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Title: Third-order nonlinear optical response of colloidal gold nanoparticles prepared by sputtering deposition

Abstract

The nonlinear optical responses of gold nanoparticles dispersed in castor oil produced by sputtering deposition were investigated, using the thermally managed Z-scan technique. Particles with spherical shape and 2.6 nm of average diameter were obtained and characterized by transmission electron microscopy and small angle X-ray scattering. This colloid was highly stable, without the presence of chemical impurities, neither stabilizers. It was observed that this system presents a large refractive third-order nonlinear response and a negligible nonlinear absorption. Moreover, the evaluation of the all-optical switching figures of merit demonstrated that the colloidal nanoparticles prepared by sputtering deposition have a good potential for the development of ultrafast photonic devices.

Authors:
; ;  [1];  [2];  [3];  [4];  [5]
  1. Optics and Materials Group–OPTMA, Universidade Federal de Alagoas, CAIXA POSTAL 2051, 57061-970 Maceió (Brazil)
  2. Brazilian Synchrotron National Laboratory (LNLS), CNPEM, Rua Giuseppe Máximo Scolfaro 10.000, 13083-970 Campinas (Brazil)
  3. (Brazil)
  4. Institute of Physics, Universidade Federal do Rio Grande do Sul, 91501-970, Porto Alegre (Brazil)
  5. Laboratory of Molecular Catalysis, Institute of Chemistry, Universidade Federal do Rio Grande do Sul, 91501-970, Porto Alegre (Brazil)
Publication Date:
OSTI Identifier:
22217862
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 114; Journal Issue: 18; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CASTOR OIL; COLLOIDS; DEPOSITION; FABRICATION; GOLD; IMPURITIES; NANOSTRUCTURES; NONLINEAR PROBLEMS; PARTICLES; REFRACTIVE INDEX; SMALL ANGLE SCATTERING; SPUTTERING; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION

Citation Formats

Castro, Hemerson P. S., Alencar, Márcio A. R. C., Hickmann, Jandir M., Wender, Heberton, Department of Physics, Universidade Federal do Mato Grosso do Sul, 79070-900, Campo Grande, Teixeira, Sergio R., and Dupont, Jairton. Third-order nonlinear optical response of colloidal gold nanoparticles prepared by sputtering deposition. United States: N. p., 2013. Web. doi:10.1063/1.4831679.
Castro, Hemerson P. S., Alencar, Márcio A. R. C., Hickmann, Jandir M., Wender, Heberton, Department of Physics, Universidade Federal do Mato Grosso do Sul, 79070-900, Campo Grande, Teixeira, Sergio R., & Dupont, Jairton. Third-order nonlinear optical response of colloidal gold nanoparticles prepared by sputtering deposition. United States. doi:10.1063/1.4831679.
Castro, Hemerson P. S., Alencar, Márcio A. R. C., Hickmann, Jandir M., Wender, Heberton, Department of Physics, Universidade Federal do Mato Grosso do Sul, 79070-900, Campo Grande, Teixeira, Sergio R., and Dupont, Jairton. 2013. "Third-order nonlinear optical response of colloidal gold nanoparticles prepared by sputtering deposition". United States. doi:10.1063/1.4831679.
@article{osti_22217862,
title = {Third-order nonlinear optical response of colloidal gold nanoparticles prepared by sputtering deposition},
author = {Castro, Hemerson P. S. and Alencar, Márcio A. R. C. and Hickmann, Jandir M. and Wender, Heberton and Department of Physics, Universidade Federal do Mato Grosso do Sul, 79070-900, Campo Grande and Teixeira, Sergio R. and Dupont, Jairton},
abstractNote = {The nonlinear optical responses of gold nanoparticles dispersed in castor oil produced by sputtering deposition were investigated, using the thermally managed Z-scan technique. Particles with spherical shape and 2.6 nm of average diameter were obtained and characterized by transmission electron microscopy and small angle X-ray scattering. This colloid was highly stable, without the presence of chemical impurities, neither stabilizers. It was observed that this system presents a large refractive third-order nonlinear response and a negligible nonlinear absorption. Moreover, the evaluation of the all-optical switching figures of merit demonstrated that the colloidal nanoparticles prepared by sputtering deposition have a good potential for the development of ultrafast photonic devices.},
doi = {10.1063/1.4831679},
journal = {Journal of Applied Physics},
number = 18,
volume = 114,
place = {United States},
year = 2013,
month =
}
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