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Title: Hierarchical mesoporous/microporous carbon with graphitized frameworks for high-performance lithium-ion batteries

Abstract

A hierarchical meso-/micro-porous graphitized carbon with uniform mesopores and ordered micropores, graphitized frameworks, and extra-high surface area of ∼2200 m{sup 2}/g, was successfully synthesized through a simple one-step chemical vapor deposition process. The commercial mesoporous zeolite Y was utilized as a meso-/ micro-porous template, and the small-molecule methane was employed as a carbon precursor. The as-prepared hierarchical meso-/micro-porous carbons have homogeneously distributed mesopores as a host for electrolyte, which facilitate Li{sup +} ions transport to the large-area micropores, resulting a high reversible lithium ion storage of 1000 mA h/g and a high columbic efficiency of 65% at the first cycle.

Authors:
; ; ;  [1];  [2];  [3];  [1]
  1. Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Laboratory of Advanced Materials, Fudan University, Shanghai 200433 (China)
  2. Department of Chemical Engineering, Monash University, Clayton, VIC 3800 (Australia)
  3. Chemistry Department and The Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589 (Saudi Arabia)
Publication Date:
OSTI Identifier:
22303407
Resource Type:
Journal Article
Journal Name:
APL Materials
Additional Journal Information:
Journal Volume: 2; Journal Issue: 11; Other Information: (c) 2014 Author(s); Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 2166-532X
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; CARBON; CHEMICAL VAPOR DEPOSITION; EFFICIENCY; ELECTRIC BATTERIES; ELECTROLYTES; LITHIUM IONS; NANOSTRUCTURES; POROUS MATERIALS; ZEOLITES

Citation Formats

Lv, Yingying, Fang, Yin, Qian, Xufang, Tu, Bo, Wu, Zhangxiong, Asiri, Abdullah M., Zhao, Dongyuan, and Department of Chemical Engineering, Monash University, Clayton, VIC 3800. Hierarchical mesoporous/microporous carbon with graphitized frameworks for high-performance lithium-ion batteries. United States: N. p., 2014. Web. doi:10.1063/1.4897201.
Lv, Yingying, Fang, Yin, Qian, Xufang, Tu, Bo, Wu, Zhangxiong, Asiri, Abdullah M., Zhao, Dongyuan, & Department of Chemical Engineering, Monash University, Clayton, VIC 3800. Hierarchical mesoporous/microporous carbon with graphitized frameworks for high-performance lithium-ion batteries. United States. https://doi.org/10.1063/1.4897201
Lv, Yingying, Fang, Yin, Qian, Xufang, Tu, Bo, Wu, Zhangxiong, Asiri, Abdullah M., Zhao, Dongyuan, and Department of Chemical Engineering, Monash University, Clayton, VIC 3800. 2014. "Hierarchical mesoporous/microporous carbon with graphitized frameworks for high-performance lithium-ion batteries". United States. https://doi.org/10.1063/1.4897201.
@article{osti_22303407,
title = {Hierarchical mesoporous/microporous carbon with graphitized frameworks for high-performance lithium-ion batteries},
author = {Lv, Yingying and Fang, Yin and Qian, Xufang and Tu, Bo and Wu, Zhangxiong and Asiri, Abdullah M. and Zhao, Dongyuan and Department of Chemical Engineering, Monash University, Clayton, VIC 3800},
abstractNote = {A hierarchical meso-/micro-porous graphitized carbon with uniform mesopores and ordered micropores, graphitized frameworks, and extra-high surface area of ∼2200 m{sup 2}/g, was successfully synthesized through a simple one-step chemical vapor deposition process. The commercial mesoporous zeolite Y was utilized as a meso-/ micro-porous template, and the small-molecule methane was employed as a carbon precursor. The as-prepared hierarchical meso-/micro-porous carbons have homogeneously distributed mesopores as a host for electrolyte, which facilitate Li{sup +} ions transport to the large-area micropores, resulting a high reversible lithium ion storage of 1000 mA h/g and a high columbic efficiency of 65% at the first cycle.},
doi = {10.1063/1.4897201},
url = {https://www.osti.gov/biblio/22303407}, journal = {APL Materials},
issn = {2166-532X},
number = 11,
volume = 2,
place = {United States},
year = {Sat Nov 01 00:00:00 EDT 2014},
month = {Sat Nov 01 00:00:00 EDT 2014}
}