00:00 EDT 2014}
}