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Title: Synthesis and characterization of a new organic sulphate, [2,3-(CH{sub 3}){sub 2}C{sub 6}H{sub 3}NH{sub 3}]HSO{sub 4}·H{sub 2}O

Abstract

Highlights: ► The packing of this hybrid compound shows strong and moderate non-centrosymmetrical structure. ► In all the studied temperature range, this conductivity increases with the temperature showing that this material has semi-conductor behaviour. ► The reported crystal could be an optically non-linear material. A study of this activity could open to it opportunities on applied plan. -- Abstract: Crystals of a new hybrid compound C{sub 8}H{sub 12}N{sup +}, HSO{sub 4}{sup −}·H{sub 2}O were synthesized in aqueous solution and characterized by X-ray diffraction and IR absorption spectroscopy. This compound crystallizes in the orthorhombic non-centrosymmetrical space group P2{sub 1}2{sub 1}2{sub 1} and an unit cell with a = 5.74(2) Å, b = 9.17(2) Å, c = 21.34(4) Å, V = 1124(6) Å{sup 3}, and Z = 4. Its crystal structure is a packing of alternated inorganic and organic layers parallel to (a,b) planes. The different components are connected by a bi-dimensional network of strong O-H…O and N-H…O hydrogen bonds. Then, in order to detect phase transitions and watch changes in the conductivity behaviour, investigations by DTA–TG and differential scanning calorimetry (DSC) and electrical conductivity measurements were carried out.

Authors:
 [1];  [1];  [2];  [1]
  1. Laboratory of Material Chemistry, Faculty of Sciences, 7021-Zarzouna Bizerte (Tunisia)
  2. Petrochemical Research Chair College of Science, King Saud University, Riyadh (Saudi Arabia)
Publication Date:
OSTI Identifier:
22215111
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 47; Journal Issue: 6; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ABSORPTION SPECTROSCOPY; AQUEOUS SOLUTIONS; CALORIMETRY; CRYSTALS; DIELECTRIC PROPERTIES; ELECTRIC CONDUCTIVITY; HYBRIDIZATION; INFRARED SPECTRA; ORTHORHOMBIC LATTICES; PHASE TRANSFORMATIONS; SPACE GROUPS; SULFATES; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION

Citation Formats

Sahbani, T., Smirani, W., E-mail: wajda_sta@yahoo.fr, Al-Deyab, Salem S., and Rzaigui, M. Synthesis and characterization of a new organic sulphate, [2,3-(CH{sub 3}){sub 2}C{sub 6}H{sub 3}NH{sub 3}]HSO{sub 4}·H{sub 2}O. United States: N. p., 2012. Web. doi:10.1016/J.MATERRESBULL.2012.02.041.
Sahbani, T., Smirani, W., E-mail: wajda_sta@yahoo.fr, Al-Deyab, Salem S., & Rzaigui, M. Synthesis and characterization of a new organic sulphate, [2,3-(CH{sub 3}){sub 2}C{sub 6}H{sub 3}NH{sub 3}]HSO{sub 4}·H{sub 2}O. United States. doi:10.1016/J.MATERRESBULL.2012.02.041.
Sahbani, T., Smirani, W., E-mail: wajda_sta@yahoo.fr, Al-Deyab, Salem S., and Rzaigui, M. Fri . "Synthesis and characterization of a new organic sulphate, [2,3-(CH{sub 3}){sub 2}C{sub 6}H{sub 3}NH{sub 3}]HSO{sub 4}·H{sub 2}O". United States. doi:10.1016/J.MATERRESBULL.2012.02.041.
@article{osti_22215111,
title = {Synthesis and characterization of a new organic sulphate, [2,3-(CH{sub 3}){sub 2}C{sub 6}H{sub 3}NH{sub 3}]HSO{sub 4}·H{sub 2}O},
author = {Sahbani, T. and Smirani, W., E-mail: wajda_sta@yahoo.fr and Al-Deyab, Salem S. and Rzaigui, M.},
abstractNote = {Highlights: ► The packing of this hybrid compound shows strong and moderate non-centrosymmetrical structure. ► In all the studied temperature range, this conductivity increases with the temperature showing that this material has semi-conductor behaviour. ► The reported crystal could be an optically non-linear material. A study of this activity could open to it opportunities on applied plan. -- Abstract: Crystals of a new hybrid compound C{sub 8}H{sub 12}N{sup +}, HSO{sub 4}{sup −}·H{sub 2}O were synthesized in aqueous solution and characterized by X-ray diffraction and IR absorption spectroscopy. This compound crystallizes in the orthorhombic non-centrosymmetrical space group P2{sub 1}2{sub 1}2{sub 1} and an unit cell with a = 5.74(2) Å, b = 9.17(2) Å, c = 21.34(4) Å, V = 1124(6) Å{sup 3}, and Z = 4. Its crystal structure is a packing of alternated inorganic and organic layers parallel to (a,b) planes. The different components are connected by a bi-dimensional network of strong O-H…O and N-H…O hydrogen bonds. Then, in order to detect phase transitions and watch changes in the conductivity behaviour, investigations by DTA–TG and differential scanning calorimetry (DSC) and electrical conductivity measurements were carried out.},
doi = {10.1016/J.MATERRESBULL.2012.02.041},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = 6,
volume = 47,
place = {United States},
year = {2012},
month = {6}
}