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Title: Nanocrystallization in spark plasma sintered Fe{sub 48}Cr{sub 15}Mo{sub 14}Y{sub 2}C{sub 15}B{sub 6} bulk amorphous alloy

Abstract

Spark plasma sintering (SPS) is evolving as an attractive process for the processing of multi-component Fe-based bulk amorphous alloys and their in-situ nanocomposites with controlled primary nanocrystallization. Extended Q-range small angle neutron scattering (EQ-SANS) analysis, complemented by x-ray diffraction and transmission electron microscopy, was performed to characterize nanocrystallization behavior of SPS sintered Fe-based bulk amorphous alloys. The SANS experiments show significant scattering for the samples sintered in the supercooled region indicating local structural/compositional changes associated with the profuse nucleation of nanoclusters (∼4 nm). For the samples spark plasma sintered near and above crystallization temperature (>653 °C), the SANS data show the formation of interference maximum indicating the formation and growth of (Fe,Cr){sub 23}C{sub 6} crystallites. The SANS data also indicate the evolution of bimodal crystallite distribution at higher sintering temperatures (above T{sub x1}). The growth of primary nanocrystallites results in impingement of concentration gradient fields (soft impingement effect), leading to non-random nucleation of crystallites near the primary crystallization.

Authors:
;  [1]; ;  [2];  [3]
  1. School of Mechanical and Aerospace Engineering, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)
  2. Department of Materials Science and Engineering, University of North Texas, Denton, Texas 76203 (United States)
  3. Advanced Photon Source, Argonne National Laboratory, Chicago, Illinois 60439 (United States)
Publication Date:
OSTI Identifier:
22218253
Resource Type:
Journal Article
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 114; Journal Issue: 5; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0021-8979
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; BORON ALLOYS; CHROMIUM ALLOYS; COMPOSITE MATERIALS; CONCENTRATION RATIO; CRYSTALLIZATION; IMPINGEMENT; IRON ALLOYS; MOLYBDENUM ALLOYS; NANOSTRUCTURES; NEUTRON DIFFRACTION; NUCLEATION; PLASMA; SINTERING; SMALL ANGLE SCATTERING; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION; YTTRIUM ALLOYS

Citation Formats

Singh, Ashish, Harimkar, Sandip P., Katakam, Shravana, Dahotre, Narendra B., and Ilavsky, Jan. Nanocrystallization in spark plasma sintered Fe{sub 48}Cr{sub 15}Mo{sub 14}Y{sub 2}C{sub 15}B{sub 6} bulk amorphous alloy. United States: N. p., 2013. Web. doi:10.1063/1.4817379.
Singh, Ashish, Harimkar, Sandip P., Katakam, Shravana, Dahotre, Narendra B., & Ilavsky, Jan. Nanocrystallization in spark plasma sintered Fe{sub 48}Cr{sub 15}Mo{sub 14}Y{sub 2}C{sub 15}B{sub 6} bulk amorphous alloy. United States. doi:10.1063/1.4817379.
Singh, Ashish, Harimkar, Sandip P., Katakam, Shravana, Dahotre, Narendra B., and Ilavsky, Jan. Wed . "Nanocrystallization in spark plasma sintered Fe{sub 48}Cr{sub 15}Mo{sub 14}Y{sub 2}C{sub 15}B{sub 6} bulk amorphous alloy". United States. doi:10.1063/1.4817379.
@article{osti_22218253,
title = {Nanocrystallization in spark plasma sintered Fe{sub 48}Cr{sub 15}Mo{sub 14}Y{sub 2}C{sub 15}B{sub 6} bulk amorphous alloy},
author = {Singh, Ashish and Harimkar, Sandip P. and Katakam, Shravana and Dahotre, Narendra B. and Ilavsky, Jan},
abstractNote = {Spark plasma sintering (SPS) is evolving as an attractive process for the processing of multi-component Fe-based bulk amorphous alloys and their in-situ nanocomposites with controlled primary nanocrystallization. Extended Q-range small angle neutron scattering (EQ-SANS) analysis, complemented by x-ray diffraction and transmission electron microscopy, was performed to characterize nanocrystallization behavior of SPS sintered Fe-based bulk amorphous alloys. The SANS experiments show significant scattering for the samples sintered in the supercooled region indicating local structural/compositional changes associated with the profuse nucleation of nanoclusters (∼4 nm). For the samples spark plasma sintered near and above crystallization temperature (>653 °C), the SANS data show the formation of interference maximum indicating the formation and growth of (Fe,Cr){sub 23}C{sub 6} crystallites. The SANS data also indicate the evolution of bimodal crystallite distribution at higher sintering temperatures (above T{sub x1}). The growth of primary nanocrystallites results in impingement of concentration gradient fields (soft impingement effect), leading to non-random nucleation of crystallites near the primary crystallization.},
doi = {10.1063/1.4817379},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 5,
volume = 114,
place = {United States},
year = {2013},
month = {8}
}