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Title: Multifunctional Fe{sub 3}O{sub 4}@C@Ag hybrid nanoparticles: Aqueous solution preparation, characterization and photocatalytic activity

Abstract

Highlights: ► Ag-loaded Fe{sub 3}O{sub 4}@C magnetic-optical bifunctional materials have been investigated. ► The magnetism was studied at the room temperature. ► The photocatalytic activity was evaluated under visible light irradiation. ► Ag-loaded Fe{sub 3}O{sub 4}@C nanocomposites show superior magnetism and photocatalytic activity. ► A simple synthetic process was discussed. - Abstract: The paper describes a kind of multifunctional Fe{sub 3}O{sub 4}@C@Ag hybrid nanoparticles, which can be successfully synthesized using a simple route based on directly adsorption and spontaneous reduction of silver ions onto the surface shell of carbon-coated magnetic nanoparticles. The as-prepared samples have been characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), Fourier transform infrared (FT-IR) spectrum, vibrating sample magnetometer (VSM) and UV–vis spectrum (UV–vis). The Ag nanocrystals loaded on the surface shell of carbon-coated magnetic nanoparticles are nearly spherical with an average diameter of 10 nm. And the carbonaceous polysaccharides shell obtained using an glucose hydrothermal reaction act as a role of a bridge between magnetic Fe{sub 3}O{sub 4} core and noble metallic Ag nanocrystals. The as-prepared samples can be used as an effective catalyst for the photodegradation of organic dyes (neutral red) under the exposure of visible light. Results show that the as-prepared samplesmore » have a degradation rate of 93.7% for dyes within 30 min, which indicates their high-efficiency and rapid photocatalytic activity.« less

Authors:
 [1];  [1]; ; ; ; ;  [1]
  1. School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039 (China)
Publication Date:
OSTI Identifier:
22290450
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 48; Journal Issue: 7; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ABSORPTION SPECTROSCOPY; AQUEOUS SOLUTIONS; COMPOSITE MATERIALS; FERRITES; HYDROTHERMAL SYNTHESIS; INFRARED SPECTRA; IRON OXIDES; NANOSTRUCTURES; PARTICLES; PHOTOCATALYSIS; POLYSACCHARIDES; SILVER IONS; TRANSMISSION ELECTRON MICROSCOPY; VIBRATING SAMPLE MAGNETOMETERS

Citation Formats

Liang, Hongxia, Niu, Helin, Li, Ping, Tao, Zhiyin, Mao, Changjie, Song, Jiming, and Zhang, Shengyi. Multifunctional Fe{sub 3}O{sub 4}@C@Ag hybrid nanoparticles: Aqueous solution preparation, characterization and photocatalytic activity. United States: N. p., 2013. Web. doi:10.1016/J.MATERRESBULL.2013.02.066.
Liang, Hongxia, Niu, Helin, Li, Ping, Tao, Zhiyin, Mao, Changjie, Song, Jiming, & Zhang, Shengyi. Multifunctional Fe{sub 3}O{sub 4}@C@Ag hybrid nanoparticles: Aqueous solution preparation, characterization and photocatalytic activity. United States. https://doi.org/10.1016/J.MATERRESBULL.2013.02.066
Liang, Hongxia, Niu, Helin, Li, Ping, Tao, Zhiyin, Mao, Changjie, Song, Jiming, and Zhang, Shengyi. Mon . "Multifunctional Fe{sub 3}O{sub 4}@C@Ag hybrid nanoparticles: Aqueous solution preparation, characterization and photocatalytic activity". United States. https://doi.org/10.1016/J.MATERRESBULL.2013.02.066.
@article{osti_22290450,
title = {Multifunctional Fe{sub 3}O{sub 4}@C@Ag hybrid nanoparticles: Aqueous solution preparation, characterization and photocatalytic activity},
author = {Liang, Hongxia and Niu, Helin and Li, Ping and Tao, Zhiyin and Mao, Changjie and Song, Jiming and Zhang, Shengyi},
abstractNote = {Highlights: ► Ag-loaded Fe{sub 3}O{sub 4}@C magnetic-optical bifunctional materials have been investigated. ► The magnetism was studied at the room temperature. ► The photocatalytic activity was evaluated under visible light irradiation. ► Ag-loaded Fe{sub 3}O{sub 4}@C nanocomposites show superior magnetism and photocatalytic activity. ► A simple synthetic process was discussed. - Abstract: The paper describes a kind of multifunctional Fe{sub 3}O{sub 4}@C@Ag hybrid nanoparticles, which can be successfully synthesized using a simple route based on directly adsorption and spontaneous reduction of silver ions onto the surface shell of carbon-coated magnetic nanoparticles. The as-prepared samples have been characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), Fourier transform infrared (FT-IR) spectrum, vibrating sample magnetometer (VSM) and UV–vis spectrum (UV–vis). The Ag nanocrystals loaded on the surface shell of carbon-coated magnetic nanoparticles are nearly spherical with an average diameter of 10 nm. And the carbonaceous polysaccharides shell obtained using an glucose hydrothermal reaction act as a role of a bridge between magnetic Fe{sub 3}O{sub 4} core and noble metallic Ag nanocrystals. The as-prepared samples can be used as an effective catalyst for the photodegradation of organic dyes (neutral red) under the exposure of visible light. Results show that the as-prepared samples have a degradation rate of 93.7% for dyes within 30 min, which indicates their high-efficiency and rapid photocatalytic activity.},
doi = {10.1016/J.MATERRESBULL.2013.02.066},
url = {https://www.osti.gov/biblio/22290450}, journal = {Materials Research Bulletin},
issn = {0025-5408},
number = 7,
volume = 48,
place = {United States},
year = {2013},
month = {7}
}