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Title: Detection of a new 'nematic-like' phase in liquid crystal-amphiphile mixture by differential scanning calorimetry

Abstract

Differential Scanning Calorimetry (DSC) studies on phase transitions of the pure liquid crystalline material N-4-methoxybenzylidene-4-butylaniline (MBBA) and mixtures of MBBA and the amphiphile Stearic Acid (StA) show significant changes in the behavior of mixture from pure MBBA, as regards the nematic-isotropic (N-I) transition temperature (T{sub c}) and other thermodynamic parameters like enthalpy, specific heat and activation energy with concentration of StA. In particular, the convexity of the Arrhenius plot in pure MBBA vanishes with StA concentration pointing to the formation of a new, perhaps 'nematic-like', phase in the mixtures.

Authors:
; ;  [1]
  1. Surface Physics and Materials Science Division, Saha Institute of Nuclear Physics, 1/AF Bidhannagar Block, Sector 1, Kolkata-700064 (India)
Publication Date:
OSTI Identifier:
22269534
Resource Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 1591; Journal Issue: 1; Conference: 58. DAE solid state physics symposium 2013, Patiala, Punjab (India), 17-21 Dec 2013; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ACTIVATION ENERGY; CALORIMETRY; CONCENTRATION RATIO; DIFFERENTIAL THERMAL ANALYSIS; ENTHALPY; LIQUID CRYSTALS; MIXTURES; OCTADECANOIC ACID; PHASE STABILITY; PHASE STUDIES; PHASE TRANSFORMATIONS; SPECIFIC HEAT; TRANSITION TEMPERATURE

Citation Formats

Dan, Kaustabh, E-mail: kaustabhdan@gmail.com, Roy, Madhusudan, E-mail: kaustabhdan@gmail.com, and Datta, Alokmay, E-mail: kaustabhdan@gmail.com. Detection of a new 'nematic-like' phase in liquid crystal-amphiphile mixture by differential scanning calorimetry. United States: N. p., 2014. Web. doi:10.1063/1.4872492.
Dan, Kaustabh, E-mail: kaustabhdan@gmail.com, Roy, Madhusudan, E-mail: kaustabhdan@gmail.com, & Datta, Alokmay, E-mail: kaustabhdan@gmail.com. Detection of a new 'nematic-like' phase in liquid crystal-amphiphile mixture by differential scanning calorimetry. United States. doi:10.1063/1.4872492.
Dan, Kaustabh, E-mail: kaustabhdan@gmail.com, Roy, Madhusudan, E-mail: kaustabhdan@gmail.com, and Datta, Alokmay, E-mail: kaustabhdan@gmail.com. Thu . "Detection of a new 'nematic-like' phase in liquid crystal-amphiphile mixture by differential scanning calorimetry". United States. doi:10.1063/1.4872492.
@article{osti_22269534,
title = {Detection of a new 'nematic-like' phase in liquid crystal-amphiphile mixture by differential scanning calorimetry},
author = {Dan, Kaustabh, E-mail: kaustabhdan@gmail.com and Roy, Madhusudan, E-mail: kaustabhdan@gmail.com and Datta, Alokmay, E-mail: kaustabhdan@gmail.com},
abstractNote = {Differential Scanning Calorimetry (DSC) studies on phase transitions of the pure liquid crystalline material N-4-methoxybenzylidene-4-butylaniline (MBBA) and mixtures of MBBA and the amphiphile Stearic Acid (StA) show significant changes in the behavior of mixture from pure MBBA, as regards the nematic-isotropic (N-I) transition temperature (T{sub c}) and other thermodynamic parameters like enthalpy, specific heat and activation energy with concentration of StA. In particular, the convexity of the Arrhenius plot in pure MBBA vanishes with StA concentration pointing to the formation of a new, perhaps 'nematic-like', phase in the mixtures.},
doi = {10.1063/1.4872492},
journal = {AIP Conference Proceedings},
number = 1,
volume = 1591,
place = {United States},
year = {Thu Apr 24 00:00:00 EDT 2014},
month = {Thu Apr 24 00:00:00 EDT 2014}
}
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