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Title: Effect of p-type multi-walled carbon nanotubes for improving hydrogen storage behaviors

Abstract

In this study, the hydrogen storage behaviors of p-type multi-walled carbon nanotubes (MWNTs) were investigated through the surface modification of MWNTs by immersing them in sulfuric acid (H{sub 2}SO{sub 4}) and hydrogen peroxide (H{sub 2}O{sub 2}) at various ratios. The presence of acceptor-functional groups on the p-type MWNT surfaces was confirmed by X-ray photoelectron spectroscopy. Measurement of the zeta-potential determined the surface charge transfer and dispersion of the p-type MWMTs, and the hydrogen storage capacity was evaluated at 77 K and 1 bar. From the results obtained, it was found that acceptor-functional groups were introduced onto the MWNT surfaces, and the dispersion of MWNTs could be improved depending on the acid-mixed treatment conditions. The hydrogen storage was increased by acid-mixed treatments of up to 0.36 wt% in the p-type MWNTs, compared with 0.18 wt% in the As-received MWNTs. Consequently, the hydrogen storage capacities were greatly influenced by the acceptor-functional groups of p-type MWNT surfaces, resulting in increased electron acceptor–donor interaction at the interfaces. - Graphical abstract: Hydrogen storage behaviors of the p-type MWNTs with the acid-mixed treatments are described. Display Omitted Display Omitted.

Authors:
 [1];  [2];  [3];  [1]
  1. Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)
  2. Industrial Liaison Research Institute, Department of Mechanical Engineering, College of Engineering, Kyung Hee University, 446-701 Yongin (Korea, Republic of)
  3. Center for New and Renewable Energy Measurement, Korea Research Institute of Standards and Science, Daejeon 305-340 (Korea, Republic of)
Publication Date:
OSTI Identifier:
22274224
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 210; Journal Issue: 1; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY; CARBON NANOTUBES; DISPERSIONS; HYDROGEN PEROXIDE; HYDROGEN STORAGE; INTERACTIONS; INTERFACES; SULFURIC ACID; SURFACES; X-RAY PHOTOELECTRON SPECTROSCOPY

Citation Formats

Lee, Seul-Yi, Yop Rhee, Kyong, Nahm, Seung-Hoon, and Park, Soo-Jin, E-mail: sjpark@inha.ac.kr. Effect of p-type multi-walled carbon nanotubes for improving hydrogen storage behaviors. United States: N. p., 2014. Web. doi:10.1016/J.JSSC.2013.11.026.
Lee, Seul-Yi, Yop Rhee, Kyong, Nahm, Seung-Hoon, & Park, Soo-Jin, E-mail: sjpark@inha.ac.kr. Effect of p-type multi-walled carbon nanotubes for improving hydrogen storage behaviors. United States. doi:10.1016/J.JSSC.2013.11.026.
Lee, Seul-Yi, Yop Rhee, Kyong, Nahm, Seung-Hoon, and Park, Soo-Jin, E-mail: sjpark@inha.ac.kr. 2014. "Effect of p-type multi-walled carbon nanotubes for improving hydrogen storage behaviors". United States. doi:10.1016/J.JSSC.2013.11.026.
@article{osti_22274224,
title = {Effect of p-type multi-walled carbon nanotubes for improving hydrogen storage behaviors},
author = {Lee, Seul-Yi and Yop Rhee, Kyong and Nahm, Seung-Hoon and Park, Soo-Jin, E-mail: sjpark@inha.ac.kr},
abstractNote = {In this study, the hydrogen storage behaviors of p-type multi-walled carbon nanotubes (MWNTs) were investigated through the surface modification of MWNTs by immersing them in sulfuric acid (H{sub 2}SO{sub 4}) and hydrogen peroxide (H{sub 2}O{sub 2}) at various ratios. The presence of acceptor-functional groups on the p-type MWNT surfaces was confirmed by X-ray photoelectron spectroscopy. Measurement of the zeta-potential determined the surface charge transfer and dispersion of the p-type MWMTs, and the hydrogen storage capacity was evaluated at 77 K and 1 bar. From the results obtained, it was found that acceptor-functional groups were introduced onto the MWNT surfaces, and the dispersion of MWNTs could be improved depending on the acid-mixed treatment conditions. The hydrogen storage was increased by acid-mixed treatments of up to 0.36 wt% in the p-type MWNTs, compared with 0.18 wt% in the As-received MWNTs. Consequently, the hydrogen storage capacities were greatly influenced by the acceptor-functional groups of p-type MWNT surfaces, resulting in increased electron acceptor–donor interaction at the interfaces. - Graphical abstract: Hydrogen storage behaviors of the p-type MWNTs with the acid-mixed treatments are described. Display Omitted Display Omitted.},
doi = {10.1016/J.JSSC.2013.11.026},
journal = {Journal of Solid State Chemistry},
number = 1,
volume = 210,
place = {United States},
year = 2014,
month = 2
}
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