Synthesis, properties, and crystal structure of barium 1-oxyethylidenediphosphonatohydroxogermanate(IV) polyhydrate Ba{sub 3}[Ge({mu}-OH)({mu}-Oedph)]{sub 6} {center_dot} 25H{sub 2}O
Journal Article
·
· Crystallography Reports
- Mechnikov National University (Ukraine)
- Russian Academy of Sciences, Kurnakov Institute of General and Inorganic Chemistry (Russian Federation)
The barium salt of 1-oxyethylidenediphosphonatohydroxogermanium acid Ba{sub 3}[Ge({mu}-OH)({mu}-Oedph)]{sub 6} {center_dot} 25H{sub 2}O (I) (H{sub 4}Oedph is 1-oxyethylidenediphosphonic acid) was synthesized and studied by X-ray diffraction. The complex was characterized by elemental analysis, thermogravimetry, and IR spectroscopy. The hexanuclear cyclic complex anions [Ge({mu}-OH)({mu}-Oedph)]{sub 6}{sup 6-t-}] cations, and water molecules of crystallization are the structural units of the crystal of I.
- OSTI ID:
- 22156328
- Journal Information:
- Crystallography Reports, Vol. 58, Issue 2; Other Information: Copyright (c) 2013 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
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