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Title: Photocatalytic activity of erbium-doped TiO{sub 2} nanoparticles immobilized in macro-porous silica films

Journal Article · · Materials Research Bulletin
; ; ;  [1];  [2]
  1. C.U. de los Lagos, Universidad de Guadalajara, Lagos de Moreno, Jalisco (Mexico)
  2. C. U. de Ciencias Exactas e Ingenieria, Universidad de Guadalajara, Guadalajara, Jalisco (Mexico)

Highlights: Black-Right-Pointing-Pointer Erbium-doped TiO{sub 2} nanoparticles were immobilized on macro-porous silica films. Black-Right-Pointing-Pointer The films were obtained by a phase separation process. Black-Right-Pointing-Pointer The samples exhibited photo-catalytic activity under visible light. Black-Right-Pointing-Pointer The sensitization of TiO{sub 2} was attributed to a red shift in the TiO{sub 2} band-gap. -- Abstract: A macro-porous silica film served as mechanical support to immobilize TiO{sub 2} nanoparticles, which were doped with erbium. The films and the nanoparticles were prepared by sol-gel route. The nanoparticles exhibited photocatalytic activity under visible light. We obtained a degradation rate of methylene blue that followed first order kinetics. The sensitization of the nanoparticles to visible light was attributed to a red shift in the band-gap of the TiO{sub 2} due to the addition of erbium ions.

OSTI ID:
22212413
Journal Information:
Materials Research Bulletin, Vol. 47, Issue 2; Other Information: Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English