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Title: Facile synthesis of Cu/Cu{sub x}O nanoarchitectures with adjustable phase composition for effective NO{sub x} gas sensor at room temperature

Abstract

Graphical abstract: The Cu/Cu{sub x}O nanoarchitectures with 30–70 nm hollow nanospheres reduced by 3 mmol NaBH{sub 4} exhibits excellent gas-sensing property to low-concentration NO{sub x} gas at room temperature. - Highlights: • The Cu/Cu{sub x}O nanoarchitectures with hollow nanospheres are successfully synthesized. • The method is used for preparing the with Cu/Cu{sub x}O adjustable phase composition. • The C3 sample exhibites excellent gas-sensing propertie to NO{sub x} at room temperation. • The Cu/Cu{sub x}O nanoarchitectures have significant for application of gas sensor. - Abstract: The Cu/Cu{sub x}O nanoarchitectures with 30–70 nm hollow nanospheres are successfully synthesized by a facile wet chemical method. The synthesized products have been studied by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and thermo gravimetric-differential scanning calorimetry (TG-DSC) analysis. The Cu/Cu{sub x}O sensors based on the nanoarchitectures are used to detect the NO{sub x} at room temperature. The results demonstrate that the obtained Cu/Cu{sub x}O nanoarchitectures reduced by 3 mmol NaBH{sub 4} exhibits excellent gas-sensing properties: low detection limit of 0.97 ppm, relatively high sensitivity, short response time, broad linear range and high selectivity. The reasons for gas-sensing activity enhancement on Cu/Cu{sub x}O nanoarchitectures are discussed. The Cu/Cu{sub x}O nanocrystalline withmore » the hierarchical pores structure and tunable compositions have significant for application of gas sensor.« less

Authors:
; ; ;  [1];  [2];  [1];  [1];  [1]
  1. Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Key Laboratory of Physical Chemistry (China)
  2. Department of Chemistry, Harbin Normal University, Harbin 150025 (China)
Publication Date:
OSTI Identifier:
22285092
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 48; Journal Issue: 10; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; CALORIMETRY; CRYSTALS; METALS; NANOSTRUCTURES; NITROGEN OXIDES; PORE STRUCTURE; SCANNING ELECTRON MICROSCOPY; SENSITIVITY; SURFACE PROPERTIES; SYNTHESIS; TEMPERATURE RANGE 0273-0400 K; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION

Citation Formats

Yang, Lixue, Li, Li, Yang, Ying, Zhang, Guo, Gong, Lihong, Jing, Liqiang, Fu, Honggang, and Shi, Keying. Facile synthesis of Cu/Cu{sub x}O nanoarchitectures with adjustable phase composition for effective NO{sub x} gas sensor at room temperature. United States: N. p., 2013. Web. doi:10.1016/J.MATERRESBULL.2013.05.011.
Yang, Lixue, Li, Li, Yang, Ying, Zhang, Guo, Gong, Lihong, Jing, Liqiang, Fu, Honggang, & Shi, Keying. Facile synthesis of Cu/Cu{sub x}O nanoarchitectures with adjustable phase composition for effective NO{sub x} gas sensor at room temperature. United States. doi:10.1016/J.MATERRESBULL.2013.05.011.
Yang, Lixue, Li, Li, Yang, Ying, Zhang, Guo, Gong, Lihong, Jing, Liqiang, Fu, Honggang, and Shi, Keying. Tue . "Facile synthesis of Cu/Cu{sub x}O nanoarchitectures with adjustable phase composition for effective NO{sub x} gas sensor at room temperature". United States. doi:10.1016/J.MATERRESBULL.2013.05.011.
@article{osti_22285092,
title = {Facile synthesis of Cu/Cu{sub x}O nanoarchitectures with adjustable phase composition for effective NO{sub x} gas sensor at room temperature},
author = {Yang, Lixue and Li, Li and Yang, Ying and Zhang, Guo and Gong, Lihong and Jing, Liqiang and Fu, Honggang and Shi, Keying},
abstractNote = {Graphical abstract: The Cu/Cu{sub x}O nanoarchitectures with 30–70 nm hollow nanospheres reduced by 3 mmol NaBH{sub 4} exhibits excellent gas-sensing property to low-concentration NO{sub x} gas at room temperature. - Highlights: • The Cu/Cu{sub x}O nanoarchitectures with hollow nanospheres are successfully synthesized. • The method is used for preparing the with Cu/Cu{sub x}O adjustable phase composition. • The C3 sample exhibites excellent gas-sensing propertie to NO{sub x} at room temperation. • The Cu/Cu{sub x}O nanoarchitectures have significant for application of gas sensor. - Abstract: The Cu/Cu{sub x}O nanoarchitectures with 30–70 nm hollow nanospheres are successfully synthesized by a facile wet chemical method. The synthesized products have been studied by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and thermo gravimetric-differential scanning calorimetry (TG-DSC) analysis. The Cu/Cu{sub x}O sensors based on the nanoarchitectures are used to detect the NO{sub x} at room temperature. The results demonstrate that the obtained Cu/Cu{sub x}O nanoarchitectures reduced by 3 mmol NaBH{sub 4} exhibits excellent gas-sensing properties: low detection limit of 0.97 ppm, relatively high sensitivity, short response time, broad linear range and high selectivity. The reasons for gas-sensing activity enhancement on Cu/Cu{sub x}O nanoarchitectures are discussed. The Cu/Cu{sub x}O nanocrystalline with the hierarchical pores structure and tunable compositions have significant for application of gas sensor.},
doi = {10.1016/J.MATERRESBULL.2013.05.011},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = 10,
volume = 48,
place = {United States},
year = {2013},
month = {10}
}