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Title: Determination of carrier lifetime and mobility in colloidal quantum dot films via impedance spectroscopy

Abstract

Impedance Spectroscopy (IS) proves to be a powerful tool for the determination of carrier lifetime and majority carrier mobility in colloidal quantum dot films. We employ IS to determine the carrier lifetime in PbS quantum dot Schottky solar cells with Al and we verify the validity of the technique via transient photovoltage. We also present a simple approach based on an RC model that allows the determination of carrier mobility in PbS quantum dot films and we corroborate the results via comparison with space charge limited measurements. In summary, we demonstrate the potential of IS to characterize key-to-photovoltaics optoelectronic properties, carrier lifetime, and mobility, in a facile way.

Authors:
; ; ; ;  [1]
  1. ICFO-Institut de Ciencies Fotoniques, Mediterranean Technology Park, Castelldefels, Barcelona 08860 (Spain)
Publication Date:
OSTI Identifier:
22283181
Resource Type:
Journal Article
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 104; Journal Issue: 6; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0003-6951
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 77 NANOSCIENCE AND NANOTECHNOLOGY; CARRIER LIFETIME; CARRIER MOBILITY; COLLOIDS; COMPARATIVE EVALUATIONS; IMPEDANCE; LEAD SULFIDES; PHOTOVOLTAIC EFFECT; QUANTUM DOTS; SOLAR CELLS; SPACE CHARGE; SPECTROSCOPY; THIN FILMS; TRANSIENTS

Citation Formats

Rath, Arup K., Lasanta, Tania, Bernechea, Maria, Diedenhofen, Silke L., and Konstantatos, Gerasimos. Determination of carrier lifetime and mobility in colloidal quantum dot films via impedance spectroscopy. United States: N. p., 2014. Web. doi:10.1063/1.4865089.
Rath, Arup K., Lasanta, Tania, Bernechea, Maria, Diedenhofen, Silke L., & Konstantatos, Gerasimos. Determination of carrier lifetime and mobility in colloidal quantum dot films via impedance spectroscopy. United States. doi:10.1063/1.4865089.
Rath, Arup K., Lasanta, Tania, Bernechea, Maria, Diedenhofen, Silke L., and Konstantatos, Gerasimos. Mon . "Determination of carrier lifetime and mobility in colloidal quantum dot films via impedance spectroscopy". United States. doi:10.1063/1.4865089.
@article{osti_22283181,
title = {Determination of carrier lifetime and mobility in colloidal quantum dot films via impedance spectroscopy},
author = {Rath, Arup K. and Lasanta, Tania and Bernechea, Maria and Diedenhofen, Silke L. and Konstantatos, Gerasimos},
abstractNote = {Impedance Spectroscopy (IS) proves to be a powerful tool for the determination of carrier lifetime and majority carrier mobility in colloidal quantum dot films. We employ IS to determine the carrier lifetime in PbS quantum dot Schottky solar cells with Al and we verify the validity of the technique via transient photovoltage. We also present a simple approach based on an RC model that allows the determination of carrier mobility in PbS quantum dot films and we corroborate the results via comparison with space charge limited measurements. In summary, we demonstrate the potential of IS to characterize key-to-photovoltaics optoelectronic properties, carrier lifetime, and mobility, in a facile way.},
doi = {10.1063/1.4865089},
journal = {Applied Physics Letters},
issn = {0003-6951},
number = 6,
volume = 104,
place = {United States},
year = {2014},
month = {2}
}