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Title: Magnetic properties and magnetocaloric effect in the RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds

Abstract

The magnetic properties and magnetocaloric effect (MCE) in RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds have been investigated. All these compounds possess an antiferromagnetic (AFM)-paramagnetic (PM) transition around their respective Neel temperatures. The RCu{sub 2}Si{sub 2} compounds undergo spin-glassy behavior above Neel temperature. Furthermore, a field-induced metamagnetic transition from AFM to ferromagnetic (FM) states is observed in these compounds. The calculated magnetic entropy changes show that all RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds, especially, ErCu{sub 2}Si{sub 2} exhibits large MCEs with no thermal hysteresis and magnetic hysteresis loss. The value of −ΔS{sub M}{sup max} reaches 22.8 J/Kg K for magnetic field changes from 0 to 5 T. In particular, for field changes of 1 and 2 T, the giant reversible magnetic entropy changes −ΔS{sub M}{sup max} are 8.3 and 15.8 J/kg K at 2.5 K, which is lower than the boiling point of helium. The low-field giant magnetic entropy change, together with ignorable thermal hysteresis and field hysteresis loss of ErCu{sub 2}Si{sub 2} compound is expected to have effective applications in low temperature magnetic refrigeration.

Authors:
 [1];  [2]; ;  [3]; ; ; ;  [4]; ;  [1]
  1. School of Material Science and Engineering, Hebei University of Technology, Tianjin (China)
  2. (China)
  3. Key laboratory of cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing (China)
  4. State Key Laboratory of Magnetism, Beijing National Laboratory for Condensed Matter, Physics and Institute of Physics, Chinese Academy of Sciences, Beijing (China)
Publication Date:
OSTI Identifier:
22278029
Resource Type:
Journal Article
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 115; Journal Issue: 7; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-8979
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ANTIFERROMAGNETISM; ATOMIC FORCE MICROSCOPY; BOILING POINTS; COPPER SILICIDES; ENTROPY; ERBIUM COMPOUNDS; GERMANIDES; HOLMIUM COMPOUNDS; HYSTERESIS; MAGNETIC FIELDS; MAGNETIC PROPERTIES; NEEL TEMPERATURE; PARAMAGNETISM; TEMPERATURE DEPENDENCE

Citation Formats

Mo, Zhao-Jun, Key laboratory of cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, Shen, Jun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn, Wu, Jian-Feng, Yan, Li-Qin, Wang, Li-Chen, Sun, Ji-rong, Shen, Bao-Gen, Gao, Xin-Qiang, and Tang, Cheng-Chun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn. Magnetic properties and magnetocaloric effect in the RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds. United States: N. p., 2014. Web. doi:10.1063/1.4864419.
Mo, Zhao-Jun, Key laboratory of cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, Shen, Jun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn, Wu, Jian-Feng, Yan, Li-Qin, Wang, Li-Chen, Sun, Ji-rong, Shen, Bao-Gen, Gao, Xin-Qiang, & Tang, Cheng-Chun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn. Magnetic properties and magnetocaloric effect in the RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds. United States. doi:10.1063/1.4864419.
Mo, Zhao-Jun, Key laboratory of cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, Shen, Jun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn, Wu, Jian-Feng, Yan, Li-Qin, Wang, Li-Chen, Sun, Ji-rong, Shen, Bao-Gen, Gao, Xin-Qiang, and Tang, Cheng-Chun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn. Fri . "Magnetic properties and magnetocaloric effect in the RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds". United States. doi:10.1063/1.4864419.
@article{osti_22278029,
title = {Magnetic properties and magnetocaloric effect in the RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds},
author = {Mo, Zhao-Jun and Key laboratory of cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing and Shen, Jun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn and Wu, Jian-Feng and Yan, Li-Qin and Wang, Li-Chen and Sun, Ji-rong and Shen, Bao-Gen and Gao, Xin-Qiang and Tang, Cheng-Chun, E-mail: jshen@mail.ipc.ac.cn, E-mail: tangcc@hebut.edu.cn},
abstractNote = {The magnetic properties and magnetocaloric effect (MCE) in RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds have been investigated. All these compounds possess an antiferromagnetic (AFM)-paramagnetic (PM) transition around their respective Neel temperatures. The RCu{sub 2}Si{sub 2} compounds undergo spin-glassy behavior above Neel temperature. Furthermore, a field-induced metamagnetic transition from AFM to ferromagnetic (FM) states is observed in these compounds. The calculated magnetic entropy changes show that all RCu{sub 2}Si{sub 2} and RCu{sub 2}Ge{sub 2} (R = Ho, Er) compounds, especially, ErCu{sub 2}Si{sub 2} exhibits large MCEs with no thermal hysteresis and magnetic hysteresis loss. The value of −ΔS{sub M}{sup max} reaches 22.8 J/Kg K for magnetic field changes from 0 to 5 T. In particular, for field changes of 1 and 2 T, the giant reversible magnetic entropy changes −ΔS{sub M}{sup max} are 8.3 and 15.8 J/kg K at 2.5 K, which is lower than the boiling point of helium. The low-field giant magnetic entropy change, together with ignorable thermal hysteresis and field hysteresis loss of ErCu{sub 2}Si{sub 2} compound is expected to have effective applications in low temperature magnetic refrigeration.},
doi = {10.1063/1.4864419},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 7,
volume = 115,
place = {United States},
year = {2014},
month = {2}
}