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Title: Terahertz and infrared transmission of an organic/inorganic hybrid thermoelectric material

Abstract

We report terahertz and infrared transmission measurements of a high-performance thermoelectric material containing tellurium nanowires in a conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) matrix. The DC electrical conductivity of the hybrid material (41 S/cm) is approximately one hundred times that of pure PEDOT:PSS and more than 400 times that of a film of pure tellurium nanowires, while the terahertz-frequency (THz) conductivity of PEDOT:PSS and the hybrid material are comparable at f ∼ 2THz. A frequency-dependent conductivity model indicates that the increased DC conductivity of the hybrid material results from an increase in the DC charge mobility rather than in the free charge density. We suggest that the increased DC conductivity of the hybrid material results from an increase in linkage between PEDOT domains by the tellurium nanowires.

Authors:
; ;  [1]; ;  [2]
  1. Physics Department, Macalester College, St. Paul, Minnesota 55105 (United States)
  2. The Molecular Foundry, Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)
Publication Date:
OSTI Identifier:
22261561
Resource Type:
Journal Article
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 104; Journal Issue: 14; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0003-6951
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ELECTRIC CONDUCTIVITY; FREQUENCY DEPENDENCE; HYBRIDIZATION; POLYMERS; QUANTUM WIRES; TELLURIUM; THERMOELECTRIC MATERIALS; TRANSMISSION; WIRES

Citation Formats

Heyman, J. N., E-mail: heyman@macalester.edu, Alebachew, B. A., Kaminski, Z. S., Nguyen, M. D., Coates, N. E., and Urban, J. J. Terahertz and infrared transmission of an organic/inorganic hybrid thermoelectric material. United States: N. p., 2014. Web. doi:10.1063/1.4871316.
Heyman, J. N., E-mail: heyman@macalester.edu, Alebachew, B. A., Kaminski, Z. S., Nguyen, M. D., Coates, N. E., & Urban, J. J. Terahertz and infrared transmission of an organic/inorganic hybrid thermoelectric material. United States. https://doi.org/10.1063/1.4871316
Heyman, J. N., E-mail: heyman@macalester.edu, Alebachew, B. A., Kaminski, Z. S., Nguyen, M. D., Coates, N. E., and Urban, J. J. Mon . "Terahertz and infrared transmission of an organic/inorganic hybrid thermoelectric material". United States. https://doi.org/10.1063/1.4871316.
@article{osti_22261561,
title = {Terahertz and infrared transmission of an organic/inorganic hybrid thermoelectric material},
author = {Heyman, J. N., E-mail: heyman@macalester.edu and Alebachew, B. A. and Kaminski, Z. S. and Nguyen, M. D. and Coates, N. E. and Urban, J. J.},
abstractNote = {We report terahertz and infrared transmission measurements of a high-performance thermoelectric material containing tellurium nanowires in a conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) matrix. The DC electrical conductivity of the hybrid material (41 S/cm) is approximately one hundred times that of pure PEDOT:PSS and more than 400 times that of a film of pure tellurium nanowires, while the terahertz-frequency (THz) conductivity of PEDOT:PSS and the hybrid material are comparable at f ∼ 2THz. A frequency-dependent conductivity model indicates that the increased DC conductivity of the hybrid material results from an increase in the DC charge mobility rather than in the free charge density. We suggest that the increased DC conductivity of the hybrid material results from an increase in linkage between PEDOT domains by the tellurium nanowires.},
doi = {10.1063/1.4871316},
url = {https://www.osti.gov/biblio/22261561}, journal = {Applied Physics Letters},
issn = {0003-6951},
number = 14,
volume = 104,
place = {United States},
year = {2014},
month = {4}
}